Particles for malodor reduction

ABSTRACT

A composition including a plurality of particles, wherein the particles include: about 30% to about 95% by weight of a carrier; about 0.1% to about 30% by weight of a perfume; and about 0.00025% to about 30% by weight of a malodor agent; wherein the malodor agent comprises one or more malodor reduction materials having a Blocker Index of less than 3 or a Blocker Index average of 3 to about 0.001; and wherein each of the particles has a mass between about 0.1 mg to about 5 g.

FIELD OF THE INVENTION

Particles including malodor reduction compositions and methods of using such particles for managing malodor in laundry articles.

BACKGROUND OF THE INVENTION

Laundry articles having significant malodors is a problem that continues to face consumers.

People enjoy wearing garments that smell fresh and clean. Maintaining a full wardrobe that is populated with a sufficient number of garments that are fresh and clean can be a burden on many people because they are too busy to regularly spend their time taking care of their laundry and do not wish to pay for a service that will take care of their laundry. Further, many people have garments that comprise fabrics or appurtenances that may not be durable enough to withstand multiple wearing, washing, and drying cycles without a the appearance or function of the garment being degraded.

To compensate for these problems, many people wear garments multiple times before they launder the garment. In many circumstances, wearing a garment multiple times between washings or dry cleaning is fine. A shirt, pants, or skirt may be worn multiple times between washings if the garment has not picked up any visible stains, the person has not perspired appreciably, the person has not been in an environment having odiferous air such as a smoky environment, restaurant selling strong smelling foods, or the person has not contacted strongly smelling objects such as a pet. However, the typical experience for most people is that they do perspire, are in environments where strong odors are present, or come into contact with smelly pets and the like. So even if a person avoids acquiring a stain or smudge on their garment during wear, it is probable that the garment has picked up some odors during wear.

Sometimes laundered garments are stored in a closet for weeks or months prior to being worn. By the time the garment is worn, the scent of the garment acquired during laundering has worn off. Depending on the environment in which the garment is stored, the garment may have a neutral or no odor or may have a musty, moldy, stale malodor. The malodors associated with long term storage of garments can negatively impact the experience of the person, and those around her, who chooses to wear a garment that has been stored for an appreciable period of time.

A similar situation arises when a person wants to continue to wear an article of clothing that has been worn earlier in the day. For example, after getting off work, a person may want to go out with friends to a restaurant, pub, or movie. After wearing the clothing during the work day, the clothing may have a neutral or non-noticeable odor, or even worse may have an unattractive odor that was acquired during the course of the day. The neutral or even negative malodor can have a negative impact on the psyche of the wearer and form a negative impression upon the people around the wearer of such a garment.

Similar problems can be associated with storing laundry articles that have been worn. With wear, clothing can become sweaty and smelly. Prior to laundering, the soiled laundry article might be stored in a gym bag, trunk of the car, laundry hamper, or pile of clothing. Over time, the level of malodor can increase to a degree such that it becomes repulsive for the consumer and those around her. Further, the malodor may be experienced by the consumer when she handles the soiled laundry prior to washing.

Common malodors and sources thereof can include amine-based malodors (e.g. fish and urine), thiol and sulfide-based malodors (e.g. garlic and onion), C₂-C₁₂ carboxylic acid based malodors (e.g. body and pet odor), indole based malodors (e.g. fecal and bad breath), short chain fatty aldehyde based malodors (e.g. grease) and geosmin based malodors (e.g. mold/mildew). The typical technical approach for managing malodors is to apply a malodor reduction ingredient or to mask the malodor with perfume. Unfortunately, malodor control technologies typically cover up the malodor with a stronger scent and thus interfere with the scent of the perfumed or unperfumed laundry article that is treated with the malodor control technology. Thus, limited nature of the current malodor control technologies is constraining.

With these limitations in mind, there is a continuing unaddressed need for technologies for managing malodors in laundered and soiled laundry articles.

SUMMARY OF THE INVENTION

A composition comprising a plurality of particles, wherein said particles comprise: about 30% to about 95% by weight of a carrier; about 0.1% to about 30% by weight of a perfume; and about 0.00025% to about 30% by weight of a malodor agent; wherein said malodor agent comprises from about 1 to about 30 malodor reduction materials having a Blocker Index of less than 3 or a Blocker Index average of 3 to about 0.001; and wherein each of said particles has a mass between about 0.1 mg to about 5 g.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a particle.

FIG. 2 is a package containing particles.

FIG. 3 is a package containing particles.

DETAILED DESCRIPTION OF THE INVENTION

As used herein “MORV” is the calculated malodor reduction value for a subject material. A material's MORV indicates such material's ability to decrease or even eliminate the perception of one or more malodors. For purposes of the present application, a material's MORV is calculated in accordance with method found in the test methods section of the present application.

As used herein, the term “perfume” does not include malodor reduction materials. Thus, the perfume portion of a composition does not include, when determining the perfume's composition, any malodor reduction materials found in the composition as such malodor reduction materials are described herein. In short, if a material has a malodor reduction value “MORV” that is within the range of the MORV recited in the subject claim, such material is a malodor reduction material for purposes of such claim.

As used herein, “malodor” refers to compounds generally offensive or unpleasant to most people, such as the complex odors associated with bowel movements.

As used herein, “odor blocking” refers to the ability of a compound to dull the human sense of smell.

Unless otherwise noted, all component or composition levels are in reference to the active portion of that component or composition, and are exclusive of impurities, for example, residual solvents or by-products, which may be present in commercially available sources of such components or compositions.

All percentages and ratios are calculated by weight unless otherwise indicated. All percentages and ratios are calculated based on the total composition unless otherwise indicated.

It should be understood that every maximum numerical limitation given throughout this specification includes every lower numerical limitation, as if such lower numerical limitations were expressly written herein. Every minimum numerical limitation given throughout this specification will include every higher numerical limitation, as if such higher numerical limitations were expressly written herein. Every numerical range given throughout this specification will include every narrower numerical range that falls within such broader numerical range, as if such narrower numerical ranges were all expressly written herein.

Malodor Reduction Materials

A non-limiting set of suitable malodor reduction materials are provided in the tables below. For ease of use, each material in Tables 1-3 is assigned a numerical identifier which is found in the column for each table that is designated Number. Table 4 is a subset of Table 1, Table 5 is a subset of Table 2 and Table 6 is a subset of Table 3and there for Tables 4, 5and 6 each use the same numerical identifier as found, respectively, in Tables 1-3.

Codes A = Vapor Pressure > 0.1 torr B = Vapor Pressure is between 0.01 torr and 0.1 torr C = logP < 3 D = logP > 3 E = Probability of Ingredient Color Instability = 0% F = Probability of Ingredient Color Instability < 71% G = Odor Detection Threshold less than p.ol = 8 H = Odor Detection Threshold greater than p.ol = 8 I = Melamine formaldehyde PMC Headspace Response Ratio greater than or equal to 10 J = Melamine formaldehyde PMC leakage less than or equal to 5% K = Log of liquid dish neat product liquid-air partition coefficient greater than or equal to −7 L = Log of liquid dish neat product liquid-air partition coefficient greater than or equal to −5

TABLE 1 List of materials with at least one MORV from 1 to 5 Num- CAS Comment ber Material Name Number Code 1 2-ethylhexyl (Z)-3-(4- 5466-77-3 DEFHJ methoxyphenyl)acrylate 2 2,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ 5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 3 1,1-dimethoxynon-2-yne 13257-44-8 ACEFHJK 4 para-Cymen-8-ol 1197-01-9 BCGIJK 7 3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJK methylenebicyclo[4.3.1]decane 9 Methoxycyclododecane 2986-54-1 DEFHJK 10 1,1-dimethoxycyclododecane 950-33-4 DEFHJK 11 (Z)-tridec-2-enenitrile 22629-49-8 DEFHJK 13 Oxybenzone 131-57-7 DEFGJ 14 Oxyoctaline formate 65405-72-3 DFHJK 16 4-methyl-1-oxaspiro[5.5]undecan-4- 57094-40-3 CFGIJK ol 17 7-methyl-2H-benzo[b][1,4]dioxepin- 28940-11-6 CGIK 3(4H)-one 18 1,8-dioxacycloheptadecan-9-one 1725-01-5 DGJ 21 4-(tert-pentyl)cyclohexan-1-one 16587-71-6 ADFGIJKL 22 o-Phenyl anisol 86-26-0 DEFHJK 23 3a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK 2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 25 7-isopropyl-8,8-dimethyl-6,10- 62406-73-9 BDEFHIJK dioxaspiro[4.5]decane 28 Octyl 2-furoate 39251-88-2 DEFHJK 29 Octyl acetate 112-14-1 BDEFHJKL 30 octanal propylene glycol acetal 74094-61-4 BDEFHJKL 31 Octanal 124-13-0 ACHIKL 32 Octanal dimethyl acetal 10022-28-3 ACEFGJKL 33 Myrcene 123-35-3 ADEFGIKL 34 Myrcenol 543-39-5 BCEFGIJK 35 Myrcenyl acetate 1118-39-4 ADEFGJK 36 Myristaldehyde 124-25-4 DFHJK 37 Myristicine 607-91-0 CGJK 38 Myristyl nitrile 629-63-0 DEFHJK 39 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a- 103614-86-4 DEFHIJK octahydronaphthalen-1-ol 42 Ocimenol 5986-38-9 BCHIJK 43 Ocimenol 28977-58-4 BCHIJK 47 Nopyl acetate 128-51-8 DEFHJK 48 Nootkatone 4674-50-4 DHJK 49 Nonyl alcohol 143-08-8 BDEFGIJKL 50 Nonaldehyde 124-19-6 ADHIKL 52 12-methyl-14-tetradec-9-enolide 223104-61-8 DFHJK 57 N-ethyl-p-menthane-3-carboxamide 39711-79-0 DEFGIJK 61 1-(3-methylbenzofuran-2-yl)ethan-1- 23911-56-0 CEFHIK one 62 2-methoxynaphthalene 93-04-9 BDEFHK 63 Nerolidol 7212-44-4 DEFHJK 64 Nerol 106-25-2 BCHIK 65 1-ethyl-3- 31996-78-8 ACEFHIJKL methoxytricyclo[2.2.1.02,6]heptane 67 Methyl (E)-non-2-enoate 111-79-5 ADEFHJKL 68 10-isopropyl-2,7-dimethyl-1- 89079-92-5 BDEFHIJK oxaspiro[4.5]deca-3,6-diene 69 2-(2-(4-methylcyclohex-3-en-1- 95962-14-4 DHJK yl)propyl)cyclopentan-1-one 70 Myrtenal 564-94-3 ACFHIJKL 71 (E)-4-(2,2,3,6- 54992-90-4 BDEFHIJK tetramethylcyclohexyl)but-3-en-2- one 74 Myraldyl acetate 53889-39-7 DHJK 75 Musk tibetine 145-39-1 DHIJ 76 1,7-dioxacycloheptadecan-8-one 3391-83-1 DGJ 77 Musk ketone 81-14-1 DHJ 78 Musk ambrette 83-66-9 DHIJ 79 3-methylcyclopentadecan-1-one 541-91-3 DEFHJK 80 (E)-3-methylcyclopentadec-4-en-1- 82356-51-2 DHJK one 82 3-methyl-4-phenylbutan-2-ol 56836-93-2 BCEFHIK 83 1-(4-isopropylcyclohexyl)ethan-1-ol 63767-86-2 BDEFHIJK 85 Milk Lactone 72881-27-7 DEFHJK 91 Methyl octine carbonate 111-80-8 BDEFHKL 92 Methyl octyl acetaldehyde 19009-56-4 ADFHJKL 93 6,6-dimethoxy-2,5,5-trimethylhex-2- 67674-46-8 ACHIJKL ene 98 Methyl phenylethyl carbinol 2344-70-9 BCEFHIK 100 Methyl stearate 112-61-8 DEFHJ 101 Methyl nonyl acetaldehyde dimethyl 68141-17-3 BDEFHJK acetal 102 Methyl nonyl ketone 112-12-9 BDFHJKL 103 Methyl nonyl acetaldehyde 110-41-8 BDFHJK 104 Methyl myristate 124-10-7 DEFHJK 105 Methyl linoleate 112-63-0 DEFHJ 106 Methyl lavender ketone 67633-95-8 CFHJK 108 Methyl isoeugenol 93-16-3 ACEFHK 109 Methyl hexadecanoate 112-39-0 DEFHJK 110 Methyl eugenol 93-15-2 ACEFHK 112 Methyl epijasmonate 1211-29-6 CHJK 113 Methyl dihydrojasmonate 24851-98-7 DFHJK 114 Methyl diphenyl ether 3586-14-9 DEFHJK 117 Methyl cinnamate 103-26-4 BCEFHK 119 Methyl chavicol 140-67-0 ADEFHK 120 Methyl beta-naphthyl ketone 93-08-3 CEFHK 122 Methyl 2-octynoate 111-12-6 ACEFHKL 123 Methyl alpha-cyclogeranate 28043-10-9 ACHIJKL 126 Methoxycitronellal 3613-30-7 ACFGIJK 128 Menthone 1,2-glycerol ketal 67785-70-0 CEFHJ (racemic) 130 Octahydro-1H-4,7-methanoindene-1- 30772-79-3 BCFHIJKL carbaldehyde 134 3-(3-(tert-butyl)phenyl)-2- 62518-65-4 BDHJK methylpropanal 135 (E)-4-(4,8-dimethylnona-3,7-dien-1- 38462-23-6 DEFHJK yl)pyridine 137 (E)-trideca-3,12-dienenitrile 134769-33-8 DEFHJK 140 2,2-dimethyl-3-(m-tolyl)propan-1-ol 103694-68-4 CEFHIJK 141 2,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJK tetrahydroindeno[1,2-d][1,3]dioxine 142 Maceal 67845-30-1 BDFHJK 143 4-(4-hydroxy-4- 31906-04-4 CHJ methylpentyl)cyclohex-3-ene-1- carbaldehyde 145 1-Limonene 5989-54-8 ADEFGIJKL 146 (Z)-3-hexen-1-yl-2-cyclopenten-1- 53253-09-1 BDHK one 148 Linalyl octanoate 10024-64-3 DEFHJ 149 Linalyl isobutyrate 78-35-3 BDHJK 152 Linalyl benzoate 126-64-7 DFHJ 153 Linalyl anthranilate 7149-26-0 DFHJ 155 Linalool oxide (furanoid) 60047-17-8 BCHIJK 156 linalool oxide 1365-19-1 CGIJK 158 (2Z,6E)-3,7-dimethylnona-2,6- 61792-11-8 BDEFHJK dienenitrile 159 3-(4-methylcyclohex-3-en-1- 6784-13-0 ACFHIJK yl)butanal 161 (2,5-dimethyl-1,3-dihydroinden-2- 285977-85-7 CEFHJK yl)methanol 162 3-(4-(tert-butyl)phenyl)-2- 80-54-6 BDHJK methylpropanal 167 (E)-1-(1-methoxypropoxy)hex-3-ene 97358-54-8 ACEFGJKL 168 Leaf acetal 88683-94-7 ACEFGJKL 170 1-Carveol 2102-58-1 BCHIJK 174 Lauryl alcohol 112-53-8 DEFGJK 175 Lauryl acetate 112-66-3 DEFHJK 176 Lauric acid 143-07-7 DEFHJ 177 Lactojasmone 7011-83-8 BDEFHIJKL 178 Lauraldehyde 112-54-9 BDFHJK 179 3,6-dimethylhexahydrobenzofuran- 92015-65-1 BCEFHIJKL 2(3H)-one 182 4-(1-ethoxyvinyl)-3,3,5,5- 36306-87-3 BDFHIJK tetramethylcyclohexan-1-one 183 Khusimol 16223-63-5 CEFHJK 184 5-(sec-butyl)-2-(2,4- 117933-89-8 DEFHJ dimethylcyclohex-3-en-1-yl)-5- methyl-1,3-dioxane 185 (1-methyl-2-((1,2,2- 198404-98-7 DEFHJK trimethylbicyclo[3.1.0]hexan-3- yl)methyl)cyclopropyl)methanol 186 2-propylheptanenitrile 208041-98-9 ADEFHIJKL 187 (E)-6-(pent-3-en-1-yl)tetrahydro-2H- 32764-98-0 BCFHIKL pyran-2-one 189 2-hexylcyclopentan-1-one 13074-65-2 BDFHJKL 190 2-methyl-4-phenyl-1,3-dioxolane 33941-99-0 BCEFGIK 192 2,6,9,10-tetramethyl-1- 71078-31-4 BDEFHIJK oxaspiro(4.5)deca-3,6-diene 193 Isopulegol 89-79-2 BCEFHIJKL 195 Isopropyl palmitate 142-91-6 DEFHJ 196 Isopropyl myristate 110-27-0 DEFHJK 197 Isopropyl dodecanoate 10233-13-3 DEFHJK 199 Isopimpinellin 482-27-9 CFGJ 206 Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK 208 Isomenthone 491-07-6 ADEFGIJKL 209 Isojasmone 95-41-0 BDFHJKL 210 Isomenthone 36977-92-1 ADEFGIJKL 211 Isohexenyl cyclohexenyl 37677-14-8 DFHJK carboxaldehyde 212 Isoeugenyl benzyl ether 120-11-6 DFHJ 215 1-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2 DHJK 1,2,3,4,5,6,7,8-octahydronaphthalen- 2-yl)ethan-1-one 218 Isocyclocitral 1335-66-6 ACFHIJKL 221 Isobutyl quinoline 65442-31-1 DEFHJK 227 Isobornylcyclohexanol 68877-29-2 DEFHJK 228 Isobornyl propionate 2756-56-1 BDEFHIJK 229 Isobornyl isobutyrate 85586-67-0 BDEFHIJK 230 Isobornyl cyclohexanol 66072-32-0 DEFHJK 231 Isobornyl acetate 125-12-2 ADEFHIJKL 233 Isobergamate 68683-20-5 DEFHJK 234 Isoamyl undecylenate 12262-03-2 DEFHJK 238 Isoamyl laurate 6309-51-9 DEFHJK 242 Isoambrettolide 28645-51-4 DGJ 243 Irisnitrile 29127-83-1 ADEFHKL 244 Indolene 68527-79-7 DEFHJ 246 Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ 247 4,4a,5,9b-tetrahydroindeno[1,2- 18096-62-3 BCEFGJK d][1,3]dioxine 249 Hydroxy-citronellol 107-74-4 CEFGIJK 252 2-cyclododecylpropan-1-ol 118562-73-5 DEFHJK 253 Hydrocitronitrile 54089-83-7 CEFHJK 254 Hydrocinnamyl alcohol 122-97-4 BCEFHIK 256 Hydratropaldehyde dimethyl acetal 90-87-9 ACEFHJK 259 5-ethyl-4-hydroxy-2-methylfuran- 27538-09-6 CFGIK 3(2H)-one 260 2,3-dihydro-3,3-dimethyl-1H-indene- 173445-44-8 DHJK 5-propanal 261 3-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK inden-5-yl)propanal 263 Hexyl octanoate 1117-55-1 DEFHJK 267 Hexyl hexanoate 6378-65-0 DEFHJKL 269 Hexyl cinnamic aldehyde 101-86-0 DHJ 271 Hexyl benzoate 6789-88-4 DEFHJK 274 Hexenyl tiglate 84060-80-0 BDEFHJK 276 (E)-3,7-dimethylocta-2,6-dien-1-yl 3681-73-0 DEFHJ palmitate 277 Hexadecanolide 109-29-5 DEFGJK 278 2-butyl-4,4,6-trimethyl-1,3-dioxane 54546-26-8 ADEFHIJKL 280 Ethyl (1R,2R,3R,4R)-3- 116126-82-0 BDEFHIJK isopropylbicyclo[2.2.1]hept-5-ene-2- carboxylate 281 3a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5 CEFGJK methanoinden-6-yl acetate 285 2-(1-(3,3- 141773-73-1 DEFHJ dimethylcyclohexyl)ethoxy)-2- methylpropyl propionate 286 Heliotropine diethyl acetal 40527-42-2 CEFGJ 288 Helional 1205-17-0 CHJK 289 (E)-oxacyclohexadec-13-en-2-one 111879-80-2 DGJK 290 Gyrane 24237-00-1 ADEFHIJKL 292 Guaiol 489-86-1 DEFHJK 293 1-(2,6,6-trimethylcyclohex-2-en-1- 68611-23-4 DHJK yl)pentan-3-one 294 Ethyl 2-ethyl-6,6-dimethylcyclohex- 57934-97-1 BDEFHIJK 2-ene-1-carboxylate 295 Germacrene B 15423-57-1 DEFHJK 296 Germacrene D 23986-74-5 DEFHJK 300 Geranyl phenylacetate 102-22-7 DFHJ 301 Geranyl phenyl acetate 71648-43-6 DFHJ 303 Geranyl linalool 1113-21-9 DFHJ 307 Geranyl cyclopentanone 68133-79-9 DHJK 316 gamma-Undecalactone (racemic) 104-67-6 DEFHJKL 317 gamma-Terpinyl acetate 10235-63-9 BDHJK 318 gamma-Terpineol 586-81-2 BCGIJK 321 gamma-Nonalactone 104-61-0 BCEFHIKL 322 gamma-Muurolene 30021-74-0 DEFHJKL 323 gamma-(E)-6-(pent-3-en-1- 63095-33-0 BCEFHKL yl)tetrahydro-2H-pyran-2-one 324 gamma-Ionone 79-76-5 BDEFHIJK 325 gamma-Himachalene 53111-25-4 BDEFHJKL 328 gamma-Gurjunene 22567-17-5 DEFHJKL 329 gamma-Eudesmol 1209-71-8 DFHJK 330 gamma-Dodecalactone 2305-05-7 DEFHJK 331 gamma-Damascone 35087-49-1 BDEFHIJK 332 gamma-Decalactone 706-14-9 BDEFHIJKL 333 gamma-Cadinene 39029-41-9 DEFHJKL 334 1-(3,3-dimethylcyclohexyl)pent-4- 56973-87-6 BDEFHJK en-1-one 335 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8- 1222-05-5 DEFHJK hexahydrocyclopenta[g]isochromene 336 Furfuryl octanoate 39252-03-4 DEFHJK 338 Furfuryl hexanoate 39252-02-3 CEFHJK 339 Furfuryl heptanoate 39481-28-2 CEFHJK 342 2-methyldecanenitrile 69300-15-8 BDEFHJKL 343 8,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJK hexahydro-1H-4,7-methanoinden-6- yl propionate 344 Ethyl (3aR,4S,7R,7aR)-octahydro- 80657-64-3 DEFHIJK 3aH-4,7-methanoindene-3a- carboxylate 347 Diethyl cyclohexane-1,4- 72903-27-6 CEFHJK dicarboxylate 349 (6-isopropyl-9-methyl-1,4- 63187-91-7 CEFHJ dioxaspiro[4.5]decan-2-yl)methanol 350 2-isobutyl-4-methyltetrahydro-2H- 63500-71-0 BCEFHIJK pyran-4-ol 352 Undec-10-enenitrile 53179-04-7 BDEFHJK 353 (Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJK methanochromen-2-one 356 3-(2-ethylphenyl)-2,2- 67634-15-5 BDHJK dimethylpropanal 358 (E)-4,8-dimethyldeca-4,9-dienal 71077-31-1 BDFHJK 359 (E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK 1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3- methylbutan-2-ol 360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3 DEFHJK hexahydro-1H-4,7-methanoinden-6- yl acetate 361 3-(4-ethylphenyl)-2,2- 134123-93-6 DEFHJK dimethylpropanenitrile 362 2-heptylcyclopentan-1-one 137-03-1 DFHJKL 363 1-ethoxyethoxy Cyclododecane 389083-83-4 DEFHJK 364 3-cyclohexene-1-carboxylic acid, 815580-59-7 ACHIJKL 2,6,6-trimethyl-, methyl ester 368 Farnesyl acetate 29548-30-9 DEFHJK 369 Farnesol 4602-84-0 DEFHJK 370 Oxacyclohexadecan-2-one 106-02-5 DEFGJK 371 1-cyclopentadec-4-en-1-one 14595-54-1 DEFGJK 372 1-cyclopentadec-4-en-1-one 35720-57-1 DEFGJK 373 2-methoxy-4-(4- 128489-04-3 CGJ methylenetetrahydro-2H-pyran-2- yl)phenol 374 Eugenyl acetate 93-28-7 CFHJK 375 Eugenol 97-53-0 CHIK 377 Ethylmethylphenylglycidate 77-83-8 CFHJK 378 Ethylene brassylate 105-95-3 DFGJ 381 Ethyl undecylenate 692-86-4 DEFHJK 385 Ethyl palmitate 628-97-7 DEFHJ 386 Ethyl nonanoate 123-29-5 BDEFHJKL 388 Ethyl myristate 124-06-1 DEFHJK 390 Ethyl linalool 10339-55-6 BCEFHJK 391 Ethyl laurate 106-33-2 DEFHJK 394 Ethyl hexyl ketone 925-78-0 ADFHIKL 397 Ethyl decanoate 110-38-3 BDEFHJK 398 Ethyl gamma-Safranate 35044-57-6 ADHIJK 407 Ethyl 3-phenylglycidate 121-39-1 CGJK 413 6-ethyl-2,10,10-trimethyl-1- 79893-63-3 BDEFHIJK oxaspiro[4.5]deca-3,6-diene 414 Elemol 639-99-6 DEFHJK 415 (2-(1-ethoxyethoxy)ethyl)benzene 2556-10-7 BCEFHJK 416 (E)-3-methyl-5-(2,2,3- 67801-20-1 DHJK trimethylcyclopent-3-en-1-yl)pent-4- en-2-ol 417 d-xylose 58-86-6 CGIJ 418 (E)-4-((3aS,7aS)-octahydro-5H-4,7- 30168-23-1 DFHJK methanoinden-5-ylidene)butanal 421 Dodecanal dimethyl acetal 14620-52-1 DEFHJK 424 d-Limonene 5989-27-5 ADEFGIJKL 425 Dipropylene Glycol 25265-71-8 CEFGIK 426 Dispirone 83863-64-3 BDEFHJK 428 Diphenyloxide 101-84-8 BDEFHK 429 Diphenylmethane 101-81-5 DEFGK 432 Dimethyl benzyl carbinyl butyrate 10094-34-5 DEFHJK 436 2,6-dimethyloct-7-en-4-one 1879-00-1 ADEFHIJKL 441 Octahydro-1H-4,7-methanoinden-5- 64001-15-6 DEFHJKL yl acetate 444 Dihydrocarveol acetate 20777-49-5 BDEFHIJK 445 Dihydrocarveol 619-01-2 BCEFHIJKL 449 Dihydro Linalool 18479-51-1 BCEFGIJKL 450 Dihydro Isojasmonate 37172-53-5 DHJK 453 Dibutyl sulfide 544-40-1 ADEFHIKL 457 Dibenzyl 103-29-7 DEFGJK 459 delta-Undecalactone 710-04-3 DEFHJKL 461 delta-Elemene 20307-84-0 BDEFHJK 462 delta-Guaiene 3691-11-0 DEFHJKL 463 delta-Dodecalactone 713-95-1 DEFHJK 464 delta-Decalactone 705-86-2 BDEFHIJKL 465 delta-Cadinene 483-76-1 DEFHJKL 466 delta-damascone 57378-68-4 ADHIJK 467 delta-Amorphene 189165-79-5 DEFHJKL 468 delta-3-Carene 13466-78-9 ADEFGIJKL 470 Decylenic alcohol 13019-22-2 BDEFHJK 471 Decyl propionate 5454-19-3 DEFHJK 473 Decanal diethyl acetal 34764-02-8 DEFHJK 474 Decahydro-beta-naphthol 825-51-4 BCEFGIK 475 1-cyclohexylethyl (E)-but-2-enoate 68039-69-0 BDFHJK 478 3-(4-isopropylphenyl)-2- 103-95-7 BDFHJK methylpropanal 479 Cyclotetradecane 295-17-0 DEFGJKL 480 Cyclopentadecanone 502-72-7 DEFGJK 482 Cyclohexyl salicylate 25485-88-5 DFGJ 484 3a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK methanoinden-6-yl butyrate 485 Cyclic ethylene dodecanedioate 54982-83-1 DFGJ 486 8,8-dimethyl-1,2,3,4,5,6,7,8- 68991-97-9 DHJK octahydronaphthalene-2- carbaldehyde 487 3a,4,5,6,7,7a-hexahydro-1H-4,7- 67634-20-2 DEFHJK methanoinden-5-yl isobutyrate 488 Curzerene 17910-09-7 DHJK 491 Cumic alcohol 536-60-7 CHIJK 493 Coumarone 1646-26-0 BCEFHIK 497 2-(3-phenylpropyl)pyridine 2110-18-1 CEFHJK 498 Dodecanenitrile 2437-25-4 DEFHJK 501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ 502 Citryl acetate 6819-19-8 DFHJK 503 Citrus Propanol 15760-18-6 CEFHIJK 505 Citronitrile 93893-89-1 CEFHJK 519 Citral propylene glycol acetal 10444-50-5 CEFHJK 520 Citral dimethyl acetal 7549-37-3 BCEFHJK 521 Citral diethyl acetal 7492-66-2 BDEFHJK 524 cis-Ocimene 3338-55-4 ADGIKL 527 cis-Limonene oxide 13837-75-7 ADEFGIJKL 529 Cis-iso-ambrettolide 36508-31-3 DGJ 530 cis-6-nonenol 35854-86-5 BCEFHIKL 531 cis-carveol 1197-06-4 BCHIJK 532 cis-4-Decen-1-al 21662-09-9 ADHKL 534 cis-3-hexenyl-cis-3-hexenoate 61444-38-0 BDEFHJK 537 cis-3-Hexenyl salicylate 65405-77-8 DEFGJ 541 Cis-3-hexenyl Benzoate 25152-85-6 DEFHJK 544 cis-3-Hexenyl 2-methylbutyrate 53398-85-9 ADEFHJKL 546 cis-3, cis-6-nonadienol 53046-97-2 ACEFHK 548 Cinnamyl propionate 103-56-0 DEFHJK 550 Cinnamyl isobutyrate 103-59-3 DEFHJK 551 Cinnamyl formate 104-65-4 BCEFHK 552 Cinnamyl cinnamate 122-69-0 DHJ 553 Cinnamyl acetate 103-54-8 BCEFHK 555 Cinnamic alcohol 104-54-1 BCEFHIK 558 Cetyl alcohol 36653-82-4 DEFHJ 559 (E)-1-(2,6,6-trimethylcyclohex-2-en- 79-78-7 DHJK 1-yl)hepta-1,6-dien-3-one 560 2-methyl-4-(2,6,6-trimethylcyclohex- 65405-84-7 DFHJK 1-en-1-yl)butanal 561 (3aR,5aR,9aR,9bR)-3a,6,6,9a- 3738-00-9 DEFHJK tetramethyldodecahydronaphtho[2,1- b]furan 562 1,6-dioxacycloheptadecan-7-one 6707-60-4 DGJ 563 1-(6-(tert-butyl)-1,1-dimethyl-2,3- 13171-00-1 DEFHJK dihydro-1H-inden-4-yl)ethan-1-one 565 Cedryl methyl ether 19870-74-7 ADEFHJK 566 Cedryl formate 39900-38-4 BDEFHJK 567 Cedryl acetate 77-54-3 DEFHJK 568 (4Z,8Z)-1,5,9-trimethyl-13- 71735-79-0 DFHJK oxabicyclo[10.1.0]trideca-4,8-diene 569 Cedrol 77-53-2 DEFHJK 570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJK trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 571 5-methyl-1-(2,2,3- 426218-78-2 DFHJ trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 572 1,1,2,3,3-pentamethyl-1,2,3,5,6,7- 33704-61-9 BDEFHIJK hexahydro-4H-inden-4-one 573 Caryophyllene alcohol acetate 32214-91-8 DEFHJK 574 Caryolan-1-ol 472-97-9 DEFHJK 577 Carvyl acetate 97-42-7 BDHIJK 578 Caprylnitrile 124-12-9 ACEFGIKL 580 Caprylic alcohol 111-87-5 ACEFGIKL 581 Caprylic acid 124-07-2 BCEFHIK 582 Capric acid 334-48-5 DEFHJK 584 Capraldehyde 112-31-2 ADHKL 586 3-(4-methoxyphenyl)-2- 5462-06-6 BCHJK methylpropanal 587 Camphorquinone 10373-78-1 ACEFGIJK 589 Camphene 79-92-5 ADEFGIJKL 591 Ethyl 2-methyl-4-oxo-6- 59151-19-8 DHJ pentylcyclohex-2-ene-1-carboxylate 592 Butylated hydroxytoluene 128-37-0 DEFGIJK 594 Butyl stearate 123-95-5 DEFHJ 595 Butyl butyryl lactate 7492-70-8 CEFGJK 599 Butyl 10-undecenoate 109-42-2 DEFHJK 600 2-methyl-4-(2,2,3- 72089-08-8 DEFHJK trimethylcyclopent-3-en-1-yl)butan- 1-ol 601 3-(4-(tert-butyl)phenyl)propanal 18127-01-0 BDHJK 603 Bornyl isobutyrate 24717-86-0 BDEFHIJK 604 Bornyl acetate 76-49-3 ADEFHIJKL 606 2-ethoxy-2,6,6-trimethyl-9- 68845-00-1 BDEFHJK methylenebicyclo[3.3.1]nonane 607 (ethoxymethoxy)cyclododecane 58567-11-6 DEFHJK 608 Bisabolene 495-62-5 DEFHJK 609 Bigarade oxide 72429-08-4 ADEFHJKL 610 beta-Vetivone 18444-79-6 DHJK 611 beta-Terpinyl acetate 10198-23-9 BDHJK 612 beta-Terpineol 138-87-4 BCGIJK 613 beta-Sinensal 60066-88-8 DHJK 614 beta-Sesquiphellandrene 20307-83-9 DEFHJK 615 beta-Selinene 17066-67-0 BDEFGJK 616 beta-Santalol 77-42-9 DEFHJK 618 beta-Pinene 127-91-3 ADEFGIJKL 620 beta-Naphthyl ethyl ether 93-18-5 BDEFHJK 621 beta-Patchoulline 514-51-2 BDEFGJKL 624 beta-Himachalene Oxide 57819-73-5 BDFHJK 625 beta-Himachalene 1461-03-6 DEFHJKL 626 beta-Guaiene 88-84-6 DEFHJKL 627 (2,2-dimethoxyethyl)benzene 101-48-4 DHJK 628 beta-Farnesene 18794-84-8 DEFHJK 631 beta-Copaene 18252-44-3 BDEFHJKL 632 beta-Cedrene 546-28-1 BDEFGJKL 633 beta-Caryophyllene 87-44-5 DEFHJKL 635 beta-Bisabolol 15352-77-9 DFHJK 636 Beta ionone epoxide 23267-57-4 BDEFHIJK 638 Bergaptene 484-20-8 CGJ 639 Benzyl-tert-butanol 103-05-9 CEFGJK 644 Benzyl laurate 140-25-0 DEFHJ 649 Benzyl dimethyl carbinol 100-86-7 BCEFGIK 650 Benzyl cinnamate 103-41-3 DHJ 653 Benzyl benzoate 120-51-4 DHJ 655 Benzophenone 119-61-9 DEFHK 658 7-isopentyl-2H- 362467-67-2 DHJ benzo[b][1,4]dioxepin-3(4H)-one 659 2′-isopropyl-1,7,7- 188199-50-0 DEFHJK trimethylspiro[bicyclo[2.2.1]heptane- 2,4′-[1,3]dioxane] 660 4-(4-methylpent-3-en-1-yl)cyclohex- 21690-43-7 DEFHJK 3-ene-1-carbonitrile 661 Aurantiol 89-43-0 DEFHJ 663 Anisyl phenylacetate 102-17-0 DFHJ 668 Methyl (E)-octa-4,7-dienoate 189440-77-5 ACEFHKL 671 Amyl Cinnamate 3487-99-8 DEFHJK 673 (3aR,5aS,9aS,9bR)-3a,6,6,9a- 6790-58-5 DEFHJK tetramethyldodecahydronaphtho[2,1- b]furan 674 (4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJK hexamethyloctahydro-4H-4a,9- methanoazuleno[5,6-d][1,3]dioxole 675 2,5,5-trimethyl-1,2,3,4,5,6,7,8- 71832-76-3 DEFHJK octahydronaphthalen-2-ol 676 2,5,5-trimethyl-1,2,3,4,5,6,7,8- 41199-19-3 DEFHJK octahydronaphthalen-2-ol 677 1-((2-(tert- 139504-68-0 DEFHJK butyl)cyclohexyl)oxy)butan-2-ol 678 (3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJ tetramethyldodecahydro-5H-3,5a- epoxynaphtho[2,1-c]oxepine 679 2,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 ADEFHJK 2H-indeno[4,5-b]furan 680 2,2,6,6,7,8,8-heptamethyldecahydro- 647828-16-8 ADEFHJK 2H-indeno[4,5-b]furan 681 Amber acetate 37172-02-4 BDEFHJK 682 Alpinofix ® 811436-82-5 DEFHJ 683 alpha-Thujone 546-80-5 ADEFGIJKL 684 alpha-Vetivone 15764-04-2 DHJK 686 alpha-Terpinyl propionate 80-27-3 BDEFHJK 691 alpha-Sinensal 17909-77-2 DHJK 692 alpha-Selinene 473-13-2 BDEFHJK 693 alpha-Santalene 512-61-8 ADEFHJKL 694 alpha-Santalol 115-71-9 DEFHJK 696 alpha-Patchoulene 560-32-7 ADEFHJKL 697 alpha-neobutenone 56973-85-4 BDHJK 698 alpha-Muurolene 10208-80-7 DEFHJKL 700 alpha-methyl ionone 127-42-4 BDHJK 702 alpha-Limonene 138-86-3 ADEFGIJKL 704 alpha-Irone 79-69-6 BDHJK 706 alpha-Humulene 6753-98-6 DEFHJK 707 alpha-Himachalene 186538-22-7 BDEFHJK 708 alpha-Gurjunene 489-40-7 BDEFHJKL 709 alpha-Guaiene 3691-12-1 DEFHJKL 710 alpha-Farnesene 502-61-4 DEFHJK 711 alpha-Fenchene 471-84-1 ADEFGIJKL 712 alpha-Eudesmol 473-16-5 DEFHJK 713 alpha-Curcumene 4176-17-4 DEFHJK 714 alpha-Cubebene 17699-14-8 ADEFHJKL 715 alpha-Cedrene epoxide 13567-39-0 ADEFHJK 716 alpha-Cadinol 481-34-5 DEFHJK 717 alpha-Cadinene 24406-05-1 DEFHJKL 718 alpha-Bisabolol 515-69-5 DFHJK 719 alpha-bisabolene 17627-44-0 DEFHJK 720 alpha-Bergamotene 17699-05-7 BDEFHJKL 721 alpha-Amylcinnamyl alcohol 101-85-9 DEFHJ 722 alpha-Amylcinnamyl acetate 7493-78-9 DEFHJ 723 alpha-Amylcinnamaldehyde diethyl 60763-41-9 DEFHJ acetal 724 alpha-Amylcinnamaldehyde 122-40-7 DHJK 725 alpha-Amorphene 23515-88-0 DEFHJKL 726 alpha-Agarofuran 5956-12-7 BDEFHJK 727 1-methyl-4-(4-methyl-3-penten-1- 52475-86-2 DFHJK yl)-3-Cyclohexene-1-carboxaldehyde 730 1-Phenyl-2-pentanol 705-73-7 CEFHK 731 1-Phenyl-3-methyl-3-pentanol 10415-87-9 CEFHJK 733 2,3,4-trimethoxy-benzaldehyde 2103-57-3 BCGI 735 2,4,5-trimethoxy-benzaldehyde 4460-86-0 BCG 736 2,4,6-trimethoxybenzaldehyde 830-79-5 BCGI 738 2,4-Nonadienal 6750-03-4 ACHKL 741 2,6,10-Trimethylundecanal 105-88-4 BDFGJK 742 alpha,4-Dimethyl benzenepropanal 41496-43-9 ACHJK 746 Allyl cyclohexyl propionate 2705-87-5 BDEFHJK 748 Allyl amyl glycolate 67634-00-8 BCEFGJK 750 Allo-aromadendrene 25246-27-9 BDEFHJKL 752 Aldehyde C-11 143-14-6 ADHJK 754 Methyl (E)-2-(((3,5- 94022-83-0 DEFHJ dimethylcyclohex-3-en-1- yl)methylene)amino)benzoate 757 2,6,10-trimethylundec-9-enal 141-13-9 BDFHJK 758 Acetoxymethyl-isolongifolene 59056-62-1 BDEFHJK (isomers) 763 Acetate C9 143-13-5 BDEFHJKL 764 Acetarolle ® 744266-61-3 DFHJK 766 Acetaldehyde phenylethyl propyl 7493-57-4 CEFHJK acetal 767 Acetaldehyde dipropyl acetal 105-82-8 ACEFGIKL 768 Acetaldehyde benzyl 2-methoxyethyl 7492-39-9 BCEFHJK acetal 769 (Z)-2-(4-methylbenzylidene)heptanal 84697-09-6 DHJ 770 9-decenal 39770-05-3 ADHKL 771 8-Hexadecenolide 123-69-3 DGJ 772 7-Methoxycoumarin 531-59-9 CHK 774 7-epi-alpha-Selinene 123123-37-5 BDEFHJK 775 7-eip-alpha-Eudesmol 123123-38-6 DEFHJK 776 7-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJ hexamethyltetralin 778 6-Isopropylquinoline 135-79-5 CEFHJK 781 6,6-dimethyl-2-norpinene-2- 33885-51-7 BCFHJK propionaldehyde 782 6,10,14-trimethyl-2-Pentadecanone 502-69-2 DEFHJK 786 5-Isopropenyl-2-methyl-2- 13679-86-2 ACGIJKL vinyltetrahydrofuran 788 5-Cyclohexadecenone 37609-25-9 DEFGJK 791 4-Terpinenol 562-74-3 BCHIJK 792 4-Pentenophenone 3240-29-7 BCEFHIK 800 4-Carvomenthenol 28219-82-1 BCHIJK 802 4,5,6,7-Tetrahydro-3,6- 494-90-6 BCEFHIJKL dimethylbenzofuran 803 4-(p-Methoxyphenyl)-2-butanone 104-20-1 BCEFHJK 804 3-Thujopsanone 25966-79-4 BDEFHJK 805 3-Propylidenephthalide 17369-59-4 CEFHK 806 3-Nonylacrolein 20407-84-5 BDFHJK 807 3-Methyl-5-phenyl-1-pentanal 55066-49-4 BDFHJK 814 3-Hexenyl isovalerate 10032-11-8 ADEFHJKL 821 3,6-Dimethyl-3-octanyl acetate 60763-42-0 ADEFHIJKL 824 3,4,5-trimethoxybenzaldehyde 86-81-7 BCGIK 826 3-(p- 7775-00-0 BDFHJK Isopropylphenyl)propionaldehyde 827 2-Undecenenitrile 22629-48-7 BDEFHJK 828 2-Undecenal 2463-77-6 ADHJK 829 2-trans-6-trans-Nonadienal 17587-33-6 ACHKL 831 2-Phenylethyl butyrate 103-52-6 DEFHJK 833 2-Phenyl-3-(2-furyl)prop-2-enal 57568-60-2 CHJ 834 2-Phenoxyethanol 122-99-6 BCEFGIK 837 2-Nonen-1-al 2463-53-8 ADHKL 839 2-Nonanol 628-99-9 BDEFGIKL 840 2-Nonanone 821-55-6 ADFHIKL 849 2-Isobutyl quinoline 93-19-6 CEFHJK 850 2-Hexylidene cyclopentanone 17373-89-6 DFHJKL 852 2-Heptyl tetrahydrofuran 2435-16-7 BDEFHJKL 856 2-Decenal 3913-71-1 ADHKL 864 2,6-Nonadienal 26370-28-5 ACHKL 865 2,6-Nonadien-1-ol 7786-44-9 ACEFHK 866 2,6-dimethyl-octanal 7779-07-9 ADFGIJKL 868 1-Decanol 112-30-1 BDEFGJK 869 1-Hepten-1-ol, 1-acetate 35468-97-4 ACEFHKL 870 10-Undecen-1-ol 112-43-6 DEFHJK 871 10-Undecenal 112-45-8 ADHJK 872 10-epi-gamma-Eudesmol 15051-81-7 DFHJK 873 1,8-Thiocineol 68391-28-6 ADEFHIJKL 876 1,3,5-undecatriene 16356-11-9 ADEFHJKL 877 1,2-Dihydrolinalool 2270-57-7 BCEFGIJKL 878 1,3,3-trimethyl-2-norbornanyl 13851-11-1 ADEFHIJKL acetate 879 1,1,2,3,3-Pentamethylindan 1203-17-4 ADHIJKL 881 (Z)-6,10-dimethylundeca-5,9-dien-2- 3239-37-0 DEFHJK yl acetate 884 (Z)-3-Dodecenal 68141-15-1 BCFHJK 885 (S)-gamma-Undecalactone 74568-05-1 DEFHJKL 886 (R)-gamma-Undecalactone 74568-06-2 DEFHJKL 890 (E)-6,10-dimethylundeca-5,9-dien-2- 3239-35-8 DEFHJK yl acetat 892 (2Z)-3-methyl-5-phenyl-2- 53243-59-7 DEFHJK Pentenenitrile 893 (2S,5S,6S)-2,6,10,10-tetramethyl-1- 65620-50-0 DFHIJK oxaspiro[4_5]decan-6-ol 894 (2E)-3-methyl-5-phenyl-2- 53243-60-0 CEFHJK pentenenitrile 897 (+)-Dihydrocarveol 22567-21-1 BCEFHIJKL 905 Menthone 89-80-5 ADEFGIJKL 908 (R,E)-2-methyl-4-(2,2,3- 185068-69-3 CHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 912 2-(8-isopropyl-6- 68901-32-6 DEFHJK methylbicyclo[2.2.2]oct-5-en-2-yl)- 1,3-dioxolane 913 gamma-methyl ionone 7388-22-9 BDHIJK 914 3-(3-isopropylphenyl)butanal 125109-85-5 BDHJK 916 3-(1-ethoxyethoxy)-3,7- 40910-49-4 BDEFHJK dimethylocta-1,6-diene 919 3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3 CEFHJK methanoinden-6-yl propionate 920 Bulnesol 22451-73-6 DEFHJK 922 Benzyl phenylacetate 102-16-9 DHJ 923 Benzoin 119-53-9 CEFHJ 924 (E)-1,2,4-trimethoxy-5-(prop-1-en-1- 2883-98-9 BCFGJK yl)benzene 925 alpha,alpha,6,6-tetramethyl 33885-52-8 BDFHJK bicyclo[3.1.1]hept-2-ene-propanal 926 7-epi-sesquithujene 159407-35-9 DEFHJKL 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK hexamethylindan 928 3-Methylphenethyl alcohol 1875-89-4 BCEFHIK 929 3,6-Nonadien-1-ol 76649-25-7 ACEFHK 930 2-Tridecenal 7774-82-5 BDFHJK 933 Patchouli alcohol 5986-55-0 DEFHIJK 937 p-Cresyl isobutyrate 103-93-5 BDHJK 939 p-Cresyl n-hexanoate 68141-11-7 DEFHJK 941 5-hexyl-4-methyldihydrofuran- 67663-01-8 BDEFHIJKL 2(3H)-one 942 Ethyl (2Z,4E)-deca-2,4-dienoate 3025-30-7 BDEFHJK 943 Pelargene 68039-40-7 DEFHJK 945 2-cyclohexylidene-2- 10461-98-0 DFHJK phenylacetonitrile 946 Perillaldehyde 2111-75-3 ACHIJK 947 Perillyl acetate 15111-96-3 DFHJK 948 Perillyl alcohol 536-59-4 CHIJK 950 (2-isopropoxyethyl)benzene 68039-47-4 ACEFHJKL 951 Ethyl (2Z,4E)-deca-2,4-dienoate 313973-37-4 BDEFHJK 953 (2-(cyclohexyloxy)ethyl)benzene 80858-47-5 DEFHJK 954 Phenethyl 2-methylbutyrate 24817-51-4 DEFHJK 955 Phenethyl alcohol 60-12-8 BCEFGIK 959 Phenethyl phenylacetate 102-20-5 DHJ 962 Phenoxanol 55066-48-3 DEFHJK 965 Phenyl benzoate 93-99-2 DFHJK 967 Phenyl ethyl benzoate 94-47-3 DHJ 969 Phenylacetaldehyde ethyleneglycol 101-49-5 BCEFGIK acetal 973 2-(6,6-dimethylbicyclo[3.1.1]hept-2- 30897-75-7 ACFHIJKL en-2-yl)acetaldehyde 974 Pinocarveol 5947-36-4 BCEFGIJKL 976 Piperonyl acetone 55418-52-5 CEFGJ 978 3a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK methanoinden-6-yl pivalate 980 (4aR,8aS)-7-methyloctahydro-1,4- 41724-19-0 CEFGJKL methanonaphthalen-6(2H)-one 982 p-Menth-3-en-1-ol 586-82-3 BCGIJK 985 (E)-3,3-dimethyl-5-(2,2,3- 107898-54-4 DHJK trimethylcyclopent-3-en-1-yl)pent-4- en-2-ol 988 1-methyl-4-(4-methylpent-3-en-1- 52474-60-9 DFHJK yl)cyclohex-3-ene-1-carbaldehyde 993 Propylene glycol 57-55-6 ACEFGIKL 998 p-Tolyl phenylacetate 101-94-0 DFHJ 1000 Ethyl 2,4,7-decatrienoate 78417-28-4 BDEFHJK 1003 2-benzyl-4,4,6-trimethyl-1,3-dioxane 67633-94-7 DEFHJK 1006 2,4-dimethyl-4- 82461-14-1 BDEFHJK phenyltetrahydrofuran 1007 (2R,4a′R,8a′R)-3,7′-dimethyl- 41816-03-9 DEFHJK 3′,4′,4a′,5′,8′,8a′-hexahydro-1′H- spiro[oxirane-2,2′- [1,4]methanonaphthalene] 1008 (Z)-6-ethylideneoctahydro-2H-5,8- 93939-86-7 BCEFHJKL methanochromene 1009 2-((S)-1-((S)-3,3- 236391-76-7 DFHJ dimethylcyclohexyl)ethoxy)-2- oxoethyl propionate 1010 Methyl 2,2-dimethyl-6- 81752-87-6 ADHIJKL methylenecyclohexane-1-carboxylate 1012 2-methyl-5-phenylpentan-1-ol 25634-93-9 DEFHJK 1016 4-methyl-2-phenyl-3,6-dihydro-2H- 60335-71-9 BCEFGJK pyran 1020 Sabinol 471-16-9 BCEFHIJKL 1021 Safrole 94-59-7 BCEFHK 1022 2,2,7,9-tetramethylspiro(5.5)undec- 502847-01-0 DHIJK 8-en-1-one 1023 3-methyl-5-(2,2,3- 65113-99-7 DEFHJK trimethylcyclopent-3-en-1-yl)pentan- 2-ol 1024 (Z)-2-ethyl-4-(2,2,3- 28219-61-6 DEFHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1025 (E)-2-methyl-4-(2,2,3- 28219-60-5 CHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1026 5-methoxyoctahydro-1H-4,7- 86803-90-9 CHJK methanoindene-2-carbaldehyde 1027 5-methoxyoctahydro-1H-4,7- 193425-86-4 CHJK methanoindene-2-carbaldehyde 1028 Sclareol 515-03-7 DEFHJ 1029 Sclareol oxide 5153-92-4 DEFHJK 1031 Selina-3,7(11)-diene 6813-21-4 DEFHJKL 1032 2-(1-(3,3- 477218-42-1 DEFHJ dimethylcyclohexyl)ethoxy)-2- methylpropyl cyclopropanecarboxylate 1033 3-(4-isobutylphenyl)-2- 6658-48-6 DHJK methylpropanal 1035 Spathulenol 6750-60-3 DEFHJK 1036 Spirambrene 533925-08-5 BCEFHJK 1037 Spirodecane 6413-26-9 BCEFGIJKL 1038 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en- 224031-70-3 DGJK 1-one 1042 2-(4-methylthiazol-5-yl)ethan-1-ol 137-00-8 CGIKL 1043 2-(heptan-3-yl)-1,3-dioxolane 4359-47-1 ACEFHIJKL 1045 (Z)-dodec-4-enal 21944-98-9 BDFHJK 1046 tau-Cadinol 5937-11-1 DEFHJK 1047 tau-Muurolol 19912-62-0 DEFHJK 1053 Tetrahydrojasmone 13074-63-0 BDFHIJKL 1057 2,6,10,10-tetramethyl-1- 36431-72-8 BDFHIJKL oxaspiro[4.5]dec-6-ene 1059 Thiomenthone 38462-22-5 BDEFHIJKL 1060 Thujopsene 470-40-6 BDEFGJKL 1062 Thymol methyl ether 1076-56-8 ADHIJKL 1063 1-(2,2,6-trimethylcyclohexyl)hexan- 70788-30-6 DEFHJK 3-ol 1064 trans,trans-2,4-Nonadienal 5910-87-2 ACHKL 1065 trans,trans-Farnesol 106-28-5 DEFHJK 1066 trans-2,cis-6-Nonadienal 557-48-2 ACHKL 1067 trans-2-Decenal 3913-81-3 ADHKL 1070 trans-2-Nonen-1-al 18829-56-6 ADHKL 1072 trans-3,cis-6-nonadienol 56805-23-3 ACEFHK 1073 trans-4-Decen-1-al 65405-70-1 ADHKL 1075 trans-ambrettolide 51155-12-5 DGJ 1077 trans-beta-ocimene 13877-91-3 ADGIKL 1078 trans-beta-Ocimene 3779-61-1 ADGIKL 1082 trans-Geraniol 106-24-1 BCHIK 1083 trans-Hedione 2570-03-8 DFHJK 1085 7-(1,1-Dimethylethyl)-2H-1,5- 195251-91-3 CEFHJ benzodioxepin-3(4H)-one 1089 Tricyclone 68433-81-8 DEFHJK 1090 Tridecyl alcohol 112-70-9 DEFGJK 1091 Triethyl citrate 77-93-0 CEFGJ 1093 Methyl 2-((1-hydroxy-3- 144761-91-1 DFHJ phenylbutyl)amino)benzoate 1095 1-((2E,5Z,9Z)-2,6,10- 28371-99-5 DHJK trimethylcyclododeca-2,5,9-trien-1- yl)ethan-1-one 1097 Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 BDEFHJK 2h-indeno(4,5-b)furan 1099 13-methyl oxacyclopentadec-10-en- 365411-50-3 DEFHJK 2-one 1102 Undecanal 112-44-7 BDHJK 1104 (E)-4-methyldec-3-en-5-ol 81782-77-6 BDEFHIJK 1105 Valencene 4630-07-3 BDEFHJK 1107 Valerianol 20489-45-6 DEFHJK 1111 Vanillin isobutyrate 20665-85-4 CHJ 1113 Vaniwhite ® 5533-03-9 CGIK 1116 (Z)-2-methyl-4-(2,6,6- 68555-62-4 BDFHJK trimethylcyclohex-2-en-1-yl)but-2- enal 1117 Methyl 2,4-dihydroxy-3,6- 4707-47-5 CGIJ dimethylbenzoate 1120 1-methoxy-3a,4,5,6,7,7a-hexahydro- 27135-90-6 ACEFHJKL 1H-4,7-methanoindene 1121 Methyl (Z)-2-((3-(4-(tert- 91-51-0 DFHJ butyl)phenyl)-2- methylpropylidene)amino)benzoate 1125 (Z)-hex-3-en-1-yl isobutyrate 41519-23-7 ADEFHJKL 1126 Vertacetal 5182-36-5 BCFHJK 1129 1-((3R,3aR,7R,8aS)-3,6,8,8- 32388-55-9 DHJK tetramethyl-2,3,4,7,8,8a-hexahydro- 1H-3a,7-methanoazulen-5-yl)ethan- 1-one 1131 Methyl (Z)-2-(((2,4- 68738-99-8 DEFHJ dimethylcyclohex-3-en-1- yl)methylene)amino)benzoate 1135 Vetiverol 89-88-3 CEFHIJK 1136 Vetivert Acetate 117-98-6 DEFHJK 1137 Decahydro-3H-spiro[furan-2,5′- 68480-11-5 DEFGJKL [4,7]methanoindene] 1138 (2Z,6E)-nona-2,6-dienenitrile 67019-89-0 ACEFHKL 1139 (Z)-cyclooct-4-en-1-yl methyl 87731-18-8 BCHJKL carbonate 1140 (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJK tetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 1142 3,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJ tetrahydronaphthalene-2-carbonitrile 1143 (1S,2S,3S,5R)-2,6,6- 133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]heptane- 3,1′-cyclohexan]-2′-en-4′-one 1144 1′,1′,5′,5′-tetramethylhexahydro- 154171-76-3 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′- [2,4a]methanonaphthalene] 1145 1′,1′,5′,5′-tetramethylhexahydro- 154171-77-4 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′- [2,4a]methanonaphthalene] K 1146 4-(4-hydroxy-3- 122-48-5 CEFGJ methoxyphenyl)butan-2-one 1147 (1R,8aR)-4-isopropyl-1,6-dimethyl- 41929-05-9 DEFHJKL 1,2,3,7,8,8a-hexahydronaphthalene 1148 4,5-epoxy-4,11,11-trimethyl-8- 1139-30-6 DEFHJK methylenebicyclo(7.2.0)undecane 1149 1,3,4,6,7,8alpha-hexahydro-1,1,5,5- 23787-90-8 DEFHIJK tetramethyl-2H-2,4alpha- methanophtalen-8(5H)-one

TABLE 2 List of materials with at least one MORV greater than 5 to 10 Num- CAS Comment ber Material Name Number Code 2 2,4-dimethyl-2-(5,5,8,8-tetramethyl- 131812-67-4 DFHJ 5,6,7,8-tetrahydronaphthalen-2-yl)- 1,3-dioxolane 23 3a,5,6,7,8,8b-hexahydro- 823178-41-2 DEFHJK 2,2,6,6,7,8,8-heptamethyl-4H- indeno(4,5-d)-1,3-dioxole 141 2,4-dimethyl-4,4a,5,9b- 27606-09-3 CEFHJK tetrahydroindeno[1,2-d][1,3]dioxine 185 (1-methyl-2-((1,2,2- 198404-98-7 DEFHJK trimethylbicyclo[3.1.0]hexan-3- yl)methyl)cyclopropyl)methanol 227 Isobornylcyclohexanol 68877-29-2 DEFHJK 230 Isobornyl cyclohexanol 66072-32-0 DEFHJK 246 Indol/Hydroxycitronellal Schiff base 67801-36-9 DEFHJ 248 Hydroxymethyl isolongifolene 59056-64-3 DEFHJK 343 8,8-dimethyl-3a,4,5,6,7,7a- 76842-49-4 DEFHJK hexahydro-1H-4,7-methanoinden-6- yl propionate 359 (E)-4-((3aR,4R,7R,7aR)- 501929-47-1 DEFHJK 1,3a,4,6,7,7a-hexahydro-5H-4,7- methanoinden-5-ylidene)-3- methylbutan-2-ol 565 Cedryl methyl ether 19870-74-7 BDEFHJK 631 beta-Copaene 18252-44-3 BDEFHJKL 659 2′-isopropyl-1,7,7- 869292-93-3 BDEFHJK trimethylspiro[bicyclo[2.2.1]heptane- 2,4′-[1,3]dioxane] 674 (4aR,5R,7aS,9R)-2,2,5,8,8,9a- 211299-54-6 DEFHJK hexamethyloctahydro-4H-4a,9- methanoazuleno[5,6-d][1,3]dioxole 678 (3S,5aR,7aS,11aS,11bR)-3,8,8,11a- 57345-19-4 DEFHJ tetramethyldodecahydro-5H-3,5a- epoxynaphtho[2,1-c]oxepine 679 2,2,6,6,7,8,8-heptamethyldecahydro- 476332-65-7 DEFHJK 2H-indeno[4,5-b]furan 715 alpha-Cedrene epoxide 13567-39-0 BDEFHJK 758 Acetoxymethyl-isolongifolene 59056-62-1 DEFHJK (isomers) 1028 Sclareol 515-03-7 DEFHJ 1097 Decahydro-2,6,6,7,8,8-hexamethyl- 338735-71-0 DEFHJK 2h-indeno(4,5-b)furan

TABLE 3 List of materials with at least one MORV from 0.5 to less than 1 Number Material Name CAS Number Comment Code 12 1-ethoxy-4-(tert- 181258-89-9 ADEFHJK pentyl)cyclohexane 19 (3Z)-1-(2-buten-1-yloxy)-3- 888744-18-1 ADEFHJKL hexene 20 4-(2-methoxypropan-2-yl)-1- 14576-08-0 ADHIJKL methylcyclohex-1-ene 24 O-Methyl linalool 60763-44-2 ADHIJKL 26 o-Methoxycinnamaldehyde 1504-74-1 ACHK 27 Octanal, 3,7-dimethyl- 25795-46-4 ADGIJKL 53 3,3-Dimethyl-5(2,2,3- 329925-33-9 CEFHJ Trimethyl-3-Cyclopenten- 1yl)-4-Penten-2-ol 54 n-Hexyl salicylate 6259-76-3 DEFHJ 55 n-Hexyl 2-butenoate 19089-92-0 ADEFHJKL 59 Neryl Formate 2142-94-1 BCEFHJK 72 Methyl-beta-ionone 127-43-5 DHJK 73 Myroxide 28977-57-3 ADGIJKL 81 (E)-3,7-dimethylocta-4,6- 18479-54-4 BCEFGIJK dien-3-ol 84 (Z)-hex-3-en-1-yl 188570-78-7 BCEFHIKL cyclopropanecarboxylate 96 Methyl phenyl carbinyl 120-45-6 BCHJK propionate 97 Methyl phenylacetate 101-41-7 ACEFHIKL 107 2-methyl-6- 91069-37-3 BCEFGIKL oxaspiro[4.5]decan-7-one 111 Methyl geraniate 2349-14-6 BCHJKL 115 2-ethoxy-4- 5595-79-9 CFGK (methoxymethyl)phenol 116 Methyl 40203-73-4 ACEFHIKL cyclopentylideneacetate 125 Methoxymelonal 62439-41-2 ACGIJK 133 ((1s,4s)-4- 13828-37-0 BDEFHIJK isopropylcyclohexyl)methanol 147 Linalyl propionate 144-39-8 BDFHJK 150 Linalyl formate 115-99-1 ACFHJK 151 Linalyl butyrate 78-36-4 BDEFHJK 154 Linalyl acetate 115-95-7 BDHJK 157 Linalool 78-70-6 BCEFGIJK 163 (Z)-hex-3-en-1-yl methyl 67633-96-9 ACEFGKL carbonate 166 Lepidine 491-35-0 BCEFHIKL 169 L-Carvone 6485-40-1 ACGIJKL 181 Khusinil 75490-39-0 DHJK 191 Isoraldeine 1335-46-2 BDHIJK 194 Isopropylvinylcarbinol 4798-45-2 ACGIKL 198 Isopropyl 2-methylbutyrate 66576-71-4 ACEFGIJKL 201 Isopentyrate 80118-06-5 ADEFGIJKL 204 Isononyl acetate 40379-24-6 BDEFHJKL 205 Isononanol 27458-94-2 BDEFGIKL 213 Isoeugenyl acetate 93-29-8 CFHJK 214 Isoeugenol 97-54-1 CEFHIK 232 Isoborneol 124-76-5 ACEFHIJKL 237 Isoamyl octanoate 2035-99-6 DEFHJK 239 Isoamyl isobutyrate 2050-01-3 ACEFGIJKL 255 Hydrocinnamic acid 501-52-0 CEFHIK 258 Hydratopic alcohol 1123-85-9 BCEFHIK 264 Hexyl propanoate 2445-76-3 ADEFHIKL 270 Hexyl butyrate 2639-63-6 BDEFHJKL 273 Hexyl 2-methylbutanoate 10032-15-2 BDEFHJKL 275 Hexyl 2-furoate 39251-86-0 DEFHJK 282 Heptyl alcohol 111-70-6 ACEFGIKL 283 Heptyl acetate 112-06-1 ADEFHKL 284 Heptaldehyde 111-71-7 ACHIKL 287 Heliotropin 120-57-0 BCGIK 302 Geranyl nitrile 5146-66-7 BCEFHKL 306 Geranyl formate 105-86-2 BCEFHJK 308 Geranyl caprylate 51532-26-4 DEFHJ 310 Geranyl benzoate 94-48-4 DFHJ 312 Geranial 141-27-5 ACHIKL 314 N,2-dimethyl-N- 84434-18-4 BCEFHJK phenylbutanamide 319 gamma-Terpinene 99-85-4 ADEFGIJKL 346 2-(sec-butyl)cyclohexan-1- 14765-30-1 ADFHIKL one 354 3-(2-ethylphenyl)-2,2- 67634-14-4 BDHJK dimethylpropanal 355 2-(tert-butyl)cyclohexyl ethyl 67801-64-3 BDFHJK carbonate 365 2-(tert-butyl)cyclohexyl ethyl 81925-81-7 ACFHIKL carbonate 366 Fenchyl alcohol 1632-73-1 ACGIJKL 376 Eucalyptol 470-82-6 ADEFGIJKL 379 Ethyl vanillin acetate 72207-94-4 CHJ 387 Ethyl octanoate 106-32-1 BDEFHJKL 400 Ethyl cinnamate 103-36-6 BCEFHK 412 Ethyl 2- 2511-00-4 BDFHIJKL (cyclohexyl)propionate 419 d-p-8(9)-Menthen-2-one 5524-05-0 ACGIJKL 420 4-methyl-2-phenyltetrahydro- 94201-73-7 BDEFHJK 2H-pyran 437 Dihydromyrcenol 18479-58-8 ADEFGIJK 438 Dihydrojasmone 1128-08-1 BCFHIJKL 439 Dihydroisophorone 873-94-9 ACEFGIJKL 440 Dihydroeugenol 2785-87-7 CEFHIJK 442 Dihydrocoumarin 119-84-6 BCGIKL 443 Dihydrocarvone 7764-50-3 ACGIJKL 447 Dihydro-alpha-terpinyl 80-25-1 BDEFHIJKL acetate 448 Dihydro-alpha-ionone 31499-72-6 BDHIJK 454 Dibenzyl ether 103-50-4 DEFHJK 455 Dibutyl o-phthalate 84-74-2 DEFHJ 469 2-pentylcyclopentan-1-one 4819-67-4 BDFHIKL 472 Decyl anthranilate 18189-07-6 DEFHJ 477 Methyl (1s,4s)-1,4- 23059-38-3 ADEFHIJKL dimethylcyclohexane-1- carboxylate 481 Cyclohexylethyl acetate 21722-83-8 BDEFHJKL 492 Creosol 93-51-6 BCHIK 495 Cosmene 460-01-5 ADEFGIKL 496 4-cyclohexyl-2-methylbutan- 83926-73-2 BDEFGIJK 2-ol 504 2-benzyl-2-methylbut-3- 97384-48-0 BDHJK enenitrile 509 Citronellyl nitrile 51566-62-2 BCEFGIKL 510 Citronellyl phenylacetate 139-70-8 DFHJ 512 Citronellyl formate 105-85-1 BCEFGJKL 515 Citronellyl benzoate 10482-77-6 DFHJ 517 Citronellol 106-22-9 BCHIJKL 518 Citronellal 106-23-0 ACHIJKL 522 Citral 5392-40-5 ACHIKL 525 cis-Pinane 6876-13-7 ADEFGIJKL 526 (Z)-3-methyl-2-(pent-2-en-1- 488-10-8 BCHIJKL yl)cyclopent-2-en-1-one 528 cis-iso-Eugenol 5912-86-7 CEFHIK 535 cis-3-Hexenyl valerate 35852-46-1 BDEFHJKL 536 cis-3-Hexenyl tiglate 67883-79-8 BDEFHJK 538 cis-3-Hexenyl propionate 33467-74-2 ACEFHIKL 540 cis-3-Hexenyl butyrate 16491-36-4 ADEFHJKL 542 cis-3-Hexen-1-ol 928-96-1 ACEFHIKL 547 cis-2-Hexenol 928-94-9 ACEFHIKL 549 Cinnamyl nitrile 4360-47-8 ACEFGIK 554 Cinnamic aldehyde 104-55-2 ACHIK 556 Cinnamyl nitrile 1885-38-7 ACEFGIK 557 Chloroxylenol 88-04-0 BCHIJK 575 Carvacrol 499-75-2 DHIJK 576 Carvone 99-49-0 ACGIJKL 579 Carbitol 111-90-0 BCEFGIK 583 Caproyl alcohol 111-27-3 ACEFGIKL 585 2-(2,2,3-trimethylcyclopent-3- 15373-31-6 ACGIJKL en-1-yl)acetonitrile 588 Camphor 76-22-2 ACEFGIJKL 602 (E)-2-methyl-4-(2,6,6- 3155-71-3 DHJK trimethylcyclohex-1-en-1- yl)but-2-enal 605 Borneol 507-70-0 ACEFHIJKL 617 beta-Pinene epoxide 6931-54-0 ACEFGIJKL 619 beta-Phellandrene 555-10-2 ADEFGIJKL 640 Benzylacetone 2550-26-7 ACEFGIK 641 Benzyl salicylate 118-58-1 DFGJ 645 Benzyl isovalerate 103-38-8 BDEFHJK 647 Benzyl isobutyrate 103-28-6 BCHJK 651 Benzyl butyrate 103-37-7 BCEFHJK 652 Benzyl alcohol 100-51-6 ACEFGIKL 662 1-(3,3- 25225-08-5 ADEFHIJKL dimethylcyclohexyl)ethyl formate 664 Anisyl acetate 104-21-2 BCEFGK 665 Anisyl formate 122-91-8 BCEFGK 667 Anethole 104-46-1 ACEFHK 672 Amyl benzoate 2049-96-9 DEFHJK 687 alpha-Terpinyl acetate 80-26-2 BDHJK 699 alpha-methyl- 10528-67-3 BDEFHIK cyclohexanepropanol 701 alpha-methyl cinnamaldehyde 101-39-3 ACHIK 703 alpha-Isomethylionone 127-51-5 BDHIJK 740 2,5-Dimethyl-4-methoxy- 4077-47-8 ACEFGIJKL 3(2H)-furanone 743 Allyl phenoxyacetate 7493-74-5 BCGK 744 Allyl Phenethyl ether 14289-65-7 ACEFHK 745 Allyl heptanoate 142-19-8 ADEFHJKL 755 N-ethyl-N-(m- 179911-08-1 CEFHJK tolyl)propionamide 760 3-hydroxybutan-2-one 513-86-0 ACEFGIKL 761 Acetoanisole 100-06-1 BCEFHIK 777 6-Methylquinoline 91-62-3 BCEFHIKL 779 6,8-Diethyl-2-nonanol 70214-77-6 BDEFGIJKL 784 5-Methyl-3-heptanone 541-85-5 ACFGIKL 789 4-Vinylphenol 2628-17-3 BCHIK 796 4-hydroxy-3-methoxy- 458-36-6 CH cinnamaldehyde 797 4-Ethylguaiacol 2785-89-9 CEFHIK 799 4-Damascol 4927-36-0 BDFHJK 808 3-methyl-4-phenylpyrazole 13788-84-6 CEFHK 810 3-Methyl-1,2- 765-70-8 ACEFGIKL cyclopentanedione 811 3-Methoxy-5-methylphenol 3209-13-0 BCHIK 812 3-Methoxy-3-Methyl Butanol 56539-66-3 ACGIKL 817 3-Hexenol 544-12-7 ACEFHIKL 819 3,7-dimethyl-2-methylene-6- 22418-66-2 ADFHIJK octenal 820 3,7-dimethyl-1-octanol 106-21-8 BDEFGIJKL 832 2-Phenylethyl acetate 103-45-7 BCEFHK 835 2-Phenethyl propionate 122-70-3 BCEFHJK 836 2-Pentylcyclopentan-1-ol 84560-00-9 DEFHIKL 838 2-nonanone propylene glycol 165191-91-3 BDEFHJK acetal 845 2-Methoxy-3-(1- 24168-70-5 BCEFGIK methylpropyl)pyrazine 846 2-isopropyl-N,2,3- 51115-67-4 ACEFGIJK trimethylbutyramide 847 2-Isopropyl-5-methyl-2- 35158-25-9 ADFGIJKL hexenal 848 2-Isopropyl-4-methylthiazole 15679-13-7 ACHIJKL 851 2-Hexen-1-ol 2305-21-7 ACEFHIKL 858 2-Butoxyethanol 111-76-2 ACEFGIKL 875 1,4-Cineole 470-67-7 ADGIJKL 880 1-(2,6,6-Trimethyl-2- 43052-87-5 BDHIJK cyclohexen-1-yl)-2-buten-1- one 882 (Z)-3-hepten-1-yl acetate 1576-78-9 ACEFHKL 883 (S)—(1R,5R)-4,6,6- 1196-01-6 ACEFGIJKL trimethylbicyclo[3.1.1]hept-3- en-2-one 888 (R)-(−)-Linalool 126-91-0 BCEFGIJK 889 (l)-Citronellal 5949-05-3 ACHIJKL 891 (d)-Citronellal 2385-77-5 ACHIJKL 899 (+)-Citronellol 1117-61-9 BCHIJKL 900 (−)-Citronellol 7540-51-4 BCHIJKL 901 (+)-alpha-Pinene 7785-70-8 ADEFGIJKL 902 (+)-Carvone 2244-16-8 ACGIJKL 903 (−)-alpha-Pinene 7785-26-4 ADEFGIJKL 904 Methyl 2-methylbutyrate 868-57-5 ACEFGIKL 909 Hexyl tiglate 16930-96-4 BDEFHJKL 918 Allyl 2- 68901-15-5 CHJK (cyclohexyloxy)acetate 921 1,5- 75147-23-8 CFHIJK dimethylbicyclo[3.2.1]octan- 8-one oxime 931 alpha-acetoxystyrene 2206-94-2 ACEFHIK 940 p-Cymene 99-87-6 ADGIJKL 956 Phenethyl formate 104-62-1 ACEFHK 958 Phenethyl isobutyrate 103-48-0 DHJK 960 Phenethyl tiglate 55719-85-2 DHJK 971 Phenylethyl methacrylate 3683-12-3 DHJK 977 p- 4395-92-0 BDFHK Isopropylphenylacetaldehyde 981 1,2-dimethyl-3-(prop-1-en-2- 72402-00-7 BCEFGIJKL yl)cyclopentan-1-ol 983 p-Methoxyphenylacetone 122-84-9 BCEFHK 986 (2Z,5Z)-5,6,7-trimethylocta- 358331-95-0 ADHIJKL 2,5-dien-4-one 987 p-Propyl anisole 104-45-0 ADEFHKL 994 p-t-butyl phenyl acetaldehyde 109347-45-7 BDHJK 995 p-tert-Amyl cyclohexanol 5349-51-9 BDEFHIJK 1001 Racemic alpha-Pinene 80-56-8 ADEFGIJKL 1002 4-(4-hydroxyphenyl)butan-2- 5471-51-2 CEFGIK one 1004 Rhodinol 141-25-3 BCHIJKL 1005 Ethyl (2,3,6- 93981-50-1 BDEFHJKL trimethylcyclohexyl)carbonate 1011 1-(3,3- 25225-10-9 ADHIJKL dimethylcyclohexyl)ethyl acetate 1017 S)-(+)-Linalool 126-90-9 BCEFGIJK 1018 Sabinene 3387-41-5 ADEFGIJKL 1019 Sabinene hydrate 546-79-2 ADEFGIJKL 1030 Propyl (S)-2-(tert- 319002-92-1 BDEFHJK pentyloxy)propanoate 1039 Spirolide 699-61-6 BCGIKL 1040 (Z)-5-methylheptan-3-one 22457-23-4 BCEFGIJKL oxime 1041 1-phenylethyl acetate 93-92-5 ACEFHIK 1051 Tetrahydrogeranial 5988-91-0 ADGIJKL 1052 Tetrahydroionol 4361-23-3 BDEFHIJK 1054 Tetrahydrolinalool 78-69-3 BDEFGIJKL 1055 Tetrahydrolinalyl acetate 20780-48-7 ADEFHJKL 1058 Ethyl (1R,6S)-2,2,6- 22471-55-2 ADEFHIJKL trimethylcyclohexane-1- carboxylate 1061 Thymol 89-83-8 BDHIJK 1069 trans-2-Hexenol 928-95-0 ACEFHIKL 1071 trans-2-tert- 5448-22-6 ACGIJKL Butylcyclohexanol 1074 trans-alpha-Damascone 24720-09-0 BDHIJK 1076 trans-Anethole 4180-23-8 ACEFHK 1079 trans-Cinnamic acid 140-10-3 CEFHK 1081 trans-Dihydrocarvone 5948-04-9 ACGIJKL 1084 trans-Isoeugenol 5932-68-3 CEFHIK 1088 Trichloromethyl phenyl 90-17-5 BDEFGJ carbinyl acetate 1098 2-mercapto-2-methylpentan- 258823-39-1 ACEFHIJKL 1-ol 1110 Vanillin acetate 881-68-5 CH 1112 Vanitrope 94-86-0 CEFHK 1115 2,2,5-trimethyl-5- 65443-14-3 BDFGIJKL pentylcyclopentan-1-one 1118 Veratraldehyde 120-14-9 BCGIK 1119 (1R,5R)-4,6,6- 18309-32-5 ACEFGIJKL trimethylbicyclo[3.1.1]hept-3- en-2-one 1122 Verdol 13491-79-7 ACGIJKL 1127 4-(tert-butyl)cyclohexyl 10411-92-4 BDEFHJK acetate 1128 4-(tert-butyl)cyclohexyl 32210-23-4 BDEFHJK acetate 1133 Vethymine 7193-87-5 CEFGK 1134 4-methyl-4-phenylpentan-2-yl 68083-58-9 BDFHJK acetate 1141 (Z)-1-((2- 292605-05-1 ADEFHKL methylallyl)oxy)hex-3-ene

TABLE 4 List of malodor reduction materials with ALL MORVs from 1 to 5 CAS Comment Number Material Name Number Code 7 3-methoxy-7,7-dimethyl-10- 216970-21-7 BDEFHJK methylenebicyclo[4.3.1]decane 14 Oxyoctaline formate 65405-72-3 DFHJK 39 2,2,6,8-tetramethyl- 103614-86-4 DEFHIJK 1,2,3,4,4a,5,8,8a-octahydro- naphthalen-1-ol 48 Nootkatone 4674-50-4 DHJK 183 Khusimol 16223-63-5 CEFHJK 199 Isopimpinellin 482-27-9 CFGJ 206 Iso3-methylcyclopentadecan-1-one 3100-36-5 DEFGJK 212 Isoeugenyl benzyl ether 120-11-6 DFHJ 215 1-((2S,3S)-2,3,8,8-tetramethyl- 54464-57-2 DHJK 1,2,3,4,5,6,7,8-octahydro- naphthalen-2-yl)ethan-1-one 229 Isobornyl isobutyrate 85586-67-0 BDEFHIJK 260 2,3-dihydro-3,3-dimethyl-1H- 173445-44-8 DHJK indene-5-propanal 261 3-(3,3-dimethyl-2,3-dihydro-1H- 173445-65-3 DHJK inden-5-yl)propanal 281 3a,4,5,6,7,7a-hexahydro-1H-4,7- 5413-60-5 CEFGJK methanoinden-6-yl acetate 329 gamma-Eudesmol 1209-71-8 DFHJK 335 4,6,6,7,8,8-hexamethyl- 1222-05-5 DEFHJK 1,3,4,6,7,8-hexahydro- cyclopenta[g]isochromene 353 (Z)-6-ethylideneoctahydro-2H-5,8- 69486-14-2 CEFGJK methanochromen-2-one 360 8,8-dimethyl-3a,4,5,6,7,7a- 171102-41-3 DEFHJK hexahydro-1H-4,7-methanoinden- 6-yl acetate 441 Octahydro-1H-4,7-methanoinden- 64001-15-6 DEFHJKL 5-yl acetate 484 3a,4,5,6,7,7a-hexahydro-1H-4,7- 113889-23-9 DEFHJK methanoinden-6-yl butyrate 487 3a,4,5,6,7,7a-hexahydro-1H-4,7- 67634-20-2 DEFHJK methanoinden-5-yl isobutyrate 488 Curzerene 17910-09-7 DHJK 501 (E)-cycloheptadec-9-en-1-one 542-46-1 DEFGJ 566 Cedryl formate 39900-38-4 BDEFHJK 567 Cedryl acetate 77-54-3 DEFHJK 569 Cedrol 77-53-2 DEFHJK 570 5-methyl-1-(2,2,3- 139539-66-5 DEFHJK trimethylcyclopent-3-en-1-yl)-6- oxabicyclo[3.2.1]octane 573 Caryophyllene alcohol acetate 32214-91-8 DEFHJK 574 Caryolan-1-ol 472-97-9 DEFHJK 603 Bornyl isobutyrate 24717-86-0 BDEFHIJK 616 beta-Santalol 77-42-9 DEFHJK 621 beta-Patchoulline 514-51-2 BDEFGJKL 624 beta-Himachalene Oxide 57819-73-5 BDFHJK 627 (2,2-dimethoxyethyl)benzene 101-48-4 DHJK 632 beta-Cedrene 546-28-1 BDEFGJKL 663 Anisyl phenylacetate 102-17-0 DFHJ 680 2,2,6,6,7,8,8-heptamethyldeca- 647828-16-8 ADEFHJK hydro-2H-indeno[4,5-b]furan 684 alpha-Vetivone 15764-04-2 DHJK 694 alpha-Santalol 115-71-9 DEFHJK 696 alpha-Patchoulene 560-32-7 ADEFHJKL 708 alpha-Gurjunene 489-40-7 BDEFHJKL 712 alpha-Eudesmol 473-16-5 DEFHJK 714 alpha-Cubebene 17699-14-8 ADEFHJKL 726 alpha-Agarofuran 5956-12-7 BDEFHJK 750 Allo-aromadendrene 25246-27-9 BDEFHJKL 764 Acetarolle 744266-61-3 DFHJK 775 7-eip-alpha-Eudesmol 123123-38-6 DEFHJK 776 7-Acetyl-1,1,3,4,4,6- 1506-02-1 DEFHJ hexamethyltetralin 788 5-Cyclohexadecenone 37609-25-9 DEFGJK 804 3-Thujopsanone 25966-79-4 BDEFHJK 872 10-epi-gamma-Eudesmol 15051-81-7 DFHJK 919 3a,4,5,6,7,7a-hexahydro-1H-4,7- 17511-60-3 CEFHJK methanoinden-6-yl propionate 927 5-Acetyl-1,1,2,3,3,6- 15323-35-0 DEFHJK hexamethylindan 933 Patchouli alcohol 5986-55-0 DEFHIJK 978 3a,4,5,6,7,7a-hexahydro-1H-4,7- 68039-44-1 DEFHJK methanoinden-6-yl pivalate 1007 (2R,4a′R,8a′R)-3,7′-dimethyl- 41816-03-9 DEFHJK 3′,4′,4a′,5′,8′,8a′-hexahydro-1′H- spiro[oxirane-2,2′- [1,4]methanonaphthalene] 1022 2,2,7,9-tetramethylspiro(5.5)undec- 502847-01-0 DHIJK 8-en-1-one 1024 (Z)-2-ethyl-4-(2,2,3- 28219-61-6 DEFHJK trimethylcyclopent-3-en-1-yl)but-2- en-1-ol 1027 5-methoxyoctahydro-1H-4,7- 193425-86-4 CHJK methanoindene-2-carbaldehyde 1029 Sclareol oxide 5153-92-4 DEFHJK 1035 Spathulenol 6750-60-3 DEFHJK 1038 1-(spiro[4.5]dec-7-en-7-yl)pent-4- 224031-70-3 DGJK en-1-one 1060 Thujopsene 470-40-6 BDEFGJKL 1089 Tricyclone 68433-81-8 DEFHJK 1107 Valerianol 20489-45-6 DEFHJK 1129 1-((3R,3aR,7R,8aS)- 32388-55-9 DHJK 3,6,8,8-tetramethyl-2,3,4,7,8,8a- hexahydro-1H-3a,7- methanoazulen-5-yl)ethan-1-one 1131 Methyl (Z)-2-(((2,4- 68738-99-8 DEFHJ dimethylcyclohex-3-en-1- yl)methylene)amino)benzoate 1136 Vetivert Acetate 117-98-6 DEFHJK 1137 Decahydro-3H-spiro[furan-2,5′- 68480-11-5 DEFGJKL [4,7]methanoindene] 1140 (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7- 552-02-3 DEFHJK tetramethyldecahydro-1H- cyclopropa[e]azulen-4-ol 1142 3,5,5,6,7,8,8-heptamethyl-5,6,7,8- 127459-79-4 DHJ tetrahydronaphthalene-2- carbonitrile 1143 (1S,2S,3S,5R)-2,6,6- 133636-82-5 DEFHJK trimethylspiro[bicyclo[3.1.1]- heptane- 3,1′-cyclohexan]-2′-en-4′-one 1144 1′,1′,5′,5′-tetramethylhexahydro- 154171-76-3 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′- [2,4a]methanonaphthalene] 1145 1′,1′,5′,5′-tetramethylhexahydro- 154171-77-4 DEFHJK 2′H,5′H-spiro[[1,3]dioxolane-2,8′- [2,4a]methanonaphthalene] K 1148 4,5-epoxy-4,11,11-trimethyl-8- 1139-30-6 DEFHJK methylenebicyclo(7.2.0)undecane 1149 1,3,4,6,7,8alpha-hexahydro- 23787-90-8 DEFHIJK 1,1,5,5-tetramethyl-2H-2,4alpha- methanophtalen-8(5H)-one

TABLE 5 List of malodor reduction materials with ALL MORVs greater than 5 to 10 Number Material Name CAS Number Comment Code 248 Hydroxymethyl 59056-64-3 BDEFHJK isolongifolene

TABLE 6 List of malodor reduction materials with ALL MORVs from 0.5 to less than 1 Number Material Name CAS Number Comment Code 472 Decyl anthranilate 18189-07-6 DEFHJ 526 (Z)-3-methyl-2-(pent- 488-10-8 BCHIJKL 2-en-1-yl)cyclopent- 2-en-1-one The materials in Tables 1-6 can be supplied by one or more of the following:

-   Firmenich Inc. of Plainsboro N.J. USA; International Flavor and     Fragrance Inc. New York, N.Y. USA; Takasago Corp. Teterboro, N.J.     USA; Symrise Inc. Teterboro, N.J. USA; Sigma-Aldrich/SAFC Inc.     Carlsbad, Calif. USA; and Bedoukian Research Inc. Danbury, Conn.     USA. -   Actual MORV values for each material listed in Tables 1-6 above are     as follows:

MORV value MORV MORV MORV Material for Value for Value for value for No. Equation a.) Equation b.) Equation c.) Equation d.) 1 0.548223914 0.876283261 1.22018588 −0.41901144 2 1.520311929 3.493450446 2.70657265 5.11342862 3 2.267801995 −0.81712657 0.43218875 1.595983683 4 −0.591063369 −0.48283571 0.16199804 1.210497701 7 1.437444636 2.131822996 3.81633465 1.318339345 9 2.151445882 −0.46189495 0.56090469 1.206360803 10 2.5733592 −0.58780849 1.39751471 1.258361951 11 3.052627325 1.008519135 −0.30475953 0.076323462 12 0.683776599 −0.01157903 0.82853231 0.326169402 13 1.549643217 1.809183231 0.70864531 2.22799611 14 2.82111224 2.339505033 1.240818 2.502429355 16 −0.31551128 −0.06816599 −0.04371934 2.76742389 17 −1.334904153 −0.5773313 1.75644798 1.898455724 18 −1.34154226 −2.63596666 0.06885109 1.001431671 19 0.15532384 0.09866097 0.64214585 −0.33330779 20 0.640261783 0.693213268 0.54637273 −0.97556029 21 0.936895364 −0.01521118 1.1697513 −0.63510809 22 1.158981042 1.115900089 −0.25859776 1.318200884 23 3.702361074 1.399942641 5.23954766 7.089933671 24 0.773874141 0.146848137 −1.05705847 −0.36193173 25 −1.016103969 −1.18967936 0.78064625 2.944710012 25 −1.016103969 −1.18967936 0.78064625 2.944710012 26 0.615085491 −0.00096877 −0.35697252 −0.18121401 27 0.70261974 −0.22197386 0.19710806 −2.37196477 28 1.366472597 −0.42546942 −0.59394241 −0.01417395 29 1.096043453 −1.02972898 −1.42167356 −0.63817943 30 1.143415203 −0.85945441 −0.41416913 2.499807942 31 1.138642907 −0.19595476 −0.54547769 −0.98828898 32 1.914414495 −0.64487788 0.63212987 1.166699371 33 0.314847366 1.848003955 −1.3905032 −0.62848261 34 −0.113542761 0.981530917 0.32824239 1.126524277 35 0.472382903 1.494882467 −0.07201236 −0.64589543 36 3.158513795 1.084094934 −0.00328981 −0.17786385 37 −1.055631982 2.240172964 0.92596118 2.105391988 38 3.158513795 0.592820874 −0.49326241 0.212867212 39 1.083800659 2.069727985 2.48170879 3.205630609 42 −0.103134861 0.267726008 −0.65350189 1.125952363 43 0.323961628 1.469295081 −0.52991193 0.797908251 47 1.703678841 1.348737095 2.00634162 −0.16505407 48 2.370955056 2.783472865 2.68240273 1.221864405 49 1.670680003 −0.41866107 −0.9173849 1.181929544 50 1.670680003 0.076369374 −0.49915943 −0.85392575 52 0.464485039 0.057512869 1.31230219 −0.11170276 53 0.626671823 −0.46954947 −0.33383736 0.277079201 54 0.666149043 0.009549925 −0.36226343 0.197224432 55 0.723473579 −1.50916383 −0.3848989 −0.71458778 57 0.381273227 1.192994109 1.65593321 −1.65739236 59 0.561360663 −0.17793966 −1.63250554 −0.7564969 61 0.146473611 −0.01535544 −0.16339658 1.738656146 62 1.20162032 −0.3576095 −0.10695443 1.322155191 63 1.084291915 2.258720158 −1.01245416 1.688283974 64 0.744770665 0.155243763 −1.8029919 1.023503542 65 0.972835178 2.797151284 1.53453579 0.857051645 67 2.069410561 0.021831924 0.37855159 −0.67235457 68 0.527636614 0.590831983 1.02843762 2.208655795 69 2.133965691 2.088998449 2.05751412 −0.9433713 70 0.327378959 0.996844599 1.23648533 −1.25138371 71 1.40093669 0.778222691 0.70401172 −0.24075444 72 0.617697349 −0.29503359 0.52404847 0.816184656 73 0.617792473 0.888976061 −0.45289639 0.615659244 74 1.437359024 1.548292147 0.10314807 −0.48982286 75 −1.970885622 3.398008325 4.08025266 −0.89948156 76 −1.32746934 −2.65365233 0.10272816 1.001614125 77 −2.541686116 3.295534192 3.75284227 0.404837808 78 −2.110794 2.109874746 3.13350902 −0.3880285 79 1.641162056 −0.28533994 1.53676145 0.652696023 80 1.594400214 0.283682865 2.23140233 1.111682021 81 0.176566806 −2.0786518 −2.13986952 0.981126964 82 0.980373758 −0.28813159 0.19404501 1.252564677 83 0.941833098 0.317310013 1.17606727 0.72992237 84 0.774237336 −0.27140727 0.72461427 −1.56415746 85 2.092976965 0.810644229 0.82999192 −0.62861806 91 2.061595915 −0.79930338 −0.18285395 −0.66898499 92 2.068748434 −0.24299896 0.07214682 −1.11758276 93 −0.08984279 −1.06025959 −0.05068694 1.560050105 96 0.927758203 −0.44129515 0.89190422 0.744284978 97 0.658667572 −0.68771072 0.46051026 −0.53120883 98 0.853222693 −0.2037738 −0.21414441 1.119784962 100 1.654535066 0.995056228 2.35139085 0.543654824 101 2.173663649 −0.11491477 1.48285148 1.698527571 102 2.066679492 −0.16785146 −0.84780149 0.12159477 103 2.335152618 −0.02866585 0.16993375 −0.98254522 104 2.760588276 0.459513599 1.35310241 0.000336976 105 1.654535066 3.654489674 3.13033965 0.544225478 106 1.750588169 −0.55853348 0.50257773 1.630011313 107 0.896789863 0.73615897 0.53011623 −0.54697747 108 0.532375207 0.826537134 1.21040312 0.690230716 109 2.407655187 0.742651426 1.80322099 0.271832856 110 0.54830833 2.916795026 1.40126098 0.690230716 111 0.939597126 −0.3750368 −1.23479972 −0.89366351 112 1.398518854 1.265740274 4.19618377 −0.12762692 113 1.415726941 0.086297006 3.43559555 −0.12964168 115 −1.557729423 −0.44113526 0.86330536 0.590708892 116 0.193562268 −1.58091165 0.83247813 −0.70978039 117 1.353510875 −0.59062398 −0.31776345 −0.3050158 119 0.830052725 2.28725579 0.38409695 0.219336109 120 1.261997955 −0.22622961 −1.04772194 2.028504137 122 1.505653628 −1.14748206 −0.19760084 −0.81373045 123 −0.658721962 −0.21299878 1.01439841 −0.76731016 125 0.749676998 −1.0761601 0.99563924 −1.15409002 126 0.931054384 −0.35067079 1.06050832 −1.62171794 128 −1.344832644 −0.09451199 1.19145467 1.621274257 130 1.153249538 1.605070708 2.38047907 −0.93842293 133 0.840066046 0.2323025 0.19054023 −0.26588341 134 0.522267541 0.824106618 1.83479545 0.364403434 135 2.142817887 2.142411243 −0.93830995 0.696522652 137 3.052627325 3.606270166 0.50445208 0.076323462 140 −0.153437637 0.246303216 0.76565758 1.800968868 141 2.067620311 1.424830396 2.33536931 7.644025075 142 0.98353103 1.950251373 2.50851828 −0.24499521 143 1.736969725 0.991537809 2.5691601 1.227191656 145 −0.211768579 1.46336231 −0.93580247 −1.48749449 146 1.912710035 0.926306508 1.81253333 0.494121361 147 0.675736703 0.99202385 −0.66034472 −0.66302669 148 0.757176542 1.83006252 0.16210659 0.243674851 149 0.438772371 1.091438092 −0.1560319 −0.61711642 150 0.84399938 0.675302022 −1.69771411 −0.73841711 151 0.633570539 0.988413715 −0.54991825 −0.43550324 152 0.911582356 1.974700218 −0.92267786 0.628660087 153 0.319053885 2.531735341 −0.39139184 0.734629224 154 0.714814512 0.690769753 −2.06588692 −0.73356628 155 −0.161798388 0.032135767 −0.13802086 1.734928461 156 −0.571799976 −1.32834264 −1.65346017 1.856689553 157 0.131224024 0.21510779 −1.70996346 0.964902175 158 1.201616145 −0.21158932 −0.8501176 −0.33330779 159 0.811289908 1.606645397 0.25352447 −1.83775117 159 0.811289908 1.606645397 0.25352447 −1.83775117 161 0.475184006 1.99305646 1.90910177 3.288337059 162 0.833030517 0.487189028 1.76798642 0.104378164 163 0.58993703 −0.46431772 0.74883588 −0.81090824 166 −0.121286831 −0.84664528 −0.32625341 0.778055656 167 0.846400186 −0.25922232 0.69248774 1.183696217 168 −0.310930833 −0.81048493 0.08527131 1.61831109 169 −0.2346025 0.890438419 −0.13206526 −0.83961838 170 −0.169223695 1.172917966 −0.11306441 0.099121666 174 2.863652137 0.236674094 −0.69038707 1.610215283 175 1.789769228 −0.31740428 −0.89529921 −0.09686469 176 2.625947334 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0.03050609 −1.62235977 904 −1.320466583 −2.49763118 0.9787365 −1.85867969 905 −0.386224123 −0.24799559 1.19406353 −1.61243489 908 1.878331515 1.287303121 0.11530502 1.132065786 909 0.614968453 −1.61827184 −0.80789799 −0.66927285 912 0.530707518 0.774109528 3.0396125 4.394775258 913 0.337020095 1.531840025 0.10544973 0.347450471 914 0.774589061 1.224705331 1.87994281 −0.11684579 916 −0.363201351 0.35600238 −1.20673542 2.056973054 918 0.153047955 0.702054562 0.76757802 0.096096862 919 2.891894151 2.295157633 3.54101626 1.984030826 920 1.292959895 0.808281618 2.92956952 2.204248324 921 −0.465333775 0.862817284 0.1439546 0.64701735 922 1.54265003 0.291977233 0.79089158 0.801314068 923 1.340862559 0.503169303 0.53213093 3.164832031 924 0.158497146 1.507280765 2.25315926 1.173977914 925 1.23162703 1.671882685 3.1838372 −0.22917041 926 2.608734063 3.080604939 −0.69726361 −0.36219702 927 1.879182741 3.409153142 2.48473663 3.409954437 928 −0.093106169 0.019939108 0.15932154 1.229749745 929 1.670680003 1.94609957 0.19633838 1.14825764 930 3.052627325 0.956834107 −0.29721209 −0.31007607 931 0.367631287 0.501274945 −1.31074554 −0.39331005 933 3.702965303 3.03402795 4.33630831 4.238503729 937 0.570011387 0.097928934 1.03350455 −0.13392581 939 1.801474588 0.770314085 0.70188154 0.22333959 940 −0.412950838 −0.1781887 0.50649275 −0.57215449 941 1.691004766 −0.42331992 0.66279648 0.0318465 942 1.451782586 −0.565439 −0.32447381 −0.43378383 943 1.188491672 0.120632811 0.20106994 3.078484746 945 1.214814941 0.806987609 0.47605587 1.372949466 946 0.561732094 1.21448402 0.35542793 −1.03704442 947 0.956565856 1.505997176 0.88115653 −0.60583691 948 0.592575441 1.383482681 0.93567635 1.058669028 950 0.343657562 −0.85471906 −0.21125904 1.184648122 951 1.236659334 3.828926809 1.57729777 −0.31942874 953 1.836389049 0.755753735 −0.36014522 1.262853393 953 1.836389049 0.755753735 −0.36014522 1.262853393 954 1.001653875 −0.85635082 0.89224781 −0.39245818 955 −0.122918652 −0.846489 −0.63367729 1.182912962 956 0.589766639 −0.9783487 −0.67638264 −0.38772225 958 0.715082397 −0.90020686 0.86817768 0.030652004 959 1.609198886 0.500797943 0.795571 0.908389449 960 0.952787327 −0.90555475 −0.17381408 0.06786323 962 1.836429446 0.208275147 −0.14300625 1.067462181 965 1.9158432 0.35211823 −1.02174589 0.625657932 967 1.383869627 0.274520494 −0.11659267 0.840327437 969 −0.445579934 −1.68867059 −0.5241276 2.233793943 971 0.736419048 0.409875189 −0.63140848 0.034514594 973 1.073465817 2.18418874 2.01361447 −0.93754437 974 0.130904221 1.882440008 1.85101055 0.112524893 976 −0.236681385 −0.09745533 0.1779313 2.08923366 977 0.904402612 0.936956925 0.87731788 0.102346515 978 2.201759817 2.123549573 3.7881607 2.358768953 980 1.784266982 1.845281076 3.42873622 −0.31098233 981 −0.225023329 0.087962898 −0.29053012 0.514272787 982 −0.231175318 −0.0159671 1.27391892 1.090487158 983 0.889215441 0.24321159 0.06877629 0.816247177 985 1.864634345 0.133647536 1.29803755 1.951226654 986 0.511450274 −2.33512445 −0.56246315 −0.42184152 987 0.847260813 0.368638185 0.4114346 0.219336109 988 1.596170102 1.592158381 0.30052357 0.283467897 993 −3.549941097 −2.6847861 −0.17502622 1.41034664 994 0.445802042 0.899738574 0.61059602 0.323194673 995 0.949498724 0.357111159 0.28371155 −0.14156488 998 2.197271885 1.578871826 0.90563334 1.056619658 998 2.197271885 1.578871826 0.90563334 1.056619658 1000 1.456120673 0.626173572 0.07683183 −0.43324035 1001 −0.440378333 0.918089245 0.03050609 −1.62235977 1002 0.819929066 0.459101825 −0.09227583 0.324342063 1003 1.64412453 −0.09343399 0.70197344 3.710273595 1004 0.796928207 0.459954079 −0.88538616 0.152000937 1005 0.044923203 −0.19994963 0.60082875 0.258347835 1006 −0.320452673 −0.33232662 −0.52315783 1.406273663 1007 4.040291133 3.474551355 3.57146797 3.565985043 1008 0.764519082 0.917635102 2.88258762 2.319622474 1009 −0.071112206 0.539362906 2.98048732 0.580423329 1010 −0.689737481 0.547928768 1.98805626 −0.76653376 1011 0.343668917 0.931501008 −0.05483722 0.395369857 1012 1.926713131 0.124849138 −0.09654906 1.126499382 1016 0.124247716 0.193102712 0.39003599 1.737670628 1017 0.131224136 0.21510779 −1.70996346 0.964902175 1018 0.499624069 0.962843507 0.77617619 −1.15296947 1019 0.813491983 0.322635656 0.02800396 0.599500927 1020 0.715468114 1.015469049 1.45994989 0.352548581 1021 −1.176339404 1.539767848 −0.14427147 1.389902738 1022 1.364966718 1.690570939 2.05914194 2.364375484 1023 2.154641091 0.800066339 0.85365652 0.965810338 1024 2.302280068 1.252164308 1.73414439 1.549538352 1025 1.878331515 1.287303121 0.11530502 1.132065786 1026 2.97722987 2.096441965 3.87172868 0.550274831 1027 2.474381478 1.950326182 3.81861867 1.366897355 1028 1.778414353 3.114931059 4.47690731 6.054314034 1029 3.672910795 2.760483725 3.26915034 3.042677588 1030 −0.604959715 −2.13584086 0.8687855 0.024144016 1031 2.012732245 2.293857161 0.54405555 1.261882121 1032 −1.086688867 0.953083194 2.92177054 0.876865185 1033 1.617520676 1.008017006 2.21183536 −0.1288484 1035 2.506372295 3.419954592 4.58206882 4.134341651 1036 −0.675805062 −0.15357004 0.94597719 3.966016669 1037 −0.275092569 −0.67687665 −0.52763797 1.489972106 1038 2.753559643 3.81185814 2.71344734 2.243351472 1039 0.65087433 0.026885305 −0.0153558 0.011870127 1040 0.141526548 −1.65455278 0.50170705 −1.90794 1041 0.458680435 −0.69730218 −0.48806249 0.586073092 1042 −0.513264812 −0.22001961 0.36339519 1.03208599 1043 −1.497887014 −1.76116109 −0.76634926 1.137002742 1045 2.863652137 1.96790869 0.43661485 −0.44756897 1046 0.981194248 1.73892162 2.21166953 2.738129365 1047 0.981194248 1.73892162 2.21166953 2.738129365 1051 0.70261974 −0.22197386 0.19710806 −2.37196477 1052 0.662126832 0.741436531 0.61672724 0.289359903 1053 0.87463644 −0.19717783 1.2664131 −0.4187507 1054 0.284558077 −1.46754925 −0.03124571 0.587227244 1055 0.885837831 −0.91907796 −0.45817355 −1.1936897 1057 0.790964847 1.387925398 −0.18370692 1.302393792 1058 −1.052897931 −0.85226912 0.90324527 −1.09684959 1059 −0.871565421 −0.17856476 1.51267137 −1.52734367 1060 3.311161199 3.074783921 2.10199297 1.822541682 1061 −0.655128061 0.497032417 0.92381279 −0.56348341 1062 −0.443129049 0.96200606 1.51641349 −0.22974864 1063 1.385675542 0.738759296 1.1677069 0.501211562 1064 1.670680003 −0.20756775 −0.73755051 −0.84924056 1065 1.43532227 1.656262941 −1.09448841 1.674272267 1066 1.670680003 1.284791101 0.14864516 −0.84985664 1067 2.237616041 0.345329863 −0.60597063 −0.71581056 1069 −0.24632881 −0.23975349 −0.01449288 0.574861147 1070 1.670680003 0.070165381 −0.64700996 −0.85055617 1071 −1.02687397 −0.36244273 0.13010074 0.535909448 1072 1.670680003 1.94609957 0.19633838 1.14825764 1073 2.237616041 1.438074134 0.31117554 −0.71786492 1074 −0.192632911 0.142411101 0.79310676 0.125548041 1075 0.909356011 0.368597887 1.03689838 1.001198751 1076 0.812238101 0.195908668 0.21564664 0.219336109 1077 0.325255266 1.131242708 −2.79377204 −0.62848261 1078 0.325255266 1.131242708 −2.79377204 −0.62848261 1079 0.85330799 −0.6855194 −0.90046979 −0.46415796 1081 −0.131519393 0.731836014 0.81604919 −1.29993979 1082 0.744770665 0.155243763 −1.8029919 1.023503542 1083 1.415726941 0.086297223 3.43559555 −0.12964168 1084 0.161304111 0.66712144 0.58401752 0.373809692 1085 −0.72863532 −0.2873027 2.21251376 3.003873022 1088 −1.1773616 −0.23258175 0.40529195 0.994988969 1089 2.769817302 1.661618789 3.97585272 1.059236597 1090 3.052627325 0.420821685 −0.57080756 1.751222205 1091 −3.379896722 −3.71174986 2.53586709 0.644702886 1093 0.72304265 1.667011476 2.53982093 2.7903213 1095 0.744219765 1.372184572 0.15852396 1.126053442 1097 4.407270402 2.670641491 5.02636153 5.361271976 1098 −1.85804837 −2.59071226 −0.46522239 0.655734646 1099 0.745797788 −0.20547378 4.27836342 4.646390386 1102 2.068748434 −0.24299896 0.07214682 −1.11758276 1104 1.018876287 0.025163067 −0.1106021 0.838914654 1105 2.387326861 3.865456674 2.2251199 0.728667998 1107 2.352582059 2.595496601 3.20492728 2.844590737 1110 0.302703712 0.599942142 −0.25637571 −0.03195517 1111 0.750930333 0.656784751 1.68326413 0.329846578 1112 −0.205527848 0.287622624 −0.00340777 0.59203719 1115 0.999825037 0.662221152 0.43571192 0.342558518 1116 0.873381263 1.544324176 0.13703728 −0.38172701 1117 −0.682983903 1.798204302 2.42110319 −0.39173951 1118 0.069769623 0.496895599 0.67857133 −0.14954441 1119 −0.671908804 −0.65984824 0.5238174 −0.85314111 1120 0.953790113 1.106552668 3.00006904 1.585038764 1121 −1.184630973 2.476138312 4.80971952 2.450646806 1122 −1.02687397 −0.36244273 0.13010074 0.535909448 1125 0.387315524 −0.36101406 1.14153708 −0.75303953 1126 1.021783831 −0.0070257 −0.14327539 3.954381426 1127 0.990592079 0.305612583 0.14155512 −0.29526854 1128 0.990592079 0.305612583 0.14155512 −0.29526854 1129 3.18966648 3.284362987 4.49398568 3.950809104 1131 1.650621055 1.545704806 2.37535081 1.259373143 1133 −1.519747805 −0.60804324 0.02746106 0.590708892 1134 0.815942067 −0.16126019 −0.54117238 0.613093526 1135 0.626973385 1.998305877 2.61706075 1.570404253 1136 2.812199484 1.353198146 2.05618426 1.869204406 1137 2.208307057 1.387136198 3.21521374 2.069795393 1138 1.670680003 1.316442078 0.14822999 −0.46985154 1139 1.408517438 0.890457374 1.24524408 0.685687797 1140 2.765860952 2.525539595 4.12464228 3.833744077 1141 −0.484394663 0.677713073 −0.22783646 −0.37267608 1142 2.54335679 4.298105601 3.36234238 2.684404542 1143 4.204367611 3.062126931 3.4234313 2.072899554 1144 2.479165229 3.226545885 4.65897152 4.952127235 1145 2.479158921 3.226545885 4.65897152 4.952127235 1146 0.774334025 1.075800774 1.06893156 1.011113116 1147 0.844648531 1.21935371 2.59138595 0.805938034 1148 2.906236436 1.550674121 3.56959167 2.832126896 1149 2.837627443 3.707154326 4.53384262 2.625871865 Particles

The malodor reduction materials can be practical for inclusion in particles. The particles can comprise about 30% to about 95% by weight of a carrier. The particles can comprise about 0.1% to about 30% by weight of a perfume. The particles can comprise about 0.00025% to about 30% by weight of a malodor agent. The particles can comprise about 0.001% to about 30% by weight of a malodor agent. The malodor agent can comprise one or more reduction materials having a Blocker Index of less than 3 or a Blocker Index average of 3 to about 0.001. The particles can have a mass between about 0.1 mg to about 5 g.

The malodor reduction materials can have a Fragrance Fidelity Index of from about Fragrance Fidelity Index of less than 3, more preferable less than about 2.5 even more preferably less than about 2 and still more preferably less than about 1and most preferably 0 or a Fragrance Fidelity Index average of 3 to about 0.001.

The particles can comprise a weight ratio of parts of malodor agent to perfume of from about 1:20,000 to about 3000:1, optionally from about 1:10,000 to about 1,000:1, optionally 5,000:1 to about 500:1, optionally from about 1:15 to about 1:1.

The particles can comprise one or more malodor reduction materials having a log P greater than 3, preferably greater than 3 but less than 8, preferably said one or more malodor reduction materials are selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114; 119; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 601; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143; 1144; 1145; 1147; 1148; 1149; Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097; Table 3 materials 1; 9; 12; 13; 19; 20; 21; 24; 25; 27; 32; 38; 54; 55; 59; 64; 68; 71; 72; 79; 81; 83; 85; 100; 105; 109; 111; 114; 119; 133; 134; 135; 137; 140; 142; 147; 148; 150; 151; 152; 153; 154; 157; 159; 162; 178; 181; 189; 191; 192; 195; 197; 204; 211; 228; 231; 233; 234; 237; 238; 242; 246; 252; 264; 270; 273; 275; 277; 283; 285; 289; 290; 292; 293; 295; 300; 301; 302; 306; 308; 310; 312; 319; 322; 325; 331; 333; 334; 336; 338; 339; 344; 346; 354; 355; 356; 358; 361; 362; 363; 370; 371; 372; 378; 381; 385; 387; 388; 390; 412; 413; 418; 420; 428; 429; 432; 437; 438; 444; 447; 448; 454; 455; 457; 461; 465; 467; 472; 477; 478; 479; 480; 481; 482; 495; 496; 497; 502; 503; 504; 509; 510; 512; 515; 517; 518; 522; 525; 529; 535; 536; 537; 540; 541; 544; 550; 557; 558; 559; 560; 561; 568; 571; 572; 575; 589; 592; 594; 599; 600; 602; 604; 609; 619; 620; 625; 626; 633; 641; 644; 645; 650; 653; 662; 667; 672; 673; 675; 676; 681; 686; 687; 693; 697; 698; 700; 703; 704; 706; 707; 716; 717; 718; 722; 725; 744; 745; 746; 757; 769; 771; 779; 782; 799; 806; 819; 820; 827; 828; 836; 838; 839; 847; 850; 875; 878; 879; 880; 881; 888; 889; 890; 891; 893; 899; 900; 901; 903; 909; 912; 914; 920; 922; 930; 939; 940; 941; 945; 947; 948; 953; 954; 958; 959; 960; 965; 967; 971; 986; 987; 994; 995; 998; 1000; 1001; 1003; 1005; 1008; 1009; 1010; 1011; 1017; 1018; 1023; 1031; 1032; 1046; 1047; 1051; 1052; 1053; 1054; 1055; 1057; 1058; 1061; 1062; 1063; 1074; 1075; 1076; 1082; 1088; 1093; 1095; 1099; 1102; 1104; 1105; 1115; 1116; 1120; 1127; 1128; 1134; 1135; 1141; 1147;1148, 1149, and mixtures thereof; optionally the malodor reduction materials are selected from the group consisting of Table 1 materials 1; 2; 3; 7; 9; 10; 11; 13; 14; 18; 21; 22; 23; 25; 28; 29; 30; 31; 32; 33; 35; 36; 38; 39; 47; 48; 49; 50; 52; 57; 62; 63; 64; 67; 68; 69; 71; 74; 75; 76; 77; 78; 79; 80; 83; 85; 91; 92; 93; 100; 101; 102; 103; 104; 105; 109; 114; 119; 120; 122; 123; 128; 134; 135; 137; 140; 142; 145; 148; 149; 152; 153; 158; 159; 161; 162; 174; 175; 176; 177; 178; 182; 183; 184; 185; 186; 189; 192; 195; 196; 197; 206; 208; 209; 210; 211; 212; 215; 221; 227; 228; 229; 230; 231; 233; 234; 238; 242; 243; 244; 246; 252; 253; 260; 261; 263; 267; 269; 271; 274; 276; 277; 280; 285; 289; 290; 292; 293; 294; 295; 296; 300; 301; 303; 307; 316; 317; 318; 322; 324; 325; 328; 329; 330; 331; 333; 334; 335; 336; 338; 339; 342; 343; 344; 349; 352; 356; 358; 359; 360; 361; 362; 363; 364; 368; 369; 370; 371; 372; 378; 381; 385; 386; 388; 390; 391; 397; 398; 413; 414; 416; 418; 421; 424; 426; 428; 429; 432; 441; 444; 449; 453; 457; 459; 461; 462; 463; 465; 466; 467; 468; 470; 471; 473; 475; 478; 479; 480; 482; 484; 486; 487; 488; 497; 498; 501; 502; 503; 505; 519; 520; 521; 524; 529; 532; 534; 537; 541; 544; 548; 550; 552; 558; 559; 560; 561; 562; 563; 565; 566; 567; 568; 569; 570; 571; 572; 573; 574; 577; 578; 582; 584; 589; 591; 592; 594; 599; 600; 601; 603; 604; 606; 607; 608; 609; 610; 611; 613; 614; 615; 616; 618; 620; 621; 624; 625; 626; 628; 631; 632; 633; 635; 644; 650; 653; 659; 660; 661; 663; 671; 673; 674; 675; 676; 677; 678; 679; 680; 681; 684; 686; 691; 692; 693; 694; 696; 697; 698; 700; 702; 704; 706; 707; 708; 709; 710; 711; 712; 713; 714; 715; 716; 717; 718; 719; 720; 721; 722; 723; 724; 725; 726; 727; 731; 741; 746; 750; 752; 754; 757; 758; 763; 766; 769; 770; 771; 774; 775; 776; 778; 781; 782; 788; 791; 800; 802; 804; 806; 814; 821; 826; 827; 828; 831; 837; 839; 840; 849; 850; 852; 856; 866; 868; 869; 870; 871; 872; 873; 876; 877; 878; 879; 881; 884; 885; 886; 890; 892; 893; 894; 905; 908; 912; 913; 914; 916; 919; 920; 922; 925; 926; 927; 930; 933; 939; 941; 942; 943; 945; 947; 948; 950; 951; 953; 954; 959; 965; 967; 973; 978; 985; 988; 998; 1000; 1003; 1006; 1007; 1008; 1009; 1010; 1016; 1022; 1023; 1024; 1025; 1028; 1029; 1031; 1032; 1033; 1035; 1038; 1045; 1046; 1047; 1053; 1057; 1060; 1062; 1063; 1065; 1067; 1070; 1073; 1075; 1077; 1078; 1082; 1089; 1090; 1093; 1095; 1097; 1099; 1102; 1104; 1105; 1107; 1116; 1120; 1121; 1126; 1129; 1131; 1135; 1136; 1137; 1138; 1140; 1142; 1143; 1144; 1145; 1147; 1148; 1149; Table 2 materials 2; 23; 185; 227; 230; 246; 248; 343; 359; 565; 631; 659; 674; 678; 679; 715; 758; 1028; 1097and mixtures thereof; optionally the malodor reduction materials are selected from the group consisting of Table 4 materials 7; 14; 39; 48; 183; 206; 212; 215; 229; 260; 261; 329; 335; 360; 441; 484; 487; 488; 501; 566; 567; 569; 570; 573; 574; 603; 616; 621; 624; 632; 663; 680; 684; 694; 696; 708; 712; 714; 726; 750; 775; 776; 788; 804; 872; 919; 927; 933; 978; 1007; 1022; 1024; 1029; 1035; 1038; 1060; 1089; 1107; 1129; 1131; 1136; 1137; 1140; 1142; 1143; 1144; 1145; 1148, 1149 Table 5 material 248 and mixtures thereof, optionally the malodor reduction materials are selected from the group consisting of Table 4 materials 261; 680; 788;1129, 1148, 1149 and mixtures thereof. All of the aforementioned odor reduction materials have a log P that is equal to or greater than 3, thus they deposit through the wash especially well. The more selective lists of malodor materials above can be practical for counteracting all of the key malodors.

In one aspect of said product, said malodor reduction materials are not selected from the group consisting of Table 1-3 malodor reduction materials 302; 288; 50; 157; 1017; 888; 64; 1054; 832; 375; 390; 745; 504; 505; 140; 1012; 498; 362; 103; 356; 1074; 908; 1127; 475; 918; 687; 611; 317; 9; 141; 550; 602; 913; 1005; 521; 10; 215; 370; 335; 378; 1121; 360; 565; 1136; 1129; 655; 369; 1065; 914; 757; 601; 478; 889; 891; 358; 973; 162; 554; 522; 312; 125; 26; 418; 92; 586; 1026; 218; 31; 828; 871; 829; 1066; 287; 269; 769; 701; 1118; 70; 946; 142; 109; 108 or mixtures thereof.

The malodor reduction materials can be unencapsulated. The malodor reduction materials can be encapsulated. The malodor agent can comprise one or more encapsulated malodor reduction materials and one or more unencapsulated malodor reduction materials. One or more of the malodor reduction materials can be provided in a delivery system. The delivery system can include a delivery system selected from the group consisting of polymer-assisted delivery, molecular assisted deliver, cyclodextrin deliver, starch encapsulated delivery, zeolite delivery, inorganic delivery, and combinations thereof.

The carrier can be or comprise a material selected from the group consisting of water soluble inorganic alkali metal salt, water-soluble alkaline earth metal salt, water-soluble organic alkali metal salt, water-soluble organic alkaline earth metal salt, water soluble carbohydrate, water-soluble silicate, water soluble urea, and any combination thereof. Alkali metal salts can be, for example, selected from the group consisting of salts of lithium, salts of sodium, and salts of potassium, and any combination thereof. Useful alkali metal salts can be, for example, selected from the group consisting of alkali metal fluorides, alkali metal chlorides, alkali metal bromides, alkali metal iodides, alkali metal sulfates, alkali metal bisulfates, alkali metal phosphates, alkali metal monohydrogen phosphates, alkali metal dihydrogen phosphates, alkali metal carbonates, alkali metal monohydrogen carbonates, alkali metal acetates, alkali metal citrates, alkali metal lactates, alkali metal pyruvates, alkali metal silicates, alkali metal ascorbates, and combinations thereof.

Alkali metal salts can be selected from the group consisting of, sodium fluoride, sodium chloride, sodium bromide, sodium iodide, sodium sulfate, sodium bisulfate, sodium phosphate, sodium monohydrogen phosphate, sodium dihydrogen phosphate, sodium carbonate, sodium hydrogen carbonate, sodium acetate, sodium citrate, sodium lactate, sodium tartrate, sodium silicate, sodium ascorbate, potassium fluoride, potassium chloride, potassium bromide, potassium iodide, potassium sulfate, potassium bisulfate, potassium phosphate, potassium monohydrogen phosphate, potassium dihydrogen phosphate, potassium carbonate, potassium monohydrogen carbonate, potassium acetate, potassium citrate, potassium lactate, potassium tartrate, potassium silicate, potassium, ascorbate, and combinations thereof. Alkaline earth metal salts can be selected from the group consisting of salts of magnesium, salts of calcium, and the like, and combinations thereof. Alkaline earth metal salts can be selected from the group consisting of alkaline metal fluorides, alkaline metal chlorides, alkaline metal bromides, alkaline metal iodides, alkaline metal sulfates, alkaline metal bisulfates, alkaline metal phosphates, alkaline metal monohydrogen phosphates, alkaline metal dihydrogen phosphates, alkaline metal carbonates, alkaline metal monohydrogen carbonates, alkaline metal acetates, alkaline metal citrates, alkaline metal lactates, alkaline metal pyruvates, alkaline metal silicates, alkaline metal ascorbates, and combinations thereof. Alkaline earth metal salts can be selected from the group consisting of magnesium fluoride, magnesium chloride, magnesium bromide, magnesium iodide, magnesium sulfate, magnesium phosphate, magnesium monohydrogen phosphate, magnesium dihydrogen phosphate, magnesium carbonate, magnesium monohydrogen carbonate, magnesium acetate, magnesium citrate, magnesium lactate, magnesium tartrate, magnesium silicate, magnesium ascorbate, calcium fluoride, calcium chloride, calcium bromide, calcium iodide, calcium sulfate, calcium phosphate, calcium monohydrogen phosphate, calcium dihydrogen phosphate, calcium carbonate, calcium monohydrogen carbonate, calcium acetate, calcium citrate, calcium lactate, calcium tartrate, calcium silicate, calcium ascorbate, and combinations thereof. Inorganic salts, such as inorganic alkali metal salts and inorganic alkaline earth metal salts, do not contain carbon. Organic salts, such as organic alkali metal salts and organic alkaline earth metal salts, contain carbon. The organic salt can be an alkali metal salt or an alkaline earth metal salt of sorbic acid (i.e., asorbate). Sorbates can be selected from the group consisting of sodium sorbate, potassium sorbate, magnesium sorbate, calcium sorbate, and combinations thereof.

The carrier can be or comprise a material selected from the group consisting of a water-soluble inorganic alkali metal salt, a water-soluble organic alkali metal salt, a water-soluble inorganic alkaline earth metal salt, a water-soluble organic alkaline earth metal salt, a water-soluble carbohydrate, a water-soluble silicate, a water-soluble urea, and combinations thereof.

The carrier or water soluble-soluble carrier can be selected from the group consisting of sodium chloride, potassium chloride, calcium chloride, magnesium chloride, sodium sulfate, potassium sulfate, magnesium sulfate, sodium carbonate, potassium carbonate, sodium hydrogen carbonate, potassium hydrogen carbonate, sodium acetate, potassium acetate, sodium citrate, potassium citrate, sodium tartrate, potassium tartrate, potassium sodium tartrate, calcium lactate, water glass, sodium silicate, potassium silicate, dextrose, fructose, galactose, isoglucose, glucose, sucrose, raffinose, isomalt, xylitol, candy sugar, coarse sugar, and combinations thereof. In one embodiment, the carrier or water-soluble carrier can be sodium chloride. In one embodiment, the carrier or water-soluble carrier can be table salt.

The carrier can be or comprise a material selected from the group consisting of sodium bicarbonate, sodium sulfate, sodium carbonate, sodium formate, calcium formate, sodium chloride, sucrose, maltodextrin, corn syrup solids, corn starch, wheat starch, rice starch, potato starch, tapioca starch, clay, silicate, citric acid carboxymethyl cellulose, fatty acid, fatty alcohol, glyceryl diester of hydrogenated tallow, glycerol, and combinations thereof.

The carrier can be selected from the group consisting of water soluble organic alkali metal salt, water soluble inorganic alkaline earth metal salt, water soluble organic alkaline earth metal salt, water soluble carbohydrate, water soluble silicate, water soluble urea, starch, clay, water insoluble silicate, citric acid carboxymethyl cellulose, fatty acid, fatty alcohol, glyceryl diester of hydrogenated tallow, glycerol, polyethylene glycol, and combinations thereof.

The carrier can be selected from the group consisting of polyvinyl alcohol, modified polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl alcohol/polyvinyl pyrrolidone, polyvinyl alcohol/polyvinyl amine, partially hydrolyzed polyvinyl acetate, polyalkylene oxide, polyethylene glycol, acrylamide, acrylic acid, cellulose, alkyl cellulosics, methyl cellulose, ethyl cellulose, propyl cellulose, cellulose ethers, cellulose esters, cellulose amides, polyvinyl acetates, polycarboxylic acids and salts, polyaminoacids or peptides, polyamides, polyacrylamide, copolymers of maleic/acrylic acids, polysaccharides, starch, modified starch, gelatin, alginates, xyloglucans, hemicellulosic polysaccharides, xylan, glucuronoxylan, arabinoxylan, mannan, glucomannan, galactoglucomannan, natural gums, pectin, xanthan, carrageenan, locus bean, arabic, tragacanth, polyacrylates, sulfonated polyacrylates, water-soluble acrylate copolymers, alkylhydroxy cellulosics, methylcellulose, carboxymethylcellulose sodium, modified carboxy-methylcellulose, dextrin, ethylcellulose, propylcellulose, hydroxyethyl cellulose, hydroxypropyl methylcellulose, maltodextrin, polymethacrylates, polyvinyl alcohol copolymers, hydroxypropyl methyl cellulose, and mixtures thereof. A water soluble carrier can be practical.

The particles can comprise from about 40% by weight to about 99% by weight of the particles of the carrier. The carrier can be polyethylene glycol.

The precursor material can comprise more than about 40% by weight polyethylene glycol having a weight average molecular weight from about 2000 to about 13000. Polyethylene glycol (PEG) has a relatively low cost, may be formed into many different shapes and sizes, minimizes unencapsulated perfume diffusion, and dissolves well in water. PEG comes in various weight average molecular weights. A suitable weight average molecular weight range of PEG includes from about 2,000 to about 13,000, from about 4,000 to about 12,000, alternatively from about 5,000 to about 11,000, alternatively from about 6,000 to about 10,000, alternatively from about 7,000 to about 9,000, alternatively combinations thereof. PEG is available from BASF, for example PLURIOL E 8000.

The particles can comprise more than about 40% by weight of the particles of PEG. The particles can comprise more than about 50% by weight of the particles of PEG. The particles can comprise more than about 60% by weight of the particles of PEG. The particles may comprise from about 65% to about 99% by weight of the composition of PEG. The particles may comprise from about 40% to about 99% by weight of the composition of PEG.

Alternatively, the particles can comprise from about 40% to less than about 90%, alternatively from about 45% to about 75%, alternatively from about 50% to about 70%, alternatively combinations thereof and any whole percentages or ranges of whole percentages within any of the aforementioned ranges, of PEG by weight of the particles.

Depending on the application, the particles can comprise from about 0.5% to about 5% by weight of the particles of a balancing agent selected from the group consisting of glycerin, polypropylene glycol, isopropyl myristate, dipropylene glycol, 1,2-propanediol, and PEG having a weight average molecular weight less than 2,000, and mixtures thereof.

The particles can comprise an antioxidant. The antioxidant can help to promote stability of the color and or odor of the particles over time between production and use. The particles can comprise between about 0.01% to about 1% by weight antioxidant. The particles can comprise between about 0.001% to about 2% by weight antioxidant. The particles can comprise between about 0.01% to about 0.1% by weight antioxidant. The antioxidant can be butylated hydroxytoluene.

In addition to the PEG in the particles, the particles can comprise perfume. The perfume can be unencapsulated perfume, encapsulated perfume, or a combination of encapsulated perfume and unencapsulated perfume.

The particles can comprise 0.1% to about 30% by weight perfume, or optionally 0.1% to about 20% by weight perfume. The perfume can be unencapsulated perfume, encapsulated perfume, perfume provided by a perfume delivery technology, or a perfume provided in some other manner Perfumes are generally described in U.S. Pat. No. 7,186,680 at column 10, line 56, to column 25, line 22. The particles can comprise unencapsulated perfume and are essentially free of perfume carriers, such as perfume microcapsules. The particles can comprise perfume carrier materials (and perfume contained therein). Examples of perfume carrier materials are described in U.S. Pat. No. 7,186,680, column 25, line 23, to column 31, line 7. Specific examples of perfume carrier materials may include cyclodextrin and zeolites.

The particles can comprise about 0.1% to about 20%, alternatively about 1% to about 15%, alternatively 2% to about 10%, alternatively combinations thereof and any whole percentages within any of the aforementioned ranges, of perfume by weight of the particles. The particles can comprise from about 0.1% by weight to about 6% by weight of the particles of perfume. The perfume can be unencapsulated perfume and or encapsulated perfume.

The perfume can comprise a perfume raw material having a saturation vapor pressure greater than about 0.01 torr. Such a vapor pressure can be practical for having the perfume be sufficiently volatile to reach the consumers nose when the particles are in use. The composition can comprise a perfume raw material having a logP greater than about 3. Such a logP for the perfume can be practical for having acceptable deposition onto a laundry article, article of clothing. The perfume can comprise a perfume raw material having a saturation vapor pressure greater than about 0.01 torr and a logP greater than about 3. Such a perfume can be practical for providing sufficient volatility for the perfume to reach the consumers nose and sufficient deposition on to a laundry article, article of clothing, textile, or the like.

The particles can be free or substantially free of a perfume carrier. The particles may comprise about 0.1% to about 20%, alternatively about 1% to about 15%, alternatively 2% to about 10%, alternatively combinations thereof and any whole percentages within any of the aforementioned ranges, of unencapsulated perfume by weight of the particles.

The particles can comprise unencapsulated perfume and perfume microcapsules. The particles may comprise about 0.1% to about 20%, alternatively about 1% to about 15%, alternatively from about 2% to about 10%, alternatively combinations thereof and any whole percentages or ranges of whole percentages within any of the aforementioned ranges, of the unencapsulated perfume by weight of the particles. Such levels of unencapsulated perfume can be appropriate for any of the particles disclosed herein that have unencapsulated perfume.

The particles can comprise unencapsulated perfume and a perfume microcapsule but be free or essentially free of other perfume carriers. The particles can comprise unencapsulated perfume and perfume microcapsules and be free of other perfume carriers.

The particles can comprise encapsulated perfume. Encapsulated perfume can be provided as a plurality of perfume microcapsules. A perfume microcapsule is perfume oil enclosed within a shell. The shell can have an average shell thickness less than the maximum dimension of the perfume core. The perfume microcapsules can be friable perfume microcapsules. The perfume microcapsules can be moisture activated perfume microcapsules.

The perfume microcapsules can comprise a melamine/formaldehyde shell. Perfume microcapsules may be obtained from Appleton, Quest International, or International Flavor & Fragrances, or other suitable source. The perfume microcapsule shell can be coated with polymer to enhance the ability of the perfume microcapsule to adhere to fabric. This can be desirable if the particles are designed to be a fabric treatment composition. The perfume microcapsules can be those described in U.S. Patent Pub. 2008/0305982.

The particles can comprise about 0.1% to about 20%, alternatively about 1% to about 15%, alternatively 2% to about 10%, alternatively combinations thereof and any whole percentages within any of the aforementioned ranges, of encapsulated perfume by weight of the particles.

The particles can comprise perfume microcapsules but be free of or essentially free of unencapsulated perfume. The particles may comprise about 0.1% to about 20%, alternatively about 1% to about 15%, alternatively about 2% to about 10%, alternatively combinations thereof and any whole percentages within any of the aforementioned ranges, of encapsulated perfume by weight of the particles.

The particles may comprise dye. The particles may comprise less than about 0.1%, alternatively about 0.001% to about 0.1%, alternatively about 0.01% to about 0.02%, alternatively combinations thereof and any hundredths of percent or ranges of hundredths of percent within any of the aforementioned ranges, of dye by weight of the particles. Examples of suitable dyes include, but are not limited to, LIQUITINT PINK AM, AQUA AS CYAN 15, and VIOLET FL, available from Milliken Chemical.

The particles may have a variety of shapes. The particles may be formed into different shapes include tablets, pills, spheres, and the like. A particle can have a shape selected from the group consisting of spherical, hemispherical, compressed hemispherical, lentil shaped, and oblong. Lentil shaped refers to the shape of a lentil bean. Compressed hemispherical refers to a shape corresponding to a hemisphere that is at least partially flattened such that the curvature of the curved surface is less, on average, than the curvature of a hemisphere having the same radius. A compressed hemispherical particle 10 can have a ratio of height (H) to maximum base dimension B of from about 0.01 to about 0.45, as shown in FIG. 1, alternatively from about 0.1 to about 0.45, alternatively from about 0.1 to about 0.4, alternatively from about 0.2 to about 0.3, the base being the substantially flat surface of the compressed hemispherical particle. Oblong shaped refers to a shape having a maximum dimension and a maximum secondary dimension orthogonal to the maximum dimension, wherein the ratio of maximum dimension to the maximum secondary dimension is greater than about 1.2. An oblong shape can have a ratio of maximum base dimension to maximum minor base dimension greater than about 1.5. An oblong shape can have a ratio of maximum base dimension to maximum minor base dimension greater than about 2. Oblong shaped particles 10 can have a maximum base dimension from about 2 mm to about 6 mm, a maximum minor base dimension of from about 2 mm to about 6 mm

Individual particles 10 can have a mass from about 0.1 mg to about 5 g, alternatively from about 10 mg to about 1 g, alternatively from about 10 mg to about 500 mg, alternatively from about 10 mg to about 250 mg, alternatively from about 0.95 mg to about 125 mg, alternatively combinations thereof and any whole numbers or ranges of whole numbers of mg within any of the aforementioned ranges. In a plurality of particles 10, individual particles 10 can have a shape selected from the group consisting of spherical, hemispherical, compressed hemispherical, lentil shaped, and oblong.

An individual particle may have a volume from about 0.003 cm³ to about 0.15 cm³. A number of particles 10 may collectively comprise a dose for dosing to a laundry washing machine or laundry wash basin. A single dose of the particles 10 may comprise from about 1 g to about 27 g. A single dose of the particles 10 may comprise from about 5 g to about 27 g, alternatively from about 13 g to about 27 g, alternatively from about 14 g to about 20 g, alternatively from about 15 g to about 19 g, alternatively from about 18 g to about 19 g, alternatively combinations thereof and any whole numbers of grams or ranges of whole numbers of grams within any of the aforementioned ranges. The individual particles 10 forming the dose of particles 10 that can make up the dose can have a mass from about 0.95 mg to about 2 g. The plurality of particles 10 can be made up of particles 10 having different size, shape, and/or mass. The particles 10 in a dose can have a maximum dimension less than about 1 centimeter.

Particles 10 that have occlusions of gas can be practical for possibly multiple reasons. Such particles 10 can float in a liquid. Particles 10 that have gas entrained therein are comprised of gas inclusions and solid and or liquid materials. Since the particles 10 have gas entrained therein, the particles 10 have a density that is less than the density of the constitutive solid and or liquid materials forming the particle. For instance if the particle is formed of a constitutive material having a density of 1 g/cm³, and the particle is 10% by volume air, the density of the particle is 0.90 g/cm³.

For particles 10 that are used as a laundry scent additive, it can be practical that the particles 10 float in the wash solution of a laundry washing machine. Providing particles 10 that float in a the wash solution of a washing machine can provide the benefit of enhanced perfume bloom during the washing cycle as compared to particles 10 that sink and remain submerged during the washing cycle. As the particles 10 dissolve in the wash, encapsulated perfume and or unencapsulated perfume can be released from the particles 10. Perfume bloom during the washing cycle can be important to the consumer in that it can promote a more pleasant experience to the person doing the laundry and can provide a pleasant scent in the portion of the household in which laundering is conducted.

Further, providing particles 10 that float and comprise malodor reduction materials can help release the malodor reduction materials. The malodor reduction materials can reduce the perceived malodor existing in the laundry room from soiled laundry articles that may have been positioned in the laundry room for a long period of time and have developed malodors.

The particles 10 can be packaged together as a packaged composition comprising a plurality of particles 10. The particles 10 can comprise a carrier, perfume, malodor agent, and occlusions of gas. Without being bound by theory, occlusions of gas are thought to provide for improved strength of the particles 10 as compared to particles 10 having occlusions of gas having other shapes. Spherical occlusions of gas might provide for improved strength over non-spherical occlusions of gas.

Each of the particles 10 can have a density less than 1 g/cm³. Each of the particles 10 can have a density less than about 0.95 g/cm³. Since the density of a typical washing solution is about 1 g/cm³, it can be desirable to provide particles 10 that have a density less than 1 g/cm³ or even less than about 0.95 g/cm³. By having the density less than 1 g/cm³ or even less than about 0.95 g/cm³, it is thought that with the typical manufacturing variability for particle making processes, that nearly all of the particles 10 produced will have a density less than about 1 g/cm³. Having nearly all of the particles 10 have a density less than about 1 g/cm³ can be desirable for providing for particles 10 that float in a wash liquor. The perfume bloom and release of malodor reduction materials that can occur from a wash liquor may be greater for particles 10 that float as compared to particles 10 that sink.

Each of the particles 10 can have a mass between about 0.1 mg to about 5 g. The particles 10 can have a maximum dimension of less than about 20 mm The particles 10 can have a maximum dimension of less than about 10 mm The particles 10 having such a mass and maximum dimension are thought to be readily dissolvable in solutions such a wash solutions used in laundering clothing.

Each of the particles 10 can have a volume and the occlusions of gas within the particles 10 can comprise between about 0.5% to about 50% by volume of the particle, or even between about 1% to about 20% by volume of the particle, or even between about 2% to about 15% by volume of the particle, or event between about 4% to about 12% by volume of the particle. Without being bound by theory, it is thought that if the volume of the occlusions of gas is too great, the particles 10 may not be sufficiently strong to be packaged, shipped, stored, and used without breaking apart in an undesirable manner.

The occlusions of gas can have an effective diameter between about 1 micron to about 2000 microns, or even between about 5 microns to about 1000 microns, or even between about 5 microns to about 200 microns, or even between about 25 to about 50 microns. In general, it is thought that smaller occlusions of gas are more desirable than larger occlusions of gas. If the effective diameter of the occlusions of gas are too large, it is thought that the particles 10 might not be sufficiently strong to be to be packaged, shipped, stored, and used without breaking apart in an undesirable manner. The effective diameter is diameter of a sphere having the same volume as the occlusion of gas. The occlusions of gas can be spherical occlusions of gas.

The particles 10 can be formed into water soluble particles 10 that carry the perfume and the malodor reduction materials. The particles 10 can be formed by a rotoforming process. The particles 10 can be formed on a SANDVIK ROTOFORM 3000 having a 750 mm wide 10 m long belt. The rotoforming cylinder can have 2 mm diameter apertures set at 10 mm pitch in the cross machine direction and 9.35 mm pitch in the machine direction. The rotoforming cylinder be set at about 3 mm above the belt. The belt speed and rotational speed of the rotoforming cylinder can be set at 10 m/min A melt of the precursor material for the particles 10 can be pumped to the rotoforming cylinder at a rate of about 3.1 kg/min from a mixer. A plate and frame heat exchanger can be set to control the temperature to be about 50 degrees Celsius. Upstream of the stator of the rotoformer, a gas feed line and mill can be provided to provide for particles 10 having occlusions of gas if desired. The mill can be a rotor-stator type mill. The mill can be a Quadro Z1 in-line mixer with a single stage of medium rotor stators, operated at about 400 RPM. The mill and gas feed line can be combined in a single unit. An Oakes Foamer (E. T. Oakes Corporation, 686 Old Willets Path, Hauppauge, N.Y. 11788) 2MT1A continuous foamer) can be used to provide the gas feed line, flow regulator, and mill in a single unit.

A precursor material comprising the composition of the particles 10 can be prepared by providing molten carrier into a mixer, which can optionally be a batch mixer. The mixer can be heated so as to help prepare the precursor material at the desired temperature. Perfume can added to the molten carrier, optionally in the mixer. Dye, if present, can be added to the mixer. Other adjunct materials can be added to the precursor material if desired. The precursor material can optionally be prepared by in-line mixing or other known approaches for mixing materials.

Method of Use

Any of the particles 10 disclosed herein may be used in any conventional manner. For example, the particles 10 can be used to treat a laundry article. For instance, about 1 g to about 100 g of the particles 10 can be provided in a washing machine or laundry wash basin. The laundry article can be washed in a wash liquor into which the particles 10 are dissolved. The perfume and or malodor reduction materials can form part of the wash liquor. For instance all or a portion of the perfume or perfumes and or malodor reduction material or materials can be dispersed within the wash liquor, dissolved in the wash liquor, exist as a separate phase, or otherwise exist in or be part of the wash liquor. During the wash cycle, all or a portion of the perfume or perfumes and or malodor reduction material or materials can be deposited on the laundry article being washed. All or a portion of the perfume or perfumes and or malodor reduction material may be transported from the wash liquor into the head space above the wash liquor and can be further dispersed into the surroundings of the washing machine or wash basin. The bloom of the malodor reduction materials can help to reduce the impact of malodor present in the room in which the laundry article is washed. The particles 10 can be provided in a fluid pervious package 20, as shown in FIG. 2. The particles 10 can be provided in a water soluble package. The water soluble package 20 can comprise a water soluble film 30, as shown in FIG. 3. The water soluble film can be a polyvinyl alcohol film. The fluid pervious package 20 or water soluble package 20 can contain from about 1 mg to about 100 g of the particles 10.

The laundry article can be treated with a quantity of particles 10 that deliver at least 0.001 mg of malodor agent/kg of laundry article, preferably from about 0.001 mg of malodor agent/kg of laundry article to about 30 mg of malodor agent/kg of laundry article, more preferably from about 0.1 mg of malodor agent/kg of laundry article to about 20 mg of malodor agent/kg of laundry article, most preferably from about 0.2 of malodor agent/kg of laundry article to about 10 mg of malodor agent/kg of laundry article.

The particles 10 can also be used to reduce malodor from a laundry article by providing about 1 g to about 100 g of any of the particles 10 disclosed herein in a fluid pervious package. The fluid pervious package can be a pouch, as shown in FIG. 2. The package can be placed proximal to the laundry article or the package can be contacted with the laundry article. By placing the package proximal to the laundry article or contacting the laundry article with the package one or more of the perfume and the malodor agent can be transferred from the particles 10, through the package, and to the laundry article or the air-space around the laundry article. The mass transfer can occur via diffusion, dispersion, transport of portions of the particles 10 through the package to the laundry article by contact.

Perfumes

The dispersed phase may comprise a perfume that may include materials selected from the group consisting of perfumes such as 3-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylpropanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal, alpha-damascone, beta-damascone, delta-damascone, beta-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl]cyclopentan-2-one, 2-sec-butylcyclohexanone, and beta-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol.

Perfume Delivery Technologies

The compositions of the present invention may comprise one or more perfume delivery technologies that stabilize and enhance the deposition and release of perfume ingredients from treated substrate. Such perfume delivery technologies canalso be used to increase the longevity of perfume release from the treated substrate. Perfume delivery technologies, methods of making certain perfume delivery technologies and the uses of such perfume delivery technologies are disclosed in US 2007/0275866 A1.

In one aspect, the compositions of the present invention may comprise from about 0.001% to about 20%, or from about 0.01% to about 10%, or from about 0.05% to about 5%, or even from about 0.1% to about 0.5% by weight of the perfume delivery technology. In one aspect, said perfume delivery technologies may be selected from the group consisting of: perfume microcapsules, pro-perfumes, polymer particles, functionalized silicones, polymer assisted delivery, molecule assisted delivery, fiber assisted delivery, amine assisted delivery, cyclodextrins, starch encapsulated accord, zeolite and inorganic carrier, and mixtures thereof:

In one aspect, said perfume delivery technology may comprise perfume microcapsules formed by at least partially surrounding a benefit agent with a wall material. Said benefit agent may include materials selected from the group consisting of perfumes such as 33-(4-t-butylphenyl)-2-methyl propanal, 3-(4-t-butylphenyl)-propanal, 3-(4-isopropylphenyl)-2-methylpropanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropanal, and 2,6-dimethyl-5-heptenal, alpha-damascone, beta-damascone, delta-damascone, beta-damascenone, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, methyl-7,3-dihydro-2H-1,5-benzodioxepine-3-one, 2-[2-(4-methyl-3-cyclohexenyl-1-yl)propyl] cyclopentan-2-one, 2-sec-butylcyclohexanone, and beta-dihydro ionone, linalool, ethyllinalool, tetrahydrolinalool, and dihydromyrcenol. Suitable perfume materials can be obtained from Givaudan Corp. of Mount Olive, N.J., USA, International Flavors & Fragrances Corp. of South Brunswick, N.J., USA, or Quest Corp. of Naarden, Netherlands. In one aspect, the microcapsule wall material may comprise: melamine, polyacrylamide, silicones, silica, polystyrene, polyurea, polyurethanes, polyacrylate based materials, gelatin, styrene malic anhydride, polyamides, and mixtures thereof. In one aspect, said melamine wall material may comprise melamine crosslinked with formaldehyde, melamine-dimethoxyethanol crosslinked with formaldehyde, and mixtures thereof. In one aspect, said polystyrene wall material may comprise polyestyrene cross-linked with divinylbenzene. In one aspect, said polyurea wall material may comprise urea crosslinked with formaldehyde, urea crosslinked with gluteraldehyde, and mixtures thereof. In one aspect, said polyacrylate based materials may comprise polyacrylate formed from methylmethacrylate/dimethylaminomethyl methacrylate, polyacrylate formed from amine acrylate and/or methacrylate and strong acid, polyacrylate formed from carboxylic acid acrylate and/or methacrylate monomer and strong base, polyacrylate formed from an amine acrylate and/or methacrylate monomer and a carboxylic acid acrylate and/or carboxylic acid methacrylate monomer, and mixtures thereof. In one aspect, the perfume microcapsule may be coated with a deposition aid, a cationic polymer, a non-ionic polymer, an anionic polymer, or mixtures thereof. Suitable polymers may be selected from the group consisting of: polyvinylformaldehyde, partially hydroxylated polyvinylformaldehyde, polyvinylamine, polyethyleneimine, ethoxylated polyethyleneimine, polyvinylalcohol, polyacrylates, and combinations thereof. In one aspect, the microcapsule may be a perfume microcapsule. In one aspect, one or more types of microcapsules, for example two microcapsules types having different benefit agents may be used.

In one aspect, said perfume delivery technology may comprise an amine reaction product (ARP) or a thio reaction product. One may also use “reactive” polymeric amines and or polymeric thiols in which the amine and/or thiol functionality is pre-reacted with one or more PRMs to form a reaction product. Typically the reactive amines are primary and/or secondary amines, and may be part of a polymer or a monomer (non-polymer). Such ARPs may also be mixed with additional PRMs to provide benefits of polymer-assisted delivery and/or amine-assisted delivery. Nonlimiting examples of polymeric amines include polymers based on polyalkylimines, such as polyethyleneimine (PEI), or polyvinylamine (PVAm). Nonlimiting examples of monomeric (non-polymeric) amines include hydroxyl amines, such as 2-aminoethanol and its alkyl substituted derivatives, and aromatic amines such as anthranilates. The ARPs may be premixed with perfume or added separately in leave-on or rinse-off applications. In another aspect, a material that contains a heteroatom other than nitrogen and/or sulfur, for example oxygen, phosphorus or selenium, may be used as an alternative to amine compounds. In yet another aspect, the aforementioned alternative compounds can be used in combination with amine compounds. In yet another aspect, a single molecule may comprise an amine moiety and one or more of the alternative heteroatom moieties, for example, thiols, phosphines and selenols. The benefit may include improved delivery of perfume as well as controlled perfume release. Suitable ARPs as well as methods of making same can be found in USPA 2005/0003980 A1and USP 6,413,920 B1.

Test Methods

Malodor reduction materials may be separated from mixtures and indentified by analytical methods that include GC-MS and/or NMR.

Test Method for Determining Saturation Vapor Pressure (VP)

The saturation Vapor Pressure (VP) values are computed for each PRM in the perfume mixture being tested. The VP of an individual PRM is calculated using the VP Computational Model, version 14.02 (Linux) available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide the VP value at 25° C. expressed in units of torr. The ACD/Labs' Vapor Pressure model is part of the ACD/Labs model suite.

Test Method for Determining the Logarithm of the Octanol/Water Partition Coefficient (logP)

The value of the log of the Octanol/Water Partition Coefficient (logP) is computed for each PRM in the perfume mixture being tested. The logP of an individual PRM is calculated using the Consensus logP Computational Model, version 14.02 (Linux) available from Advanced Chemistry Development Inc. (ACD/Labs) (Toronto, Canada) to provide the unitless logP value. The ACD/Labs' Consensus logP Computational Model is part of the ACD/Labs model suite.

Test Method for the Generation of Molecular Descriptors

In order to conduct the calculations involved in the computed-value test methods described herein, the starting information required includes the identity, weight percent, and molar percent of each PRM in the perfume being tested, as a proportion of that perfume, wherein all PRMs in the perfume composition are included in the calculations. Additionally for each of those PRMs, the molecular structure, and the values of various computationally-derived molecular descriptors are also required, as determined in accordance with the Test Method for the Generation of Molecular Descriptors described herein.

For each PRM in a perfume mixture or composition, its molecular structure is used to compute various molecular descriptors. The molecular structure is determined by the graphic molecular structure representations provided by the Chemical Abstract Service (“CAS”), a division of the American Chemical Society, Columbus, Ohio, U.S.A. These molecular structures may be obtained from the CAS Chemical Registry System database by looking up the index name or CAS number of each PRM. For PRMs, which at the time of their testing are not yet listed in the CAS Chemical Registry System database, other databases or information sources may be used to determine their structures. For a PRM which has potentially more than one isomer present, the molecular descriptor computations are conducted using the molecular structure of only one of the isomers, which is selected to represent that PRM. The selection of isomer is determined by the relative amount of extension in the molecular structures of the isomers. Of all the isomers of a given PRM, it is the isomer whose molecular structure that is the most prevalent which is the one that is selected to represent that PRM. The structures for other potential isomers of that PRM are excluded from the computations. The molecular structure of the isomer that is the most prevalent is paired with the concentration of that PRM, where the concentration reflects the presence of all the isomers of that PRM that are present.

A molecule editor or molecular sketching software program, such as ChemDraw (CambridgeSoft/PerkinElmer Inc., Waltham, Mass., U.S.A.), is used to duplicate the 2-dimensional molecular structure representing each PRM. Molecular structures should be represented as neutral species (quaternary nitrogen atoms are allowed) with no disconnected fragments (e.g., single structures with no counter ions). The winMolconn program described below can convert any deprotonated functional groups to the neutral form by adding the appropriate number of hydrogen atoms and will discard the counter ion.

For each PRM, the molecular sketching software is used to generate a file which describes the molecular structure of the PRM. The file(s) describing the molecular structures of the PRMs is subsequently submitted to the computer software program winMolconn, version 1.0.1.3 (Hall Associates Consulting, Quincy, Mass., U.S.A., www.molconn.com), in order to derive various molecular descriptors for each PRM. As such, it is the winMolconn software program which dictates the structure notations and file formats that are acceptable options. These options include either a MACCS SDF formatted file (i.e., a Structure-Data File); or a Simplified Molecular Input Line Entry Specification (i.e., a SMILES string structure line notation) which is commonly used within a simple text file, often with a “.smi” or “.txt” file name extension. The SDF file represents each molecular structure in the format of a multi-line record, while the syntax for a SMILES structure is a single line of text with no white space. A structure name or identifier can be added to the SMILES string by including it on the same line following the SMILES string and separated by a space, e.g.: C1=CC═CC═C1 benzene.

The winMolconn software program is used to generate numerous molecular descriptors for each PRM, which are then output in a table format. Specific molecular descriptors derived by winMolconn are subsequently used as inputs (i.e., as variable terms in mathematical equations) for a variety of computer model test methods in order to calculate values such as: saturation Vapor Pressure (VP); Boiling Point (BP); logarithm of the Octanol/Water Partition Coefficient (logP); Odor Detection Threshold (ODT); Malodor Reduction Value (MORV); and/or Universal Malodor Reduction Value (Universal MORV) for each PRM. The molecular descriptor labels used in the models' test method computations are the same labels reported by the winMolconn program, and their descriptions and definitions can be found listed in the winMolconn documentation. The following is a generic description of how to execute the winMolconn software program and generate the required molecular structure descriptors for each PRM in a composition.

-   -   Computing Molecular Structure Descriptors using winMolconn:     -   1) Assemble the molecular structure for one or more perfume         ingredients in the form of a MACCS Structure-Data File, also         called an SDF file, or as a SMILES file.     -   2) Using version 1.0.1.3 of the winMolconn program, running on         an appropriate computer, compute the full complement of         molecular descriptors that are available from the program, using         the SDF or SMILES file described above as input.         -   a. The output of winMolconn is in the form of an ASCII text             file, typically space delimited, containing the structure             identifiers in the first column and respective molecular             descriptors in the remaining columns for each structure in             the input file.     -   3) Parse the text file into columns using a spreadsheet software         program or some other appropriate technique. The molecular         descriptor labels are found on the first row of the resulting         table.     -   4) Find and extract the descriptor columns, identified by the         molecular descriptor label, corresponding to the inputs required         for each model.         -   a. Note that the winMolconn molecular descriptor labels are             case-sensitive.             MORV and Universal MORV calculation

-   1.) Input Molecular Descriptor values as determined via the method     above into the following four equations:     MORV=−8.5096+2.8597×(dxp9)+1.1253×(knotpv)−0.34484×(e1C2O2)−0.00046231×(idw)+3.3509×(idcbar)+0.11158×(n2pag22)  a)     MORV=−5.2917+2.1741×(dxvp5)−2.6595×(dxvp8)+0.45297×(e1C2C2d)−0.6202×(c1C2C2)+1.3542×(CdCH2)+0.68105×(CaasC)+1.7129×(idcbar)  b)     MORV=−0.0035+0.8028×(SHCsatu)+2.1673×(xvp7)−1.3507×(c1C1C3d)+0.61496×(c1C1O2)+0.00403×(idc)−0.23286×(nd2).  c)     MORV=−0.9926−0.03882×(SdO)+0.1869×(Ssp3OH)+2.1847×(xp7)+0.34344×(e1C3O2)−0.45767×(c1C2C3)+0.7684×(CKetone)  d)

-   Equation a) relates a material's effectiveness in reducing the     malodor trans-3-methyl-2-hexenoic acid (carboxylic acid based     malodors)

-   Equation b) relates a material's effectiveness in reducing the     malodor trimethylamine (amine based malodors)

-   Equation c) relates a material's effectiveness in reducing the     malodor 3-mercapto-3-methylhexan-1-ol (thiol based malodors)

-   Equation d) relates a material's effectiveness in reducing the     malodor skatole (indole based malodors)

-   2.) For purpose of the present application, a material's MORV is the     highest MORV value from equations 1.)a) through 1.)d).

-   3.) If all MORVvalues from equations 1.)a) through 1.)d) above are     greater than 0.5, the subject material has a Universal MORV.     Method for Assigning Fragrance Fidelity Index (FFI) and the Blocker     Index (BI) for a Malodor Reduction Material

Blocker materials suitable for use in particles 10 of the present invention are chosen for their ability to decrease malodor, while not interfering with perception of a fragrance. Material selection is done by assigning two indices to a test sample material from two reference scales in order to rank odor strengths. The two reference scales are the Fragrance Fidelity Index (FFI) scale and the Blocker Index (BI) scale. The FFI ranks the ability of the test sample material to impart a perceivable odor which could cause interference when combined with another fragrance and the BI ranks the ability of the test sample material to reduce malodor perception. The two methods for assigning the indices to a test sample on the FFI and the BI reference scales are given below.

Method for Assigning the FFI to Test Samples

The first step in the method for assigning an FFI to the test samples on the FFI reference scale is to create the FFI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known concentration of an ethyl vanillin solution. Fabric swatches for this test are white knit polycotton (4 inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.

Making the FFI Reference Swatches

Make three solutions of ethyl vanillin using a 50%/50% EtOH/water as the diluent at the following concentrations: 25 ppm, 120 ppm and 1000 ppm. Pipette 13 μL of each of the three solutions into the middle of a clean swatch resulting in about a 1 cm diameter of the solution in the middle of the swatch. This will create a sensory scale of three swatches with three different odor levels based on the concentration of the solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for odor strength on the FFI scale. The FFI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Fragrance Fidelity Index (FFI) as show in Table 7.

At least four perfumers/expert graders are used to rank the ethyl vanillin swatches in the FFI scale. The perfumer/expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/expert panel is asked to rank order swatches according to a scale between 0 and 3. The panel must demonstrate statistical differences between the swatches as seen in Table 7.

TABLE 7 Results FFI of reference swatches from six perfumers/expert graders. Expert Grader Std FFI Swatch 1 2 3 4 5 6 Ave Dev. 0 Control: stripped 0 0 0.5 0 0 0 0.08 0.2 swatch NIL ethyl vanillin 1 Stripped swatch with 0.5 0.5 0.5 1.5 0.5 1.0 0.75 0.4 13 μL 25 ppm ethyl vanillin 2 Stripped swatch with 2.0 1.5 1.5 2.0 2.0 2.0 1.8 0.2 13 μL 120 ppm ethyl vanillin 3 Stripped swatch with 3.0 2.0 3.0 3.0 3.0 3.0 2.8 0.4 13 μL 1000 ppm ethyl vanillin

The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. Grader 2 in table 1 has a range of only 2 and is eliminated from the panel. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale.

TABLE 8 This table demonstrates acceptable expert graders with an acceptable range and the panel meets the requirement for discriminating statistics. Expert Grader Std FFI Swatch 1 3 4 5 6 Ave Dev. 0 Control: stripped swatch 0 0.5 0 0 0 0.08 0.2 NIL ethyl vanillin 1 Stripped swatch with 13 μL 0.5 0.5 1.5 0.5 1.0 0.80 0.4 25 ppm ethyl vanillin 2 Stripped swatch with 13 μL 2.0 1.5 2.0 2.0 2.0 1.9 0.2 120 ppm ethyl vanillin 3 Stripped swatch with 13 μL 3.0 3.0 3.0 3.0 3.0 3.0 0.0 1000 ppm ethyl vanillin

The reference swatches represent the 0, 1, 2, and 3 FFIs on the FFI reference scale, Table 9. The expert grader should familiarize them self with the strength of the odor on the FFI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the test sample material treated swatch.

TABLE 9 Swatch treatments comprising the Fragrance Fidelity Index (FFI) reference scale Swatch treatment Conc. of ethyl vanillin FFI Clean fabric swatch w/ 13 μL 1000 ppm ethyl vanillin 3 ethyl vanillin Clean fabric swatch w/ 13 μL  120 ppm ethyl vanillin 2 ethyl vanillin Clean fabric swatch w/ 13 μL  25 ppm ethyl vanillin 1 ethyl vanillin Clean fabric swatch NIL ethyl vanillin NIL ethyl vanillin 0 Making Swatches Treated with the Test Material

A clean swatch is treated with 13 μLt of a known concentration of a test sample material resulting in an about 1 cm of the solution on the clean swatch. Just like the reference swatches, the test sample material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The test material swatches and the FFI reference swatches should be made within 2 hours of each other. The test material swatch must be used within 0.5 to 12 hours and discarded after 12 hours.

Assigning the FFI to the test material

At least two perfumers/expert graders are used to assign an FFI grade to a test sample. The perfumer/expert grader smells the test sample swatch by holding that swatch 1 inch from their nose with their nose centered over the area where the test sample was pipetted on to the fabric and then assigns the test sample an FFI grade using the FFI reference scale anchor swatches as references. The test sample swatch is assigned an FFI grade at or between numbers on the FFI scale shown in Table 9. In cases where the test sample material is graded greater than 3, the test material is not a blocker material or the concentration of the material needs to be lowered and reevaluated to determine if a lower level has a malodor blocker functionality.

Method for Assigning the BI to Test Sample

The first step in the method for assigning a BI to a test sample material on the BI reference scale is to create the BI reference swatches. The swatches for the scale are created by treating clean fabrics swatches with a known amount of a known volume of isovaleric acid solution at a known concentration. Fabric swatches for this test are white knit polycotton (4 inch×4 inch) swatches from EMC ordered as PC 50/50. The supplier is instructed to strip the swatches first, stripping involves washing twice with a fragrance-free detergent and rinsing three times.

Making the BI Reference Swatches

Make one solution of 0.08% isovaleric acid using 50%/50% EtOH/water as the diluent. The BI scale contains one clean swatch with no malodor applied. Three other swatches each have a different volume of the 0.08% isovaleric acid applied. Pipette 2 μL of the 0.08% isovaleric acid solution to one clean swatch, 5 μL of the 0.08% isovaleric acid solution to the next swatch and 20 μL of isovaleric acid to the final clean swatch. These solutions are pipetted to the middle of the swatches. This will create a sensory scale of three swatches with three different odor levels based on the volume of the 0.08% isovaleric acid solution pipetted onto the swatch. After drying for 30 minutes in a vented hood, the swatches are wrapped in aluminum foil to prevent odor contamination to the treated swatch. A clean untreated swatch is also included as the lowest anchor point of reference for malodor strength on the BI scale. The BI reference scale swatches should be used within 0.5 to 12 hours and discarded after 12 hours. The swatches are used as scale anchor points when graders evaluate a test sample(s) and are assigned a Blocker Index (BI) as show in Table 12.

At least four perfumers/expert graders are used to rank the isovaleric acid swatches in the BI scale. The perfumer/expert grader needs to demonstrate adequate discrimination on the scale. The perfumer/expert grader is asked to rank order swatches according to a scale between 0 and 3. The panel of graders must demonstrate statistical differences between the swatches as seen in Table 10.

TABLE 10 Results from six perfumers/expert graders to create the BI scale. Expert Grader Std BI Swatch 1 2 3 4 5 Ave Dev. 0 Control: stripped swatch NIL 0 0 0 0 0 0 0 isovaleric acid 1 Stripped swatch with 2 μL 0.5 2.0 1.0 1.0 0.5 1.0 0.5 0.08% isovaleric acid 2 Stripped swatch with 5 μL 2.0 2.5 2.0 2.0 2.0 2.1 0.2 0.08% isovaleric acid 3 Stripped swatch with 20 μL 3.0 3.0 3.0 3.0 2.5 2.8 0.2 0.08% isovaleric acid

The expert graders must demonstrate a full range of 2.5 over the 4 swatches to be acceptably discriminating. The panel of expert graders must also demonstrated the ability to statistically discriminate between swatches in the scale. Expert grader #2 did not demonstrate the ability to discriminate between the swatches and is eliminated from the panel, see Table 11.

TABLE 11 This table demonstrates acceptable expert graders with an acceptable range and the panel meets the requirement for discriminating statistics. Expert Grader Std BI Swatch 1 3 4 5 Ave Dev. 0 Control: stripped swatch 0 0 0 0 0 0 NIL isovaleric acid 1 Stripped swatch with 2 μL 0.5 1.0 1.0 0.5 0.8 0.3 0.08% isovaleric acid 2 Stripped swatch with 5 μL 2.0 2.0 2.0 2.0 2.0 0 0.08% isovaleric acid 3 Stripped swatch with 20 μL 3.0 3.0 3.0 2.5 2.9 0.2 0.08% isovaleric acid

The reference swatches represent the 0, 1, 2, and 3 BIs on the BI reference scale, Table 12. The expert grader should familiarizes him/herself with the strength of the odor on the BI reference swatches by sniffing each one starting at 0 (the lowest odor strength) and ending at 3 (the highest odor strength). This should be done prior to evaluating the swatch treated with the test material.

TABLE 12 Swatch treatments comprising the Blocker Index (BI) reference scale. Swatch/treatment Wt of isovaleric acid BI Clean fabric swatch w/ 20 μL 0.08%  16 mg isovaleric acid 3 isovaleric acid Clean fabric swatch w/ 5 μL 0.08%   4 mg isovaleric acid 2 isovaleric acid Clean fabric swatch w/ 2 μL 0.08% 1.6 mg isovaleric acid 1 isovaleric acid Clean fabric swatch NIL isovaleric acid NIL isovaleric acid 0 Making the Malodorous Swatch and Treating it with a Test Material

To evaluate the BI, the test material is applied to a malodorous swatch to determine how well the test material blocks the malodor. The malodorous swatch is made by treating a clean swatch with 20 μL of a 0.08% solution of isovaleric acid. Dry the malodorous swatch treated with isovaleric acid in a vented hood for 30 minutes. After drying the malodorous swatch a known concentration of test material solution, between 1 ppm and 100 ppm is pipetted onto the malodorous swatch. Apply the test material solution right on top of the spot where the isovaleric acid solution was applied making an about 1 cm diameter spot. Just like the BI reference swatches, the isovaleric acid +test material swatch is dried in a vented hood for 30 minutes and then wrapped in aluminum foil to prevent contamination. The isovaleric acid +test material swatches and the BI reference swatches should be made within 2 hrs of each other. The isovaleric acid+test material swatch must be used between 1-12 hours just like the reference swatches. It is sometimes necessary to evaluate several levels of the test material between about 1and about 100 ppm to determine the BI.

Assigning the BI to the Test Material

At least two perfumers/expert graders are used to assign the BI to the test sample. The expert grader smells the isovaleric acid +test material swatch by holding that swatch one inch from their nose with their nose centered over the area where the test sample was pipetted on to the fabric and then assigns the isovaleric acid +test material swatch a BI based on ranking its odor strength against the odor strength of the swatches in the BI reference scale. The test sample swatch is assigned a BI at or between numbers on the BI in table. In cases where the isovaleric acid+test material swatch odor is greater than 3 on the BI reference scale, this indicates the material is not a blocker or the concentration of the test material needs to be lowered to achieve its blocker functionality.

Malodor Reduction Materials with FFI and BI Grades Based on the Aforementioned

Table Ref # CAS# log P Name Conc FFI BI 281 54830-99-8 3.11 3a,4,5,6,7,7a-hexahydro-4,7- 10 ppm 0 2.0 methano-1H-indenyl acetate 50 ppm 0.5 2.0 677 139504-68-0 3.75 1-((2-(tert- 10 ppm 0 2.3 butyl)cyclohexyl)oxy)butan-2-ol 50 ppm 1.8 2.0 962 55066-48-3 3.17 3-methyl-5-phenylpentan-1-ol 10 ppm 0 2.3 50 ppm 0.5 1.7 261 173445-65-3 3.29 3-(3,3-dimethyl-2,3-dihydro-1H- 10 ppm 0 1.8 inden-5-yl)propanal 50 ppm 1.3 1.3 1139 87731-18-8 2.11 (Z)-cyclooct-4-en-1-yl methyl 10 ppm 0 2.0 carbonate 50 ppm 1.0 2.7 4430-31-3 1.43 3,4,4a,5,6,7,8,8a-octahydrochromen- 10 ppm 0 2.0 2-one 50 ppm 0 2.0 204 40379-24-6 3.89 7-methyloctyl acetate 10 ppm 0 2.0 50 ppm 0 2.7 1005 93981-50-1 5.59 ethyl (2,3,6-trimethylcyclohexyl) 50 ppm 0.5 2.6 carbonate 391 106-33-2 5.73 Ethyl laurate 50 ppm 0.3 2.2 1148 1139-30-6 4.06 Caryophyllene Oxide 50 ppm 0.5 2.3 524 13877-91-3 4.31 3,7-Dimethyl-1,3,6-Octatriene(cis-β 50 ppm 0 2.8 3338-55-4 ocimene 70%) 1149 23787-90-8 4 1,3,4,6,7,8alpha-hexahydro- 10 ppm 0 1.5 1,1,5,5-tetramethyl-2H-2,4alpha- 50 ppm 0.8 2.3 methanophtalen-8(5H)-one 112-42-5 4.62 Undecanol 50 ppm 0.8 2.3 174 112-53-8 5.17 1-dodecanol 50 ppm 0.5 2.3 98-52-2 2.78 4-tert-butyl cyclohexane 10 ppm 0 2.0 50 ppm 0.3 2.0 109 112-39-0 6.41 Methyl palmitate 10 ppm 2.0 Malodor Control Materials with Improved Performance at Lower Levels.

Below are some non-limiting examples of preferred behavior by which the malodor control material gives improved malodor control at lower concentration. These nonlimiting data provide additional compelling data that malodor is being blocked, not masked.

Table Ref # CAS# Name Conc FFI BI N/A 68912-13-0 8,8-dimethyl-3a,4,5,6,7,7a- 10 ppm 0 1.5 hexahydro-1H-4,7- 50 ppm 0 2.2 methanoinden-6-yl propionate N/A TBD 4,8-dimethyl-1-(methylethyl)- 10 ppm 2.0 7-oxybiciclo[4.3.0]nonane 50 ppm 0.3 2.2 Retesting Malodor Reduction Compounds at Lower Levels.

The example below demonstrates that while a malodor reduction material could fail to demonstrate odor blocking (BI>2.5) at a higher concentration it should be retested at a lower concentration to determine if it passes.

Table Ref # CAS # Name Conc FFI BI N/A 173445-65-3 1H-Indene-5-propanal, 2,3- 10 ppm 0 1.5 dihydro-3,3-dimethyl- 50 ppm 0.5 2.7

EXAMPLE 1 Compositions Comprising Malodor Reduction Materials

In the present invention blends enable more potent malodor reduction because blends are useful at a higher % of the product composition before becoming olfactively noticeable. Below are non-limiting examples of malodor reduction agents.

% wt Active Component CAS# A B C D E 2,2,8,8-tetramethyl-octahydro-1H- 29461-14-1 35-45 15-25  5-20 10-30 15-25 2,4a-methanonapthalene-10-one 1H-Indene-ar-propanal,2,3- 300371-33-9 10-20  1-30 NIL  5-10 1-5 dihydro-1,1-dimethyl- Hexadecanoic acid, (2E)-3,7- 3681-73-0 35-45 10-25 NIL 30-40 35-50 dimethyl-2,6-octadien-1-yl ester 1-Pentanol-3-methyl-5-phenyl 55066-48-3 10-20 10-25  2-10  5-17 10 4,7-Methano-1H-inden-5-ol, 171102-41-3 0-5 10-25 NIL 1-6 1-5 3a,4,5,6,7,7a-hexahydro-, 5-acetate 4,8-dimethyl-1-(methylethyl)-7- N/A 0-5 NIL NIL NIL 1-5 oxybiciclo [4.3.0]nonane (3Z)-3,7-dimethylocta-1,3,6-triene 3338-55-4 NIL NIL 10-20 2-5 NIL 1H-Indene-5-propanal, 2,3- 173445-65-3 NIL NIL NIL 7.5-16   1-15 dihydro-3,3-dimethyl- 3,4,4a,5,6,7,8,8a- 4430-31-3 NIL NIL NIL 3-7  1-15 octahydrochromen-2-one 1-(2-tert- 139504-68-0 NIL NIL NIL 0.25-1.5  NIL butylcyclohexyl)oxybutan-2-ol ethyl (2,3,6-trimethylcyclohexyl) 93981-50-1 NIL NIL 15-30 NIL 2 carbonate benzyl 2-hydroxypropanoate 2051-96-9 NIL NIL 2-5 NIL NIL (3,5-dimethylcyclohex-3-en-1- 67634-16-6 NIL NIL  5-30 NIL NIL yl)methanol 2-Dodecanol 10203-28-8 NIL 0.25-1   NIL 0.5-3  NIL

EXAMPLE 2 Compositions Comprising Malodor Reduction Agents

% wt Active Ingredient CAS # A B C B D E (E)-1-(2,6,6-trimethyl-1- 127-42-4  4 8 2 8  3  2 cyclohex-2-enyl)pent-1-en-3- one ethyl dodecanoate 106-33-2 NIL 1 NIL 3 NIL NIL 3a,4,5,6,7,7a-hexahydro-1H- 68912-13-0  8 30 1 4  1   3.5 4,7-methanoinden-1-yl propanoate [1R-(1R*,4R*,6R*,10S*)]- 1139-30-6 NIL 0.3 2 0.5 NIL   0.5 4,12,12-trimethyl-9- methylene-5- oxatricyclo[8.2.0.04,6]dodecane (8E)-cyclohexadec-8-en-1-one 3100-36-5 NIL 5 NIL 7 NIL NIL 3,5,5-trimethylhexyl acetate 58430-94-7 25 15 50  35 60 56 ethyl (2,3,6- 93981-50-1 NIL 1 NIL 5 NIL NIL trimethylcyclohexyl) carbonate 2,4-dimethyl-4,4a,5,9b- 27606-09-3 25 10 15  15 16 15 tetrahydroindeno[1,2- d][1,3]dioxine 2,2,7,7- 23787-90-8  8 9 5 7  5  5 tetramethyltricyclo[6.2.1.01,6] undecan-5-one (3,5-dimethylcyclohex-3-en- 67634-16-6 NIL 0.7 NIL 0.5 NIL NIL 1-yl)methanol 3-(7,7-dimethyl-4- 33885-52-8 30 20 25  15 15 18 bicyclo[3.1.1]hept-3-enyl)- 2,2-dimethylpropanal Total 100  100 100  100 100  100 

EXAMPLE 3 Malodor Reduction Agent

% wt Active Ingredient CAS # A B C 5-Cyclohexadecen-1-One 37609-25-9 15.0 2.00 2.00 decahydro-2,2,7,7,8,9,9- 476332-65-7 0.005 0.01 0.01 heptamethylindeno(4,3a-b)furan 2,3-Dihydro-5,6-dimethoxy-2-(4- 33704-61-9 0.3 0.5 0.5 piperidinylmethylene)-1H-inden-1-one Cedryl Methyl Ether 19870-74-7 6.0 10.0 4.0 Trans-4-Decenal 65405-70-1 0.005 0.002 0.002 Decyl Aldehyde 112-31-2 3.74 2.0 2.0 3-methyl cyclopentadecenone 63314-79-4 0.4 1.0 1.0 Diphenyl Oxide 101-84-8 0.5 1.0 1.0 3a,4,5,6,7,7a-hexahydro-4,7-methano- 54830-99-8 5.0 8.0 8.0 1H-indenyl acetate 3a,4,5,6,7,7a-hexahydro-1H-4,7- 68912-13-0 6.0 8.0 8.0 methanoinden-1-yl propanoate 2-(5-methyl-2-propan-2-yl-8- 68901-32-6 10.0 15.0 15.0 bicyclo[2.2.2]oct-5-enyl)-1,3-dioxolane (E)-3,7-dimethyl-2,6- 3681-73-0 10.0 10.0 16.0 octadienylhexadecanoate Iso Nonyl Acetate 58430-94-7 6.65 8.0 3.0 2,2,7,7- 23787-90-8 10.0 8.0 8.0 tetramethyltricyclo[6.2.1.01,6]undecan-5- one (1-Methyl-2-(1,2,2- 198404-98-7 0.1 0.3 0.3 trimethylbicyclo[3.1.0]-hex-3- ylmethyl)cyclopropyl)methanol Lauric Aldehyde 112-54-9 0.625 1.0 0.7 Methyl Iso Eugenol 93-16-3 18.000 10.0 13.0 Methyl hexadecanoate 112-39-0 3.000 10.0 12.0 2,3-dihydro-1,1-1H-dimethyl-indene-ar- 300371-33-9 0.400 0.0 0.3 propanal 4-tert-butylcyclohexanol 98-52-2 0.400 0.1 0.1 2-isobutyl-4-hydroxy-4- 63500-71-0 1.600 2.0 2.0 methyltetrahydropyran Undecyl Aldehyde 112-44-7 1.725 2.888 1.888 Undecylenic Aldehyde 112-45-8 0.550 0.2 1.2 Total 100 100.0 100.0

EXAMPLE 4 Malodor Reducing Agent

% wt Ingredients CAS# Active 5-Cyclohexadecen-1-One 37609-25-9 2.6 2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a- 647828-16-8 0.005 b]furan 1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro- 33704-61-9 0.3 4H-inden-4-one (3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8- 19870-74-7 6 tetramethyloctahydro-1H-3a,7-methanoazulene dodecanenitrile 2437-25-4 0.06 Trans 4-Decenal 65405-70-1 0.001 decanal 112-31-2 3 (E)-3-methylcyclopentadec-4-en-1-one 82356-51-2 0.4 oxydibenzene 101-84-8 0.5 Dipropylene Glycol 25265-71-8 0.054 3a,4,5,6,7,7a-hexahydro-4,7-methano-1H- 54830-99-8 4 inden-(5 and 6)-yl acetate 3-(2-ethylphenyl)-2,2-dimethylpropanal 67634-15-5 3 3-(3-isopropylphenyl)butanal 125109-85-5 0.6 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7- 68912-13-0 6 methanoinden-6-yl propionate 2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5- 68901-32-6 10 en-2-yl)-1,3-dioxolane d E)-3,7-dimethylocta-2,6-dien-1-yl palmitate 3681-73-0 10 7-methyloctyl acetate 40379-24-6 3 2,2,7,7-tetramethyltricyclo(6.2.1.0(1,6))- 23787-90-8 10 undecan-5-one (1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan- 198404-98-7 0.1 3-yl)methyl)cyclopropyl)methanol dodecanal 112-54-9 0.6 Linalyl Benzoate 126-64-7 1.74 4-(tert-butyl)cyclohexyl acetate 32210-23-4 4 octahydro-1H-4,7-methanoindene-1-carbaldehyde 30772-79-3 0.26 methyl 2-(3-oxo-2-pentylcyclopentyl)acetate 24851-98-7 4.15 (Z)-1,2-dimethoxy-4-(prop-1-en-1-yl)benzene 93-16-3 18.23 Methyl Palmitate 112-39-0 3 3-(3,3-dimethyl-2,3-dihydro-1H-inden-5- 300371-33-9 0.4 yl)propanal 4-tert-butyl cyclohexanol 98-52-2 0.05 3-methyl-5-phenylpentan-1-ol 55066-48-3 3.5 2-isobutyl-4-methyltetrahydro-2H-pyran-4-ol 63500-71-0 1.6 (E)-4-methyldec-3-en-5-ol 81782-77-6 0.8 undecanal 112-44-7 1.7 undec-10-enal 112-45-8 0.35

EXAMPLE 5 Particles Comprising a Malodor Agent

Examples of Particles 10 that Comprise a Malodor Reduction Agent

Blue Purple Green Formula Formula Formula Component Function GCAS/CAS Wt % Wt % Wt % PEG 8000 Carrier 95229421  80.79%  80.85%  80.89% 1-((2-(tert- Malodor 139504-68-0  9.60%  9.60%  9.60% butyl)cyclohexyl)oxy)butan- reduction 2-ol Malodor reduction Malodor  2.40%  2.40%  2.40% agent of Example 5 reduction Blue AH Dye 95559345 0.0021% Liquitint Violet FL Dye 92038834  0.015% Liquitint Green 101 Dye 10053851 0.0011% Water Carrier 0.2079% 0.1350% 0.1089% Unencapsulated Perfume  7.00%  7.00%  7.00% Perfume

The dimensions and values disclosed herein are not to be understood as being strictly limited to the exact numerical values recited. Instead, unless otherwise specified, each such dimension is intended to mean both the recited value and a functionally equivalent range surrounding that value. For example, a dimension disclosed as “40 mm” is intended to mean “about 40 mm ”

Every document cited herein, including any cross referenced or related patent or application is hereby incorporated herein by reference in its entirety unless expressly excluded or otherwise limited. The citation of any document is not an admission that it is prior art with respect to any invention disclosed or claimed herein or that it alone, or in any combination with any other reference or references, teaches, suggests, or discloses any such invention. Further, to the extent that any meaning or definition of a term in this document conflicts with any meaning or definition of the same term in a document incorporated by reference, the meaning or definition assigned to that term in this document shall govern.

While particular embodiments of the present invention have been illustrated and described, it would be obvious to those skilled in the art that various other changes and modifications can be made without departing from the spirit and scope of the invention. It is, therefore, intended to cover in the appended claims all such changes and modifications that are within the scope of this invention. 

What is claimed:
 1. A composition comprising a plurality of particles, wherein said particles comprise: about 30% to about 95% by weight of a carrier; about 0.1% to about 30% by weight of a perfume; and about 0.00025% to about 30% by weight of a malodor agent; wherein said malodor agent comprises one or more malodor reduction materials having a Blocker Index of less than 3 or a Blocker Index average of 3 to about 0.001; and wherein each of said particles has a mass between about 0.1 mg to about 5 g.
 2. The composition according to claim 1, wherein said carrier is selected from the group consisting of water soluble organic alkali metal salt, water soluble inorganic alkaline earth metal salt, water soluble organic alkaline earth metal salt, water soluble carbohydrate, water soluble silicate, water soluble urea, starch, clay, water insoluble silicate, citric acid carboxymethyl cellulose, fatty acid, fatty alcohol, glyceryl diester of hydrogenated tallow, glycerol, polyethylene glycol, and combinations thereof.
 3. The composition according to claim 1, wherein said carrier is selected from the group consisting of polyvinyl alcohol, modified polyvinyl alcohol, polyvinyl pyrrolidone, polyvinyl alcohol/polyvinyl pyrrolidone, polyvinyl alcohol/polyvinyl amine, partially hydrolyzed polyvinyl acetate, polyalkylene oxide, polyethylene glycol, acrylamide, acrylic acid, cellulose, alkyl cellulosics, methyl cellulose, ethyl cellulose, propyl cellulose, cellulose ethers, cellulose esters, cellulose amides, polyvinyl acetates, polycarboxylic acids and salts, polyaminoacids or peptides, polyamides, polyacrylamide, copolymers of maleic/acrylic acids, polysaccharides, starch, modified starch, gelatin, alginates, xyloglucans, hemicellulosic polysaccharides, xylan, glucuronoxylan, arabinoxylan, mannan, glucomannan, galactoglucomannan, natural gums, pectin, xanthan, carrageenan, locus bean, arabic, tragacanth, polyacrylates, sulfonated polyacrylates, water-soluble acrylate copolymers, alkylhydroxy cellulosics, methylcellulose, carboxymethylcellulose sodium, modified carboxy-methylcellulose, dextrin, ethylcellulose, propylcellulose, hydroxyethyl cellulose, hydroxypropyl methylcellulose, maltodextrin, polymethacrylates, polyvinyl alcohol copolymers, hydroxypropyl methyl cellulose, and mixtures thereof.
 4. The composition according claim 1, wherein said carrier is water soluble.
 5. The composition according to claim 1, wherein said perfume comprises encapsulated perfume.
 6. The composition according to claim 5, wherein said carrier is polyethylene glycol having a weight average molecular weight from about 2000 to about
 13000. 7. The composition according to claim 1, wherein at least a portion of said malodor agent is unencapsulated.
 8. The composition according to claim 1, wherein at least a portion of said malodor agent is encapsulated.
 9. The composition according to claim 1, wherein said particles comprise occlusions of gas.
 10. The composition according to claim 9, wherein said perfume comprises unencapsulated perfume.
 11. The composition according to claim 10, wherein each of said particles has a volume and said occlusions of gas within said particles comprise between about 0.5% to about 50% by volume of said particles.
 12. The composition according to claim 11, wherein said occlusions of gas have an effective diameter between about 1 micron to about 2000 microns.
 13. The composition according to claim 12, wherein said occlusions of gas are spherical occlusions of gas.
 14. The composition according to claim 1, wherein said malodor reduction materials have a Fragrance Fidelity Index of from about 3 to about 0.001.
 15. The composition according to claim 1, wherein said malodor agent comprises one or more malodor reduction materials having a log P greater than 3 and said one or more malodor reduction materials are selected from the group consisting of 2-ethylhexyl (Z)-3-4-methoxyphenyl)acrylate; 2,4-dimethyl-2-(5,5,8,8-tetramethyl-5,6,7,8-tetrahydronaphthalen-2-yl)-1,3-dioxolane; 1,1-dimethoxynon-2-yne; 3-methoxy-7,7-dimethyl-10-methylenebicyclo[4.3.1]decane; methoxycyclododecane; 1,1-dimethoxycyclododecane; (Z)-tridec-2-enenitrile; (2-hydroxy-4-methoxyphenyl)(phenyl)methanone; 2,4a,5,8a-tetramethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-yl formate; 1,8-dioxacycloheptadec an-9-one; 4-(tert-pentyl)cyclohexan-1-one; 2-methoxy-1,1′-biphenyl; 3a,5,6,7,8,8b-hexahydro-2,2,6,6,7,8,8-heptamethyl-4H-indeno(4,5-d)-1,3-dioxole; 7-isopropyl-8,8-dimethyl-6,10-dioxaspiro[4.5]decane; octyl furan-2-carboxylate; octyl acetate; 2-heptyl-4-methyl-1,3-dioxolane; octanal; 1,1-dimethoxyoctane; 7-methyl-3-methyleneocta-1,6-diene; 2-methyl-6-methyleneoct-7-en-2-yl acetate; tetradecanal; tetradecanenitrile; 2,2,6,8-tetramethyl-1,2,3,4,4a,5,8,8a-octahydronaphthalen-1-ol; 2-((1S,5R)-6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)ethyl acetate; (4R,4aS,6R)-4,4a-dimethyl-6-(prop-1-en-2-yl)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; nonan-1-ol; nonanal; 12-methyl-14-tetradec-9-enolide; N-ethyl-2-isopropyl-5-methylcyclohexane-1-carboxamide; 2-methoxynaphthalene; (E)-3,7,11-trimethyldodeca-1,6,10-trien-3-ol; (Z)-3,7-dimethylocta-2,6-dien-1-ol; methyl (E)-non-2-enoate; 10-isopropyl-2,7-dimethyl-1-oxaspiro[4.5]deca-3,6-diene; 2-(2-(4-methylcyclohex-3-en-1-yl)propyl)cyclopentan-1-one; (E)-4-(2,2,3,6-tetramethylcyclohexyl)but-3-en-2-one; (4-(4-methylpent-3-en-1-yl)cyclohex-3-en-1-yl)methyl acetate; 2-(tert-butyl)-4,5,6-trimethyl-1,3-phenylene dinitrite; 1,7-dioxacycloheptadecan-8-one; 1-(4-(tert-butyl)-2,6-dimethyl-3,5-dinitrophenyl)ethan-1-one; 1-(tert-butyl)-2-methoxy-4-methyl-3,5-dinitrobenzene; 3-methylcyclopentadecan-1-one; (E)-3-methylcyclopentadec-4-en-1-one; 1-(4-isopropylcyclohexyl)ethan-1-ol; (E)-dec-5-enoic acid; methyl non-2-ynoate; 2-methyldecanal; 6,6-dimethoxy-2,5,5-trimethylhex-2-ene; methyl stearate; 1,1-dimethoxy-2-methylundecane; undecan-2-one; 2-methylundecanal; methyl tetradecanoate; methyl (9Z,12Z)-octadeca-9,12-dienoate; methyl palmitate; 1-methyl-2-phenoxybenzene; 1-allyl-4-methoxybenzene; 1-(naphthalen-2-yl)ethan-1-one; methyl oct-2-ynoate; methyl 2,6,6-trimethylcyclohex-2-ene-1-carboxylate; 7-isopropyl-10-methyl-1,5-dioxaspiro[5.5]undecan-3-ol; 3-(3-(tert-butyl)phenyl) -2-methylpropanal; (E)-4-(4,8-dimethylnona-3,7-dien-1-yl)pyridine; (E)-trideca-3,12-dienenitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol; 8-isopropyl-6-methylbicyclo[2.2.2]oct-5-ene-2-carbaldehyde; (S)-1-methyl-4-(prop-1-en-2-yl)cyecyclohex-1-ene; 3,7-dimethylocta-1,6-dien-3-yl octanoate; 3,7-dimethylocta-1,6-dien-3-yl isobutyrate; 3,7-dimethylocta-1,6-dien-3-yl benzoate; 3,7-dimethylocta-1,6-dien-3-yl 2-aminobenzoate; (2Z,6E)-3,7-dimethylnona-2,6-dienenitrile; 3-(4-methylcyclohex-3-en-1-yl)butanal; (2,5-dimethyl-1,3-dihydroinden-2-yl)methanol; 3-(4-(tert-butyl)phenyl)-2-methylpropanal; dodecan-1-ol; dodecyl acetate; dodecanoic acid; 5-hexyl-5-methyldihydrofuran-2(3H)-one; dodecanal; 4-(1-ethoxyvinyl)-3,3,5,5-tetramethylcyclohexan-1-one; ((3S,3aR,6R,8aS)-7,7-dimethyl-8-methyleneoctahydro-1H-3a,6-methanoazulen-3-yl)methanol; 5-(sec-butyl)-2-(2,4-dimethylcyclohex-3-en-1-yl)-5-methyl-1,3-dioxane; (1-methyl-2-((1,2,2-trimethylbicyclo[3.1.0]hexan-3-yl)methyl)cyclopropyllmethanol; 2-propylheptanenitrile; 2-hexylcyclopentan-1-one; 2,6,9,10-tetramethyl-1-oxaspiro(4.5)deca-3,6-diene; isopropyl palmitate; isopropyl tetradecanoate; isopropyl dodecanoate; (E)-cyclohexadec-8-en-1-one; (2S,5S)-2-isopropyl-5-methylcyclohexan-1-one; 2-hexylcyclopent-2-en-1-one; (2S,5S)-2-isopropyl-5-methylcyclohexan-1-one; 4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; (Z)-1-(benzyloxy)-2-methoxy-4-(prop-1-en-1-yl)benzene; 1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one; 6-(sec-butyl)quinoline; 2-(cyclohexyloxy)-1,7,7-trimethylbicyclo[2.2.1]heptane; (1R,2R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl propionate; (1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; 4-(( 2 R)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl)cyclohexan-1-ol; (1R,4S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 2-(4-isopropylcyclohexa-1,4-dien-1-yl)ethyl formate; isopentyl (E)-undec-6-enoate; isopentyl dodecanoate; (E)-oxacycloheptadec-10-en-2-one; (E)-non-2-enenitrile; (E)-8-(1H-indol-1-yl)-2,6-dimethyloct-7-en-2-ol; 8,8-di(1H-indol -1-yl)-2,6-dimethyloctan-2-ol; 2-cyclododecylpropan-1-ol; 3-methyl-5-phenylpentanenitrile; 2,3-dihydro-3,3-dimethyl-1H-indene-5-propanal; 3-(3,3-dimethyl-2,3-dihydro-1H-inden-5-yl)propanal; hexyl octanoate; hexyl hexanoate; (Z)-2-benzylideneoctanal; hexyl benzoate; (Z)-hex-1-en-1-yl (Z)-2-methylbut-2-enoate; (E)-3,7-dimethylocta-2,6-dien-1-yl palmitate; oxacycloheptadecan-2-one; ethyl (1R,2R,3R,4R)-3-isopropylbicyclo[2.2.1]hept-5-ene-2-carboxylate; 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl propionate; (E)-oxacyclohexadec-13-en-2-one; 6-butyl-2,4-dimethyl-3,6-dihydro-2H-pyran; 2-((3S,5R,8S)-3,8-dimethyl-1,2,3,4,5,6,7,8-octahydroazulen-5-yl)propan-2-ol; 1-(2,6,6-trimethylcyclohex-2-en-1-yl)pentan-3-one; ethyl 2-ethyl-6,6-dimethylcyclohex-2-ene-1-carboxylate; (1Z,5Z)-1,5-dimethyl-8-(propan-2-ylidene)cyclodeca-1,5-diene; (1E,6E)-8-isopropyl-1-methyl-5-methylenecyclodeca-1,6-diene; (E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate; (E)-3,7-dimethylocta-2,6-dien-1-yl 2-phenylacetate; (6E,10E)-3,7,11,15-tetramethylhexadeca-1,6,10,14-tetraen-3-ol; (E)-2-(3,7-dimethylocta-2,6-dien-1-yl)cyclopentan-1-one; 5-heptyldihydrofuran-2(3H)-one; 1-methyl-4-(propan-2-ylidene)cyclohexyl acetate; 1-methyl-4-(propan-2-ylidene)cyclohexan-1-ol; (1R,4aR,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene; (Z)-4-(2,2-dimethyl-6-methylenecyclohexyl)but-3-en-2-one; (4aS,9aR)-3,5,5,9-tetramethyl-2,4a,5,6,7,9a-hexahydro-1H-benzo[7]annulene; (1R,3aR,4R,7R)-1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene; 2-((2R,4aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol; 5-octyldihydrofuran-2(3H)-one; (Z)-1-(2,2-dimethyl-6-methylenecyclohexyl)but-2-en-1-one; (1R,4aS,8aS)-1-isopropyl-7-methyl-4-methylene-1,2,3,4,4a,5,6,8a-octahydronaphthalene;1-(3,3-dimethylcyclohexyl)pent-4-en-1-one; 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopenta[g]isochromene; furan-2-ylmethyl octanoate; furan-2-ylmethyl hexanoate; furan-2-ylmethyl heptanoate; 2-methyldecanenitrile; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate; ethyl (3aR,4S,7R,7aR)-octahydro-3aH-4,7-methanoindene-3a-carboxylate; (6-isopropyl-9-methyl-1,4-dioxaspiro[4.5]decan-2-yl)methanol; undec-10-enenitrile; 3-(2-ethylphenyl)-2,2-dimethylpropanal; (E)-4,8-dimethyldeca-4,9-dienal; (E)-4-((3aR,4R,7R,7aR)-1,3a,4,6,7,7a-hexahydro-5H-4,7-methanoinden-5-ylidene)-3-methylbutan-2-ol; 8,8-dimethyl-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl acetate; 3-(4-ethylphenyl)-2,2-dimethylpropanenitrile; 2-heptylcyclopentan-1-one; 1-ethoxyethoxy Cyclododecane; 3-cyclohexene-1-carboxylic acid, 2,6,6-trimethyl-, methyl ester; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-yl acetate; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol; oxacyclohexadecan-2-one; (E)-cyclopentadec-4-en-1-one; 1-cyclopentadec-4-en-1-one; 1,4-dioxacycloheptadecane-5,17-dione; ethyl undec-10-enoate; ethyl palmitate; ethyl nonanoate; ethyl tetradecanoate; (E)-3,7-dimethylnona-1,6-dien-3-ol; ethyl dodecanoate; ethyl decanoate; ethyl 6,6-dimethyl-2-methylenecyclohex-3-ene-1-carboxylate; 6-ethyl-2,10,10-trimethyl-1-oxaspiro[4.5]deca-3,6-diene; 2-9(1R,3S,4S)-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohexyl)propan-2-ol; (E)-3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol; (E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; 1,1-dimethoxydodecane; (R)-1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene; 7,9-Dimethylspirol[5.5]undecan-3-one; oxydibenzene; diphenylmethane; 2-methyl-1-phenylpropan-2-yl butyrate; octahydro-1H-4,7-methanoinden-5-yl acetate; 2-methyl-5-(prop-1-en-2-yl)cyclohexyl acetate; 3,7-dimethyloct-6-en-3-ol; dibutylsulfane; 1,2-diphenylethane; 6-hexyltetrahydro-2H-pyran-2-one; (3R,4R)-1-isopropyl-4-methyl-3-(prop-1-en-2-yl)-4-vinylcyclohex-1-ene; (3S,3aS,5R)-3,8-dimethyl-5-(prop-1-en-2-yl)-1,2,3,3a,4,5,6,7-octahydroazulene; 6-heptyltetrahydro-2H-pyran-2-one; (1S,8aR)-4,7-dimethyl-1-(prop an-2-yl)-1,2,3,5,6,8a-hexahydronaphthalene; (Z)-1((1R,2S)-2,6,6-trimethylcyclohex-3-en-1-yl)but-2-en-1-one; (1S,8aS)-1-isopropyl-4,7-dimethyl-1,2,3,5,6,8a-hexahydronaphthalene; 3,7,7-trimethylbicyclol[4.1.0]hept-3-ene; dec-9-en-1-ol; decyl propionate; 1,1-diethoxydecane; 1-cyclohexylethyl (E)-but-2-enoate; 3-(4-isopropylphenyl)-2-methylpropanal; cyclotetradecane; cyclopentadecanone; cyclohexyl 2-hydroxybenzoate; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl butyrate; 8,8-dimethyl-1,2,3,4,5,6,7,8-octahydronaphthalene-2-carbaldehyde; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-5-yl isobutyrate; (5R,6R)-3,6-dimethyl-5-(prop-1-en-2-yl)-6-vinyl-4,5,6,7-tetrahydrobenzofuran; 2-(3-phenylpropyl)pyridine; dodecanenitrile; (E)-cycloheptadec-9-en-1-one; 3-(4-methylcyclohex-3-en-1-yl)but-3-en-1-yl acetate; 3-(4-methylcyclohex-3-en-1-yl)butan-1-ol; (E)-3-methyl-5-phenylpent-2-enenitrile; (E)-2-(2,6-dimethylhepta-1,5-dien-1-yl)-4-methyl-1,3-dioxolane; (E)-1,1-dimethoxy-3,7-dimethylocta-2,6-diene; (E)-1,1-diethoxy-3,7-dimethylocta-2,6-diene; (E)-3,7-dimethylocta-1,3,6-triene; (E)-oxacycloheptadec-11-en-2-one; (Z)-dec-4-enal; (E)-hex-3-en-1-yl (E)-hex-3-enoate; (Z)-hex-3-en-1-yl 2-hydroxybenzoate; (Z)-hex-3-en-1-yl benzoate; (Z)-hex-3-en-1-yl 2-methylbutanoate; cinnamyl propionate; cinnamyl isobutyrate; cinnamyl cinnamate; hexadecan-1-ol; (E)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)hepta-1,6-dien-3-one; 2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)butanal; (3aR,5aR,9aR,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan; 1,6-dioxacycloheptadecan-7-one; 1-(6-(tert-butyl)-1,1-dimethyl-2,3-dihydro-1H-inden-4-yl)ethan-1-one; (3R,3aR,6S,7S,8aS)-6-methoxy-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulene; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-3-yl formate; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-yl acetate; (4Z,8Z)-1,5,9-trimethyl-13-oxabicyclo[10.1.0]trideca-4,8-diene; (3R,3aS,6R,7R,8aS)-3,6,8,8-tetramethyloctahydro-1H-3a,7-methanoazulen-6-ol; 5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclol[3.2.1]octane; 5-methyl-1-(2,2,3-trimethylcyclopent-3-en-1-yl)-6-oxabicyclo[3.2.1]octane; 1,1,2,3,3-pentamethyl-1,2,3,5,6,7-hexahydro-4H-inden-4-one; (Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-3-en-5-yl acetate; (1S,2S,5R,8S)-4,4,8-trimethyltricyclol[6.3.1.02,5]dodecan-1-ol; 2-methyl-5-(prop-1-en-2-yl)cyclohex-2-en-1-yl acetate; octanenitrile; decanoic acid; decanal; 2,2-dimethyl-3-methylenebicyclol[2.2.1]heptane; ethyl 2-methyl-4-oxo-6-pentylcyclohex-2-ene-1-carboxylate; 2,6-di-tert-butyl-4-methylphenol; butyl stearate; butyl undec-10-enoate; 2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)butan-1-ol; 3-(4-(tert-butyl)phenyl)propanal; (1S,2S)-1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl isobutyrate; 1,7,7-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 2-ethoxy-2,6,6-trimethyl-9-methylenebicyclo[3.3.1]nonane; (ethoxymethoxy)cyclododecane; (E)-1-methyl-4-(6-methylhept-5-en-2-ylidene)cyclohex-1-ene; 3,3,6,7-tetramethyloctahydro-2H-chromene; (5R,10R)-6,10-dimethyl-2-(propan-2-ylidene)spirol[4.5]dec-6-en-8-one; 1-methyl-4-(prop-1-en-2-yl)cyclohexyl acetate; (2Z,6E)-2,6-dimethyl-10-methylenedodeca-2,6,11-trienal; (R)-3-methylene-6-((S)-6-methylhept-5-en-2-yl)cyclohex-1-ene; (4aR,7R,8aS)-4a-methyl-1-methylene-7-(prop-1-en-2-yl)decahydronaphthalene; (Z)-2-methyl-5-((1S,2R,4R)-2-methyl-3-methylenebicyclo[2.2.1]heptan-2-yl)pent-2-en-1-ol; 6,6-dimethyl-2-methylenebicyclo[3.1.1]heptane; 2-ethoxynaphthalene; (1S,4R,7R)-1,4,9,9-tetramethyl-1,2,3,4,5,6,7,8-octahydro-4,7-methanoazulene; (1aS,5aR,9aR)-1a,5,5,7-tetramethyl-1a,2,3,4,5,5a,8,9-octahydrobenzo[1,7]cyclohepta[1,2]-b oxirene; (R)-3 5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzo[7]annulene; (1S,4S)-1,4-dimethyl-7-(propan-2-ylidene)-1,2,3,4,5,6,7,8-octahydroazulene; (E)-7,11-dimethyl-3-methylenedodeca-1,6,10-triene; (1R,2S,6S,7S,8S)-8-isopropyl-1-methyl-3-methylenetricyclo[4.4.0.02,7]decane; (3R,3aS,7S,8aS)-3,8,8-trimethyl-6-methyleneoctahydro-1H-3a,7-methanoazulene; (1R,9S,Z)-4,11,11-trimethyl-8-methylenebicyclo[7.2.0]undec-4-ene; (S)-4-methyl-1-((S)-6-methylhept-5-en-2-yl)cyclohex-3-en-1-ol; benzyl dodecanoate; benzyl cinnamate; benzyl benzoate; 2′-isopropyl-1,7,7-trimethylspiro[bicyclo[2.2.1]heptane-2,4′-[1,3]dioxane]; 4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbonitrile; methyl (E)-2-((7-hydroxy-3,7-dimethyloctylidene)amino)benzoate; 4-methoxybenzyl 2-phenylacetate; pentyl (Z)-3-phenylacrylate; (3aR,5aS,9aS,9bR)-3a,6,6,9a-tetramethyldodecahydronaphtho[2,1-b]furan; (4aR,5R,7aS,9R)-2,2,5,8,8,9a-hexamethyloctahydro-4H-4a,9-methanoazuleno[5,6-d][1,3]dioxole; 2,5,5-trimethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-ol; 2,5,5-trimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-ol; 1-((2-(tert-butyl)cyclohexyl)oxy)butan-2-ol; (3S,5aR,7aS,11aS,11bR)-3,8,8,1 1a-tetramethyldodecahydro-5H-3,5a-epoxynaphtho[2,1-c]oxepine; 2,2,6,6,7,8,8-heptamethyldecahydro-2H-indeno[4,5-b]furan; 2,2,7,7,8,9,9-heptamethyldecahydroindeno[4,3a-b]furan; 2-(sec-butyl)-1-vinylcyclohexyl acetate; (4R,4aS)-4,4a-dimethyl-6-(propan-2-ylidene)-4,4a,5,6,7,8-hexahydronaphthalen-2(3H)-one; 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl propionate; (2Z,6E,9E)-2,6,10-trimethyldodeca-2,6,9,11-tetraenal; (2R,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 1,7-dimethyl-7-(4-methylpent-3-en-1-yl)tricyclo[2.2.1.02,6]heptane; (E)-5-(2,3-dimethyltricyclo[2.2.1.02,6]heptan-3-yl)-2-methylpent-2-en-1-ol; (1R,3aS,7S,8aR)-1,4,9,9-tetramethyl-2,3,6,7,8,8a-hexahydro-1H-3a,7-methanoazulene; 1-(5,5-dimethylcyclohex-1-en-1-yl)pent-4-en-1-one; (1S,4aS,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; (R,Z)-1(2,6,6-trimethylcyclohex-2-en-1-yl)pent-1-en-3-one; 1-methyl-4-(prop-1-en-2-yl)cyclohex-1-ene; (Z)-4-(2,5,6,6-tetramethylcyclohex-2-en-1-yl)but-3-en-2-one; (1Z,4E,8Z)-2,6,6,9-tetramethylcycloundeca-1,4,8-triene; (4aR,8S,9aS)-3,5,5,8tetramethyl-9-methylene-2,4a,5,6,7,8,9,9a-octahydro-1H-benzo[7]annulene; (1aR,4R,4aR,7bS)-1,1,4,7-tetramethyl-1a,2,3,4,4a,5,6,7b-octahydro-1H-cyclopropa[e]azulene; 1,4-dimethyl-7-(prop-1-en-2-yl)-1,2,3,4,5,6,7,8-octahydroazulene; (3E,6E)-3,7,11-trimethyldodeca-1,3,6,10-tetraene; 7,7-dimethyl-2-methylenebicyclo[2.2.1]heptane; 2-((2R,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan -2-ol; (R)-1-methyl-4-(6-methylhept-5-en-2-yl)benzene; (3aR,3bR,4S,7R,7aS)-4-isopropyl-7-methyl-3a,3b,4,5,6,7-hexahydro-1H-cyclopenta[1,3]cyclopropa[1,2]benzene; (1aS,2aR,3R,5aS,7R,7aR)-3,6,6,7a-tetramethyloctahydro-2H-2a,7-methanoazuleno[5,6-b]oxirene; (1R,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; (1S,4aR,8aR)-1-isopropyl-4,7-dimethyl-1,2,4a,5 6,8a-hexahydronaphthalene; (R)-2-((R)-4-methylcyclohex-3-en-1-yl)hex-5-en-2-ol; (Z)-1-methyl-4-(6-methylhepta-2,5-dien-2-yl)cyclohex-1-ene; 2,6-dimethyl-6-(4-methylpent-3-en-1-yl)bicyclo[3.1.1]hept-2-ene; (E)-2-benzylideneheptan-1-ol; (E)-2-benzylideneheptyl acetate; (Z)-(2-(diethoxymethyl)hept-1-en-1-yl)benzene; (E)-2-benzylideneheptanal; (1S,4aR,8aS)-1-isopropyl-4,7-dimethyl-1,2,4a,5,6,8a-hexahydronaphthalene; (3R,5aS,9aR)-2,2,5a,9-tetramethyl-3,4,5,5a,6,7-hexahydro-2H-3,9a-methanobenzo[b]oxepine; 1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; 3-methyl-1-phenylpentan-3-ol; 2,6,10-trimethylundecanal; allyl 3-cyclohexylpropanoate; (1aR,4aS,7R,7aR,7bS)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulene; (E)-undec-9-enal; methyl (E)-2-(((3,5-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate; 2,6,10-trimethylundec-9-enal; (7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methyl acetate; nonyl acetate; (2-(1-propoxyethoxy)ethyl)benzene; (Z)-2-(4-methylbenzylidene)heptanal; dec-9-enal; (Z)-oxacycloheptadec-8-en-2-one; (2S,4aR,8aR)-4a,8-dimethyl-2-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 2-((2S,4aR,8aR)-4a,8-dimethyl-1,2,3,4,4a,5,6,8a-octahydronaphthalen-2-yl)propan-2-ol; 1-(3,5,5,6,8,8-hexamethyl-5,6,7,8-tetrahydronaphthalen-2-yl)ethan-1-one; 6-isopropylquinoline; 3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)propanal; 6,10,14-trimethylpentadecan-2-one; (E)-cyclohexadec-5-en-1-one; 1-isopropyl-4-methylcyclohex-3-en-1-ol; 1-isopropyl-4-methylcyclohex-3-en-1-ol; 3,6-dimethyl-4,5,6,7-tetrahydrobenzofuran; (1aR,2S,4aS)-2,4a,8,8-tetramethyloctahydrocyclopropa[d]naphthalen-3(1H)-one; (Z)-dodec-2-enal; (E)-hex-3-en-1-yl 3-methylbutanoate; 3,6-dimethyloctan-3-yl acetate; 3-(4-isopropylphenyl)propanal; (Z)-undec-2-enenitrile; (E)-undec-2-enal; phenethyl butyrate; (Z)-non-2-enal; nonan-2-ol; nonan-2-one; 2-isobutylquinoline; (E)-2-hexylidenecyclopentan-1-one; 2-heptyltetrahydrofuran; (E)-dec-2-enal; 2,6-dimethyloctanal; decan-1-ol; (E)-hept-1-en-1-yl acetate; undec-10-en-1-ol; undec-10-enal; 2-((2R,4aS)-4a,8-dimethyl-1,2,3,4,4a,5,6,7-octahydronaphthalen-2-yl)propan-2-ol; 1-isopropyl-4-methyl-7-thiabicyclo[2.2.1]heptane; (3E,5Z)-undeca-1,3,5-triene; 3,7-dimethyloct-6-en-3-ol; 1,3,3-trimethylbicyclo[2.2.1]heptan-2-yl acetate; 1,1,2,3,3-pentamethyl-2,3-dihydro-1H-indene; (Z)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-dodec-3-enal; (S)-5-heptyldihydrofuran-2(3H)-one; (R)-5-heptyldihydrofuran-2(3H)-one; (E)-6,10-dimethylundeca-5,9-dien-2-yl acetate; (Z)-3-methyl-5-phenylpent-2-enenitrile; (2S,5S,6S)-2,6,10,10-tetramethyl-1-oxaspiro[4.5]decan-6-ol; (2E)-3-methyl-5-phenyl-2-pentenenitrile; (2S,5R)-2-isopropyl-5-methylcyclohexan-1-one; (R,E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 2-(8-isopropyl-6-methylbicyclo[2.2.2]oct-5-en-2-yl)-1,3-dioxolane; (E)-4-(2,2-dimethyl-6-methylenecyclohexyl)-3-methylbut-3-en-2-one; 3-(3-isopropylphenyl)butanal; 3-(1-ethoxyethoxy)-3,7-dimethylocta-1,6-diene; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl propionate; 2-((3S,3aS,5R)-3,8-dimethyl-1,2,3,3a,4,5,6,7-octahydroazulen-5-yl)propan-2-ol; benzyl 2-phenylacetate; 3-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)-2,2-dimethylpropanal; 2-methyl-5-(6-methylhept-5-en-2 -yl)bicyclo[3.1.0]hex-2-ene; 1-(1,1,2,3,3,6-hexamethyl-2,3-dihydro-1H-inden-5-yl)ethan-1-one; (E)-tridec-2-enal; (1R,4S,4aS,6R,8aS)-4,8a,9,9-tetramethyloctahydro-1,6-methanonaphthalen-1(2H)-ol; p-tolyl hexanoate; 5-hexyl-4-methyldihydrofuran-2(3H)-one; ethyl (2Z,4E)-deca-2,4-dienoate; 2,4-dimethyl-6-phenyl-3,6-dihydro-2H-pyran; 2-cyclohexylidene-2-phenylacetonitrile; (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methyl acetate; (4-(prop-1-en-2-yl)cyclohex-1-en-1-yl)methanol; 2-isopropoxyethyl)benzene; 2-cyclohexylhepta-1,6-dien-3-one; (2-(cyclohexyloxy)ethyl)benzene; phenethyl 2-methylbutanoate; phenethyl 2-phenylacetate; phenyl benzoate; phenethyl benzoate; 2-(6,6-dimethylbicyclo[3.1.1]hept-2-en-2-yl)acetaldehyde; 3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoinden-6-yl pivalate; (E)-3 3-dimethyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pent-4-en-2-ol; 1-methyl-4-(4-methylpent-3-en-1-yl)cyclohex-3-ene-1-carbaldehyde; p-tolyl 2-phenylacetate; Ethyl 2,4,7-decatrienoate; 2-benzyl-4,4,6-trimethyl-1,3-dioxane; 2,4-dimethyl-4-phenyltetrahydrofuran; (2R,4a′R,8a′R)-3,7′-dimethyl-3′,4′,4a′,5′,8′,8a′-hexahydro-1′H-spiro[oxirane-2,2′-[1,4]methanonaphthalene]; (Z)-6-ethylideneoctahydro-2H-5,8-methanochromene; 2-((S)-1-((S)-3,3-dimethylcyclohexyl)ethoxy)-2-oxoethyl propionate; methyl 2,2-dimethyl-6-methylenecyclohexane-1-carboxylate; 4-methyl-2-phenyl-3,6-dihydro-2H-pyran; 2,2,7,9-tetramethylspiro(5.5)undec-8-en-1-one; 3-methyl-5-(2,2,3-trimethylcyclopent-3-en-1-yl)pentan-2-ol; (Z)-2-ethyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; (E)-2-methyl-4-(2,2,3-trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 1-(3-hydroxy-3-methylpent-4-en-1-yl)-2,5,5,8a-tetramethyldecahydronaphthalen-2-ol; (4aR,6aS,10aS,10bR)-3,4a,7,7,10a-pentamethyl-4a,5,6,6a,7,8,9,10,10a,10b-decahydro-1H-benzo[f]chromene; (4aR,8aR)-4a,8-dimethyl-2-(propan-2-ylidene)-1,2,3,4,4a,5,6,8a-octahydronaphthalene; 2-(1-(3,3-dimethylcyclohexyl)ethoxy)-2-methylpropyl cyclopropanecarboxylate; 3-(4-isobutylphenyl)-2-methylpropanal; (1aR,4aR,7S,7aR,7bR)-1,1,7-trimethyl-4-methylenedecahydro-1H-cyclopropa[e]azulen-7-ol; 1-(spiro[4.5]dec-7-en-7-yl)pent-4-en-1-one; (Z)-dodec-4-enal; (1S,4S,4aR,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; (1S,4S,4aR,8aS)-4-isopropyl-1,6-dimethyl-1,2,3,4,4a,7,8,8a-octahydronaphthalen-1-ol; 3-methyl-2-pentylcyclopentan-1-one; 2,6,10,10-tetramethyl-1-oxaspiro[4.5]dec-6-ene; (1aR,4aS)-2,4a,8,8-tetramethyl-1,1a,4,4a,5,6,7, 8-octahydrocyclopropa[d]naphthalene; 1-isopropyl-2-methoxy-4-methylbenzene; 1-(2,2,6-trimethylcyclohexyl)hexan-3-ol; (2E,6E)-3,7,11-trimethyldodeca-2,6,10-trien-1-ol; (Z)-dec-2-enal; (E)-non-2-enal; (E)-dec-4-enal; (Z)-oxacycloheptadec-8-en-2-one; (Z)-3,7-dimethylocta-1,3,6-triene; (Z)-3,7-dimethylocta-1,3,6-triene; (E)-3,7-dimethylocta-2,6-dien-1-ol; (1R-(1alpha,3alpha,4aalpha))-2,3,4,4a,5,6-hexahydro-2,2-dimethyl-1,3-methanonaphthalen-7(1H)-one; tridecan-1-ol; methyl 2-((1-hydroxy-3-phenylbutyl)amino)benzoate; 1-((2E,5Z,9Z)-2,6,10-trimethylcyclododeca-2,5,9-trien-1-yl)ethan-1-one; decahydro-2,6,6,7,8,8-hexamethyl-2h-indeno(4,5-b)furan; pentamethyl octahydroindenodioxane; undecanal; (E)-4-methyldec-3-en-5-ol; (3R,4aS,5R)-4a,5-dimethyl-3-(prop-1-en-2-yl)-1,2,3,4,4a,5,6,7-octahydronaphthalene; 2-((2R,8R,8aS)-8,8a-dimethyl-1,2,3,4,6,7,8,8a-octahydronaphthalen-2-yl)propan-2-ol; (Z)-2-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-enal; 1-methoxy-3a,4,5,6,7,7a-hexahydro-1H-4,7-methanoindene; methyl (Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidene)amino)benzoate; 2,4,6-trimethyl-4-phenyl-1,3-dioxane; 1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one; methyl (Z)-2-(((2,4-dimethylcyclohex-3-en-1-yl)methylene)amino)benzoate; 4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-ol; 4,8-dimethyl-2-(propan-2-ylidene)-1,2,3,3a,4,5,6,8a-octahydroazulen-6-yl acetate; decahydro-3H-spiro[furan-2,5′-[4,7]methanoindene]; (2Z,6E)-nona-2,6-dienenitrile; (1aR,4S,4aS,7R,7aS,7bS)-1,1,4,7-tetramethyldecahydro-1H-cyclopropa[e]azulen-4-ol; 3,5,5,6,7,8,8-heptamethyl-5,6,7,8-tetrahydronaphthalene-2-carbonitrile; (1S,2S,3S,5R)-2,6,6-trimethylspiro[bicyclo[3.1.1]heptane-3,1′-cyclohexan]-2′-en-4′-one; 1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene]; (2′S,4a′S,8a′S)-1′,1′,5′,5′-tetramethylhexahydro-2′H,5′H-spiro[[1,3]dioxolane-2,8′-[2,4a]methanonaphthalene]; (1R,8aR)-4-isopropyl-1,6-dimethyl-1,2,3,7,8,8a-hexahydronaphthalene; (7,7,8,8-tetramethyloctahydro-2,3b-methanocyclopenta[1,3]cyclopropa[1,2]benzen-4-yl)methanol; 1-ethoxy-4-(tert-pentyl)cyclohexane; (3Z)-1-(2-buten-1-yloxy)-3-hexene; 4-(2-methoxypropan-2-yl)-1-methylcyclohex-1-ene; 3-methoxy-3,7-dimethylocta-1,6-diene; 3,7-dimethyloctanal; hexyl 2-hydroxybenzoate; hexyl (Z)-but-2-enoate; (Z)-3,7-dimethylocta-2,6-dien-1-yl formate; (Z)-1-(2,6,6-trimethylcyclohex-1-en-1-yl)pent-1-en-3-one; (E)-3,7-dimethylocta-4,6-dien-3-ol; methyl (Z)-3,7-dimethylocta-2,6-dienoate; ((1s,4s)-4-isopropylcyclohexyl)methanol; 3,7-dimethylocta-1,6-dien-3-yl propionate; 3,7-dimethylocta-1,6-dien-3-yl formate; 3,7-dimethylocta-1,6-dien-3-yl butyrate; 3,7-dimethylocta-1,6-dien-3-yl acetate; 3,7-dimethylocta-1,6-dien-3-ol; 2,2-dimethyl-5-phenylhexanenitrile; (Z)-4-(6,6-dimethylcyclohex-2-en-1-yl)-3-methylbut-3-en-2-one; 7-methyloctyl acetate; isopentyl octanoate; hexyl propionate; hexyl butyrate; hexyl 2-methylbutanoate; hexyl furan-2-carboxylate; heptyl acetate; (Z)-3,7-dimethylocta-2,6-dienenitrile; (E)-3,7-dimethylocta-2,6-dien-1-yl formate; (E)-3,7-dimethylocta-2,6-dien-1-yl octanoate; (E)-3,7-dimethylocta-2,6-dien-1-yl benzoate; (E)-3,7-dimethylocta-2,6-dienal; 1-isopropyl-4-methylcyclohexa-1,4-diene; 2-(sec-butyl)cyclohexan-1-one; 3-(2-ethylphenyl)-2,2-dimethylpropanal; 2-(tert-butyl)cyclohexyl ethyl carbonate; ethyl octanoate; ethyl 2-cyclohexylpropanoate; 4-methyl-2-phenyltetrahydro-2H-pyran; 2,6-dimethyloct-7-en-2-ol; 3-methyl-2-pentylcyclopent-2-en-1-one; 2-(4-methylcyclohexyl)propan-2-yl acetate; 4-(2,6,6-trimethylcyclohex-2-en-1-yl)butan-2-one; (oxybis(methylene))dibenzene; dibutyl phthalate; decyl 2-aminobenzoate; methyl (1s,4s)-1,4-dimethylcyclohexane-1-carboxylate; 2-cyclohexylethyl acetate; (3Z,5Z)-2,6-dimethylocta-1,3,5,7-tetraene; 4-cyclohexyl-2-methylbutan-2-ol; 2-benzyl-2-methylbut-3-enenitrile; 3,7-dimethyloct-6-enenitrile; 3,7-dimethyloct-6-en-1-yl 2-phenylacetate; 3,7-dimethyloct-6-en-1-yl formate; 3,7-dimethyloct-6-en-1-yl benzoate; 3,7-dimethyloct-6-en-1-ol;3,7-dimethyloct-6-enal; (E)-3,7-dimethylocta-2,6-dienal; (1R,2S,5R)-2,6,6-trimethylbicyclol[3.1.1]heptane; (Z)-hex-3-en-1-yl pentanoate; (E)-hex-3-en-1-yl (E)-2-methylbut-2-enoate; (Z)-hex-3-en-1-yl butyrate; 4-chloro-3,5-dimethylphenol; 5-isopropyl-2-methylphenol; (E)-2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-2-enal; 3-isopropyl-6-methylenecyclohex-1-ene; benzyl 2-hydroxybenzoate; benzyl 3-methylbutanoate; 1-(3,3-dimethylcyclohexyl)ethyl formate; (Z)-1-methoxy-4-(prop-1-en-1-yl)benzene; pentyl benzoate; 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl acetate; (Z)-3-methyl-4-(2,6,6-trimethylcyclohex-2-en-1-yl)but-3-en-2-one; (2-(allyloxy)ethyl)benzene; allyl heptanoate; 6,8-dimethylnonan-2-ol; -methyl-5-phenylhexan-3-one; 3,7-dimethyl-2-methyleneoct-6-enal; 3,7-dimethyloctan-1-ol; 2-pentylcyclopentan-1-ol; (2S,4S)-2-heptyl-2,4-dimethyl-1,3-dioxolane; (E)-2-isopropyl-5-methylhex-2-enal; 1-isopropyl-4-methyl-7-oxabicyclo[2.2.1]heptane; (Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one; (R)-3,7-dimethylocta-1,6-dien-3-ol;3 7-dimethyloct-6-enal; (R)-3,7-dimethyloct-6-enal; 3,7-dimethyloct-6-en-1-ol; 3,7-dimethyloct-6-en-1-ol; (1R,5R)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; (1S,5S)-2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; hexyl (Z)-2-methylbut-2-enoate; p-cymene; phenethyl isobutyrate; phenethyl (Z)-2-methylbut-2-enoate; phenethyl methacrylate; (2Z,5Z)-5,6,7-trimethylocta-2,5-dien-4-one; 1-methoxy-4-propylbenzene; 2-(4-(tert-butyl)phenyl)acetaldehyde; 4-(tert-pentyl)cyclohexan-1-ol; 2,6,6-trimethylbicyclo[3.1.1]hept-2-ene; ethyl (2,3,6-trimethylcyclohexyl) carbonate; 1-(3,3-dimethylcyclohexyl)ethyl acetate; (S)-3,7-dimethylocta-1,6-dien-3-ol; 1-isopropyl-4-methylenebicyclo[3.1.0]hexane; 3,7-dimethyloctanal; 4-(2,2,6-trimethylcyclohexyl)butan-2-ol; 3,7-dimethyloctan-3-ol; 3,7-dimethyloctan-3-yl acetate; ethyl (1R,6S)-2,2,6-trimethylcyclohexane-1-carboxylate; 2-isopropyl-5-methylphenol; (Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one; (Z)-1-methoxy-4-(prop-1-en-1-yl)benzene; 2,2,2-trichloro-1-phenylethyl acetate; 2,2,5-trimethyl-5-pentylcyclopentan-1-one; (4-tert-butylcyclohexyl) acetate; 4-(tert-butyl)cyclohexyl acetate; 4-methyl-4-phenylpentan-2-yl acetate; (Z)-1-((2-methylallyl)oxy)hex-3-ene; 4,5-epoxy-4,11,11-trimethyl-8-methylenebicyclo(7.2.0)undecane; 1,3,4,6,7,8alpha-hexahydro-1,1,5,5-tetramethyl-2H-2,4alpha-methanophtalen-8(5H)-one, and mixtures thereof.
 16. The composition according to claim 1, wherein said malodor reduction materials are not selected from the group consisting of geranyl nitrile; helional; nonanal; linalool; (S)-(+)-linalool; (R)-(−)-linalool; nerol; tetrahydrolinalool; 2-phenylethyl acetate; eugenol; ethyl linalool; allyl heptoate; agrumen nitrile; citronitrile; 2,2-dimethyl-3-(m-tolyl)propan-1-ol; 2-methyl-5-phenylpentan-1-ol; dodecanenitrile; 2-heptylcyclopentan-1-one; methyl nonyl acetaldehyde; 3-(2-ethylphenyl)-2,2-dimethylpropanal; (Z)-1-(2,6,6-trimethylcyclohex-2-en-1-yl)but-2-en-1-one; (R,E)-2-methyl-4-(2,2,3 -trimethylcyclopent-3-en-1-yl)but-2-en-1-ol; 4-(tert-butyl)cyclohexyl acetate; 1-cyclohexylethyl (E)-but-2-enoate; allyl 2-(cyclohexyloxy)acetate; alpha terpinyl acetate; beta terpinyl acetate; gamma terpinyl acetate; methyl dodecyl ether; 2,4-dimethyl-4,4a,5,9b-tetrahydroindeno[1,2-d][1,3]dioxine; cinnamyl isobutyrate; (E)-2-methyl-4-(2,6,6-trimethylcyclohex-1-en-1-yl)but-2-enal; gamma methyl ionone; ethyl 2,3,6-trimethyl cyclohexyl carbonate ethyl 2,3,6-trimethyl cyclohexyl carbonate; Citral diethyl acetal; Dimethoxycyclododecane; 1-((2S,3S)-2,3,8,8-tetramethyl-1,2,3,4,5,6,7,8-octahydronaphthalen-2-yl)ethan-1-one; oxacyclohexadecan-2-one; 4,6,6,7,8,8-hexamethyl-1,3,4,6,7,8-hexahydrocyclopentalglisochromene; Ethylene brassylate; Methyl (Z)-2-((3-(4-(tert-butyl)phenyl)-2-methylpropylidenelamino)benzoate; 4,7-Methano-1H-inden-5-ol, 3a,4,5,6,7,7a-hexahydro-, 5-acetate; cedryl methyl ether; vetivert acetate; 1-((3R,3aR,7R,8aS)-3,6,8,8-tetramethyl-2,3,4,7,8,8a-hexahydro-1H-3a,7-methanoazulen-5-yl)ethan-1-one; Benzophenone; Farnesol; trans,trans-farnesol; 3-(3-isopropylphenyl)butanal; 2,6,10-trimethylundec-9-enal; 3-(4-(tert-butyl)phenyl)propanal; 3-(4-isopropylphenyl)-2-methylpropanal; Citronellal (1); Citronellal (d); (E)-4,8-dimethyldeca-4,9-dienal; Pino Acetaldehyde; 3-(4-(tert-butyl)phenyl)-2-methylpropanal; Cinnamic aldehyde; Citral; Geranial; MethoxyMelonal; o-methoxycinnamaldehyde; (E)-4-((3aS,7aS)-octahydro-5H-4,7-methanoinden-5-ylidene)butanal; Methyl Octyl Acetaldehyde; 3-(4-methoxyphenyl)-2-methylpropanal; 5-methoxyoctahydro-1H-4,7-methanoindene-2-carbaldehyde; Iso Cyclocitral; Octanal; 2-Undecenal; 10-Undecenal; Trans -trans-2,6-Nonadienal; Trans-2, cis-6-nondienal; Heliotropin; Hexyl Cinnamic aldehyde; p-methyl-alpha-pentylcinnamaldehyde; Alpha-methyl cinnamaldehyde; 3,4-dimethoxybenzaldehyde; Myrtenal; Perillaldehyde; Maceal; Methyl palmitate; Methyl iso eugenol; and mixtures thereof.
 17. The composition according to claim 1, wherein said composition comprises from about 0.005% to about 10% of said malodor agent, wherein said malodor agent comprises from about 1 to about 30 malodor reduction materials having a Blocker Index of 3 to about 0.001, wherein at least a portion of said malodor reduction materials are encapsulated.
 18. A process for treating a laundry article using the composition according to claim 1 comprising the steps of: providing about 1 mg to about 100 g of said particles in a washing machine or laundry wash basin; and washing said laundry article in a wash liquor in said washing machine or laundry wash basin into which said particles are dissolved.
 19. A process for reducing malodor from a laundry article using the composition according to claim 1 comprising the steps of: providing about 1 mg to about 100 g of said particles in a fluid pervious package; and placing said package proximal to said laundry article or contacting said laundry article with said fluid pervious package. 